scholarly journals Casein/Apricot Filler in the Production of Flame-Retardant Polyurethane Composites

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3620
Author(s):  
Sylwia Członka ◽  
Agnė Kairytė ◽  
Karolina Miedzińska ◽  
Anna Strąkowska
Keyword(s):  
Mechanical Properties ◽  
Mechanical Performance ◽  
Dynamic Mechanical Properties ◽  
Uniform Structure ◽  
Thermal And Mechanical Properties ◽  
Mechanical Performances ◽  
Polyurethane Composites ◽  
Natural Combination ◽  
The Impact ◽  
And Storage

Polyurethane (PUR) composites reinforced with 1, 2, and 5 wt.% of apricot filler modified with casein were synthesized in the following study. The impact of 1, 2, and 5 wt.% of casein/apricot filler on the cellular structure and physico-mechanical performances of reinforced PUR composites were determined. It was found that the incorporation of 1 and 2 wt.% of casein/apricot filler resulted in the production of PUR composites with improved selected physical, thermal, and mechanical properties, while the addition of 5 wt.% of casein/apricot filler led to some deterioration of their physico-mechanical performance. The best results were obtained for PUR composites reinforced with 2 wt.% of casein/apricot filler. Those composites were characterized by a uniform structure and a high content of closed cells. Compared with the reference foam, the incorporation of 2 wt.% of casein/apricot filler resulted in improvement in compressive strength, flexural strength, impact strength, and dynamic mechanical properties—such as glass transition temperature and storage modulus. Most importantly, PUR composites showed better fire resistance and thermal stability due to the good thermal performance of casein. The main aim of this article is to determine the influence of the natural combination of the apricot filler and casein on the mechanical properties and flammability of the obtained composites.

scholarly journals Mechanically Strong Polyurethane Composites Reinforced with Montmorillonite-Modified Sage Filler (Salvia officinalis L.)

2021 ◽  
Vol 22 (7) ◽  
pp. 3744
Author(s):  
Sylwia Członka ◽  
Agnė Kairytė ◽  
Karolina Miedzińska ◽  
Anna Strąkowska ◽  
Agnieszka Adamus-Włodarczyk
Keyword(s):  
Mechanical Properties ◽  
Cell Structure ◽  
Dynamic Mechanical Properties ◽  
Uniform Structure ◽  
Limiting Oxygen Index ◽  
Closed Cell ◽  
Rate Of Heat Release ◽  
Salvia Officinalis L ◽  
Polyurethane Composites ◽  
The Impact

Rigid polyurethane (PUR) foams reinforced with 1, 2, and 5 wt.% of salvia filler (SO filler) and montmorillonite-modified salvia filler (MMT-modified SO filler) were produced in the following study. The impact of 1, 2, and 5 wt.% of SO filler and MMT-modified SO filler on the morphological, chemical, and mechanical properties of PUR composites were examined. In both cases, the addition of 1 and 2 wt.% of SO fillers resulted in the synthesis of PUR composites with improved physicomechanical properties, while the addition of 5 wt.% of SO fillers resulted in the formation of PUR composites with a less uniform structure and, therefore, some deterioration in their physicomechanical performances. Moreover, the results showed that the modification of SO filler with MMT improved the interphase compatibility between filler surface and PUR matrix. Therefore, such reinforced PUR composites were characterized by a well-developed closed-cell structure and improved mechanical, thermal, and flame-retardant performances. For example, when compared with reference foam, the addition of 2 wt.% of MMT-modified SO filler resulted in the formation of PUR composites with greater mechanical properties (compressive strength, flexural strength) and improved dynamic-mechanical properties (storage modulus). The PUR composites were characterized by better thermal stability as well as improved flame retardancy—e.g., decreased peak rate of heat release (pHRR), reduced total smoke release (TSR), and increased limiting oxygen index (LOI).

scholarly journals Coir Fibers Treated with Henna as a Potential Reinforcing Filler in the Synthesis of Polyurethane Composites

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1128
Author(s):  
Sylwia Członka ◽  
Anna Strąkowska ◽  
Agnė Kairytė
Keyword(s):  
Mechanical Properties ◽  
High Energy ◽  
Dynamic Mechanical Properties ◽  
Milling Process ◽  
Coir Fiber ◽  
Lawsonia Inermis ◽  
Coir Fibers ◽  
Mechanical Performances ◽  
The Impact ◽  
Reinforcing Filler

In this study, coir fibers were successfully modified with henna (derived from the Lawsonia inermis plant) using a high-energy ball-milling process. In the next step, such developed filler was used as a reinforcing filler in the production of rigid polyurethane (PUR) foams. The impact of 1, 2, and 5 wt % of coir-fiber filler on structural and physico-mechanical properties was evaluated. Among all modified series of PUR composites, the greatest improvement in physico-mechanical performances was observed for PUR composites reinforced with 1 wt % of the coir-fiber filler. For example, on the addition of 1 wt % of coir-fiber filler, the compression strength was improved by 23%, while the flexural strength increased by 9%. Similar dependence was observed in the case of dynamic-mechanical properties—on the addition of 1 wt % of the filler, the value of glass transition temperature increased from 149 °C to 178 °C, while the value of storage modulus increased by ~80%. It was found that PUR composites reinforced with coir-fiber filler were characterized by better mechanical performances after the UV-aging.

Effect of toughened polyamide-coated carbon fiber fabric on the mechanical performance and fracture toughness of CFRP

2021 ◽  
pp. 002199832199945
Author(s):  
Jong H Eun ◽  
Bo K Choi ◽  
Sun M Sung ◽  
Min S Kim ◽  
Joon S Lee
Keyword(s):  
Mechanical Properties ◽  
Fracture Toughness ◽  
Photoelectron Spectroscopy ◽  
Mechanical Performance ◽  
Epoxy Composites ◽  
Scanning Calorimetry ◽  
Internal Damage ◽  
Impact Tests ◽  
Flexural Tests ◽  
The Impact

In this study, carbon/epoxy composites were manufactured by coating with a polyamide at different weight percentages (5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.%) to improve their impact resistance and fracture toughness. The chemical reaction between the polyamide and epoxy resin were examined by fourier transform infrared spectroscopy, differential scanning calorimetry and X-ray photoelectron spectroscopy. The mechanical properties and fracture toughness of the carbon/epoxy composites were analyzed. The mechanical properties of the carbon/epoxy composites, such as transverse flexural tests, longitudinal flexural tests, and impact tests, were investigated. After the impact tests, an ultrasonic C-scan was performed to reveal the internal damage area. The interlaminar fracture toughness of the carbon/epoxy composites was measured using a mode I test. The critical energy release rates were increased by 77% compared to the virgin carbon/epoxy composites. The surface morphology of the fractured surface was observed. The toughening mechanism of the carbon/epoxy composites was suggested based on the confirmed experimental data.

Influence of Melt Temperature on Compressive Plasticity of a Cu-Zr-Al Bulk Metallic Glass

2010 ◽  
Vol 146-147 ◽  
pp. 517-521
Author(s):  
Sheng Hui Xie ◽  
Xie Rong Zeng ◽  
Dong Ju Fu ◽  
Lei Zhao ◽  
Qiang Hu
Keyword(s):  
Mechanical Properties ◽  
Plastic Deformation ◽  
Metallic Glasses ◽  
Mechanical Performance ◽  
Casting Temperature ◽  
Thermal And Mechanical Properties ◽  
Micro Hardness ◽  
Melt Temperature ◽  
Hardness Tests ◽  
Important Solution

Cu47.5Zr47.5Al5 bulk metallic glasses (BMGs) were cast from the melt temperature 1143 to 1373 K. The structure, thermal and mechanical properties of the BMGs were investigated by XRD, DSC, HRTEM, dilatometric measurements, micro-hardness tests and uniaxial compression. The results indicate that the microstructure and mechanical performance of BMGs are closely affected by the casting temperature. Proper casting temperature ensures the BMGs with large relaxed excess free volume (REFV) and nano-crystallites, which favor the plastic deformation in Cu47.5Zr47.5Al5 BMGs. Regulating the preparing parameters is an important solution to good plasticity in BMGs.

Phase Morphology, Thermal and Mechanical Properties of Compatibilized Nylon12/Natural Rubber Blends Using PS/MNR

2013 ◽  
Vol 844 ◽  
pp. 53-56
Author(s):  
Saravalee Saengthaveep ◽  
Sadhan C. Jana ◽  
Rathanawan Magaraphan
Keyword(s):  
Mechanical Properties ◽  
Natural Rubber ◽  
Moisture Absorption ◽  
Rubber Particle ◽  
Impact Resistance ◽  
Phase Morphology ◽  
Thermal And Mechanical Properties ◽  
Binary Blend ◽  
Polyamide 12 ◽  
The Impact

To produce a tough material for application demanding high impact resistance and low moisture absorption, melt blending of Nylon12 (Polyamide 12, PA12) and natural rubber (NR) was carried out in a brabender plasticorder at 210 °C with rotor speed of 70 rpm in the presence of polystyrene/maleated natural rubber (PS/MNR) blend as a compatibilizer. The effect of compatibilizer content (1, 3, 5, 7 and 10 phr) on phase morphology, thermal, and mechanical properties of [Nylon12/NR]/[PS/MNR] blends was investigated by using SEM, DSC, and Izod impact tester, respectively. The result revealed that PS/MNR blend improved the compatibility of Nylon12/NR blends efficiently due to the presence of amide linkage at the interfaces from the reaction between the reactive groups of MNR and the NH2 end groups of Nylon12 during mixing. A fine phase morphology (good dispersion and small dispersed phase size of NR domains in Nylon12 matrix) of [Nylon12/NR]/[PS/MNR] blends was observed at the optimum compatibilizer content of 7 phr, relating to the improvement of mechanical property. The impact energy of [Nylon12/NR]/[PS/MNR] blends was 503 J/m higher than that of neat Nylon12 (115 J/m) and Nylon12/NR binary blend (241 J/m) due to the toughening effect of rubber and proper morphology. The melting temperature of all blends did not change obviously from thermal analysis. However, the presence of rubber particle obstructed the crystallization of Nylon12 phase, leading to the decreasing of %crystallinity from 93% to around 70%.

scholarly journals Flame-retardant MXene/Polyimide Film with Outstanding Thermal and Mechanical Properties Based on the Secondary Orientation Strategy

2021 ◽  
Author(s):  
Yue Zhu ◽  
Qingyu Peng ◽  
Haowen Zheng ◽  
Fuhua Xue ◽  
Pengyang Li ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Transition Metal ◽  
Mechanical Performance ◽  
Polyimide Film ◽  
Polymeric Films ◽  
Two Dimensional ◽  
Thermal And Mechanical Properties ◽  
Metal Carbides ◽  
Transition Metal Carbides

With the development of multifunction and miniaturization in modern electronics, polymeric films with strong mechanical performance and high thermal conductivity are urgently needed. Two-dimensional transition metal carbides and nitrides (MXenes)...

Novel soy oil based polyurethane composites: Fabrication and dynamic mechanical properties evaluation

2004 ◽  
Vol 39 (5) ◽  
pp. 1887-1890 ◽  
Author(s):  
J.-P. Latere Dwan'isa ◽  
A. K. Mohanty ◽  
M. Misra ◽  
L. T. Drzal ◽  
M. Kazemizadeh
Keyword(s):  
Mechanical Properties ◽  
Dynamic Mechanical Properties ◽  
Soy Oil ◽  
Dynamic Mechanical ◽  
Polyurethane Composites

scholarly journals On the Use of Biobased Waxes to Tune Thermal and Mechanical Properties of Polyhydroxyalkanoates–Bran Biocomposites

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2615
Author(s):  
Vito Gigante ◽  
Patrizia Cinelli ◽  
Maria Cristina Righetti ◽  
Marco Sandroni ◽  
Giovanni Polacco ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Wheat Bran ◽  
Mechanical Performance ◽  
Low Cost ◽  
Impact Resistance ◽  
Mechanical Analysis ◽  
Polymeric Matrix ◽  
Flour Milling ◽  
Mechanical Performances ◽  
Analytic Models

In this work, processability and mechanical performances of bio-composites based on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) containing 5, 10, and 15 wt % of bran fibers, untreated and treated with natural carnauba and bee waxes were evaluated. Wheat bran, the main byproduct of flour milling, was used as filler to reduce the final cost of the PHBV-based composites and, in the same time, to find a potential valorization to this agro-food by-product, widely available at low cost. The results showed that the wheat bran powder did not act as reinforcement, but as filler for PHBV, due to an unfavorable aspect ratio of the particles and poor adhesion with the polymeric matrix, with consequent moderate loss in mechanical properties (tensile strength and elongation at break). The surface treatment of the wheat bran particles with waxes, and in particular with beeswax, was found to improve the mechanical performance in terms of tensile properties and impact resistance of the composites, enhancing the adhesion between the PHBV-based polymeric matrix and the bran fibers, as confirmed by predictive analytic models and dynamic mechanical analysis results.

Manufacture of Ultra-Dense Knitted Superelastic Structures

2018 ◽  
Author(s):  
Henry Koon ◽  
Jack Laven ◽  
Julianna Abel
Keyword(s):  
Mechanical Properties ◽  
Mechanical Performance ◽  
Cell Structure ◽  
Axial Loading ◽  
Consumer Products ◽  
Niti Shape Memory Alloy ◽  
Structural Element ◽  
Loading Tests ◽  
Structural Architecture ◽  
The Impact

Knitted Textiles made from Nickel-Titanium (NiTi) shape memory alloy wires are a new structural element with enhanced properties for a variety of applications. Potential advantages of this structural form include enhanced bending flexibility, tailorable in-plane, and through-thickness mechanical performance, and energy absorption and damping. Inspection of the knit pattern reveals a repeating cell structure of interlocking loops. Because of this repeating structure, knits can be evaluated as cellular structures that leverage their loop-based architecture for mechanical robustness and flexibility. The flexibility and robustness of the structure can be further enhanced by manufacturing with superelastic NiTi. The stiffness of superelastic NiTi, however, makes traditional knit manufacturing techniques inadequate, so knit manufacturing in this research is aided by shape setting the superelastic wire to a predefined pattern mimicking the natural curve of a strand within a knit fabric. This predefined shape-set geometry determines the outcome of the knit’s mechanical performance and tunes the mechanical properties. In this research, the impact of the shape setting process on the material itself is explored through axial loading tests to quantify the effect that heat treatment has on a knit sample. A means of continuously shape setting and feeding the wire into traditional knitting machines is described. These processes lend themselves to mass production and build upon previous textile manufacturing technologies. This research also proposes an empirical exploration of superelastic NiTi knit mechanical performance and several new techniques for manufacturing such knits with adjustable knit parameters. Displacement-controlled axial loading tests in the vertical (wale) direction determined the recoverability of each knit sample in the research and were iteratively increased until failure resulted. Knit samples showed recoverable axial strains of 65–140%, which could be moderately altered based on knit pattern and loop parameters. Furthermore, this research demonstrates that improving the density of the knit increases the stiffness of the knit without any loss in recoverable strains. These results highlight the potential of this unique structural architecture that could be used to design fabrics with adjustable mechanical properties, expanding the design space for aerospace structures, medical devices, and consumer products.

Sign in / Sign up

Export Citation Format

Share Document