scholarly journals The Rheometric Analysis of the Polymer Modifier’s Properties in the Environment of Hydrated Cement

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1064
Author(s):  
Khrystyna Moskalova ◽  
Aleksej Aniskin ◽  
Goran Kozina ◽  
Božo Soldo

This paper investigates the effect of polymer modifiers (re-dispersible powder, multifunctional additives, methylhydroxyethylcellulose) on the rheological behavior of emulsions, saturated of calcium hydrosilicates to simulate a hydrating cement structure. The subjects of the study were modified emulsions which had varied concentrations of each additive and they were examined comparatively to a base emulsion. Tests were performed with a CR-rheometer (“Himpribor-1”, Tula, Russia) applying the Searle measuring principle at various shear rates to characterize viscosity properties. The performance of modified mixtures within the operating period was analyzed by using two parameters—effective viscosity (η) and the proportion of structural failure (|m|). The test results showed that the most important factor influencing rheological characteristics is the addition of methylhydroxyethylcellulose additive—the higher additive amount in the emulsion, the higher the viscosity. Furthermore it was noted in the work that adding olefin sulfonate sodium salt causes reduced viscosities as well as lower shear moduli. If ethylhydroxyethylcellulose and ethylene vinyl acetate additives are used in the same mixture together, the rate of structural failure |m| can be relatively similar and low regardless of whether the mixture has large or small viscosity values.

1975 ◽  
Author(s):  
H. Rieger ◽  
H. Schmid-Schönbein

Even after pseudopodia formation platelets - unlike all other known formed blood elements - remain dispersed in stasis and creeping flow and become aggregated only in the presence of a minimum amount of shearing. The “rheoaggregometer” (Rieger et al., Pflüger’s Archiv, 343, R 33, 1973) allows to measure the minimum shear rates necessary for platelet aggregation (PA), as well as the initial rate and the maximum extent of PA in citrated PRP.PA is quantified photometrically as a function of variable shear rates. The initial rate of PA steadily increases with increasing shear rates up to 460 sec-1. However, the maximal extent of PA (indicating the mechanical integrity of formed aggregates) saturates at about 35 sec-1 and then decreases because of a destruction of formed aggregates and of prevention of further PA. The aggregability of the platelets, as reflected by various degrees of shape changes, is enhanced by a drop of temperature and a rise in pH as well as by the so called aggregating agents (e.g. epinephrine 10-6 up to 10-9 M/l) : consecutively lower shear rates (lower effects of collision) are necessary to induce PA. In citrated PRP stable platelet aggregates are produced only within a defined range of shear rates. Platelet aggregability and aggregate stability are independent variables influenced by different experimental conditions.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2752
Author(s):  
Benedikt Finke ◽  
Clara Sangrós Sangrós Giménez ◽  
Arno Kwade ◽  
Carsten Schilde

In this paper, a widely mechanistic model was developed to depict the rheological behaviour of nanoparticulate suspensions with solids contents up to 20 wt.%, based on the increase in shear stress caused by surface interaction forces among particles. The rheological behaviour is connected to drag forces arising from an altered particle movement with respect to the surrounding fluid. In order to represent this relationship and to model the viscosity, a hybrid modelling approach was followed, in which mechanistic relationships were paired with heuristic expressions. A genetic algorithm was utilized during model development, by enabling the algorithm to choose among several hard-to-assess model options. By the combination of the newly developed model with existing models for the various physical phenomena affecting viscosity, it can be applied to model the viscosity over a broad range of solids contents, shear rates, temperatures and particle sizes. Due to its mechanistic nature, the model even allows an extrapolation beyond the limits of the data points used for calibration, allowing a prediction of the viscosity in this area. Only two parameters are required for this purpose. Experimental data of an epoxy resin filled with boehmite nanoparticles were used for calibration and comparison with modelled values.


Author(s):  
Xing Chen ◽  
Shishun Zhang ◽  
Jiming Lin ◽  
Huiyong Zhang

The analytical and experiment research of In-Vessel Corium Retention (IVR) in the Chinese Pressurized-water Reactor 1000 MWe (CPR1000) are introduced. The IVR research consists of preliminary phase and detailed phase. The analysis of thermal failure, structural failure and penetration failure of Reactor Pressure Vessel (RPV) and the experimental research of External Reactor Vessel Cooling (ERVC) are performed at preliminary phase. Analysis results show that the RPV failure is the dominated by thermal failure mode and the probability of the thermal failure is very low. Test results show that the IVR success probability for CPR1000 is about 99% if the Critical Heat Flux (CHF) of CPR1000 is the same as that of AP600. Further works, including the ERVC enhancement design, the CHF test of the RPV outer wall and the recalculation of the IVR success probability for CPR1000, will be performed at detailed phase in the near future.


2008 ◽  
Vol 294 (4) ◽  
pp. H1833-H1839 ◽  
Author(s):  
S. C. Newcomer ◽  
C. L. Sauder ◽  
N. T. Kuipers ◽  
M. H. Laughlin ◽  
C. A. Ray

Shear rate is significantly lower in the superficial femoral compared with the brachial artery in the supine posture. The relative shear rates in these arteries of subjects in the upright posture (seated and/or standing) are unknown. The purpose of this investigation was to test the hypothesis that upright posture (seated and/or standing) would produce greater shear rates in the superficial femoral compared with the brachial artery. To test this hypothesis, Doppler ultrasound was used to measure mean blood velocity (MBV) and diameter in the brachial and superficial femoral arteries of 21 healthy subjects after being in the supine, seated, and standing postures for 10 min. MBV was significantly higher in the brachial compared with the superficial femoral artery during upright postures. Superficial femoral artery diameter was significantly larger than brachial artery diameter. However, posture had no significant effect on either brachial or superficial femoral artery diameter. The calculated shear rate was significantly greater in the brachial (73 ± 5, 91 ± 11, and 97 ± 13 s−1) compared with the superficial femoral (53 ± 4, 39 ± 77, and 44 ± 5 s−1) artery in the supine, seated, and standing postures, respectively. Contrary to our hypothesis, our current findings indicate that mean shear rate is lower in the superficial femoral compared with the brachial artery in the supine, seated, and standing postures. These findings of lower shear rates in the superficial femoral artery may be one mechanism for the higher propensity for atherosclerosis in the arteries of the leg than of the arm.


1983 ◽  
Vol 73 (6A) ◽  
pp. 1895-1902
Author(s):  
Gerard C. Pardoen

Abstract The ambient vibration test results conducted on the Imperial County Services Building prior to the 15 October 1979 Imperial Valley earthquake are summarized. These results are of significant interest because the Imperial County Services Building has been the source of many postearthquake investigations due to the fact that the 1979 earthquake represented the first time a building instrumented with strong motion recorders suffered and recorded the major structural failure.


Materials ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 7318
Author(s):  
Anita Ptak ◽  
Paula Taciak ◽  
Wojciech Wieleba

This article concerns the tribological properties of three selected polymer materials: polyamide PA6, polyethylene PE-HD and polyetheretherketone composite PEEK/BG during sliding against aluminium alloy EN AW-2017A in the presence of hydraulic oil HLP 68. The tests were carried out under contact pressure p of 3.5–11 MPa at ambient temperature T ranging from −20 °C to +20 °C. The dependence of kinetic friction coefficient μk on the two parameters was determined through tribological tests carried out using a pin-on-disc tribometer. A five-level central composite rotatable design (CCRD) was adopted for the experiment. All the test results were statistically analysed. The microhardness of the surface of the polymeric material was measured before and after the friction process. The surface was also examined under SEM. Temperature and contact pressure have been found to have a significant effect on the tribological properties of the tested sliding pairs. Relative to the applied friction conditions, the surfaces after friction showed rather heavy signs of wear.


1985 ◽  
Vol 150 ◽  
pp. 357-380 ◽  
Author(s):  
Daniel M. Hanes ◽  
Douglas L. Inman

The rapid shearing of a mixture of cohesionless glass spheres and air or water was studied in an annular, parallel-plate shear cell designed after Savage (1978). Two types of flow were observed. In the first type of flow the entire mass of the granular material was mobilized. At high shear rates the shear and normal stresses were found to be quadratically dependent upon the mean shear rate (at constant volume concentration), in general agreement with the observations of Bagnold (1954) and Savage & Sayed (1984), and the ‘kinetic’ theory of Jenkins & Savage (1983). The stresses were found to be weakly dependent on the volume concentration up to approximately 0.5, and strongly dependent above this concentration. For flows in which water was the interstitial fluid, the ratio of the shear stress to the normal stress was slightly higher (than in air), and the stresses at lower shear rates were found to be more nearly linearly related to the shear rate. It is suggested that these effects are contributed to by the viscous dampening of grain motions by the water. The second type of flow was distinguished by the existence of an internal boundary above which the granular material deformed rapidly, but below which the granular material remained rigidly locked in place. The thickness of the shearing layer was measured to be between 5 and 15 grain diameters. The stress ratio at the bottom of the shearing layer was found to be nearly constant, suggesting the internal boundary is a consequence of the immersed weight of the shearing grains, and may be described by a Coulomb yield criterion. A scaled concentration is proposed to compare similar data obtained using different-sized materials or different apparatus. An intercomparison of the two types of flow studied, along with a comparison between the present experiments and those of Bagnold (1954) and Savage & Sayed (1984), suggests that the nature of the boundaries can have a significant effect upon the dynamics of the entire flow.


2021 ◽  
Author(s):  
David Earl Cain ◽  
Keith Albert Klopfenstein ◽  
James Robert McMullan

Abstract A decommissioning and abandonment requirement to shear 9 5/8-inch casing in certain circumstances with a 13 5/8-inch × 10,000 psi rated working pressure, RWP, Shear RAM type blowout preventer, BOP, resulted in a need to develop a novel casing shear device and shear calculation method. Results of shear testing, future engineering planning guidance, the new shear calculation method, and comparison to legacy technology are included in this paper. Interaction with the end user to understand requirements, a five-step problem solving procedure, a basis of design process, materials justification, verification analysis, validation testing, and describing an improved shear operator force/pressure calculation are all described. Shear larger casing in the required and restrictive RAM BOP and well bore presented a problematic challenge. Equally, tubular fish size was required to support fishing extraction operations following shear. Validation test results exceeded requirements and resulted in the need for a new approach to the shear calculation method. The novel shear RAM geometry was developed utilizing shear calculation methods which were based on legacy considerations. API 16A shear validation procedures and two legacy shear calculation methods where employed. Shear calculations are used to anticipate the RAM BOP operator pressures required to shear a specific tubular. The larger than historically allowed casing size to be sheared in a 13 5/8-inch × 10,000 psi RAM BOP meant higher operator pressures were anticipated for each operator option. A Novel shear RAM geometry was developed as a design intent to lower shear force/pressure. There was an observation during validation testing that the geometry exceeded expectations to lower shear pressure significantly. This observation led to a conclusion that an improved shear calculation method was required for this application. This novel calculation method description / statistical treatment, test results, RAM design methods, and tabular shear engineering planning information are included in this paper. One additional requirement of the shear RAM geometry was to provide an upper and lower fish deformed surface which could be easily retrieved thru the 13 5/8-inch BOP bore. An additional observation was that the fish width requirement was achieved. The novel shear calculation method allows an engineer to precisely plan for bonnet actuation pressures when larger casing is sheared. The precise calculation of shear force/pressure also assists with BOP operator size and type selection. The engineer will gain casing size versus shear pressure for specific operator options in tabular format. Planners will gain insight into tubular fish deformation estimation allowing mitigation of tubular extraction risk during operations planning.


Author(s):  
Moncef Nehdi ◽  
Sidney Mindess

The emergence of new special concretes on construction sites has shown that concretes of the same slump may behave quite differently on the job. For these concretes, one cannot rely on the traditional workability tests for quality control and rheological characterization. It has been claimed that the flow behavior of fresh concrete closely approximates the Bingham model and that at least two parameters are therefore needed to describe its rheology. Thus, rheological measurements must be carried out at not fewer than two shear rates. This study examines the applicability of the Bingham model to fluid and self-leveling highstrength concrete (HSC). Results obtained from a rheometer are compared with results of the standard slump test. Fluid concrete mixtures were investigated that had a water/binder ratio ( w/ b) of 0.33 and slump values of 200 ± 20 mm and incorporated proportions of limestone filler, silica fume, and ground silica as partial replacement (by volume) of cement. In addition, self-leveling concrete mixtures (torque viscosity ≤ 1 Nm at 15 min) having a w/ b ratio of 0.25 and 15 percent replacement of cement by various fillers were examined. The possibility of characterizing the rheology of fluid and self-leveling HSC on the basis of only two tests carried out at two different shear rates was addressed. An effort was made to define which is more relevant in a rheometer flow curve: the ascending part, the descending part, the maximum stress requirement, the flow resistance, the torque viscosity, or combinations of these factors. The possibility of measuring the rapid stiffening behavior of fresh HSC with time and the effect of ultrafine particles on the rheology using rheometric tests were also investigated.


1983 ◽  
Vol 245 (2) ◽  
pp. H252-H258 ◽  
Author(s):  
T. Shiga ◽  
K. Imaizumi ◽  
N. Harada ◽  
M. Sekiya

An apparatus for determining the velocity of erythrocyte rouleaux formation was constructed, combining an inverted microscope, a transparent cone-plate viscometer, a TV image analyzer, and a computer. At lower shear rates, the overall process is the sedimentation and the rouleaux formation followed by the development of three-dimensional aggregates. The individual erythrocyte could be observed and the process was expressed by the time courses of the changes in the count and area of particles; taking the computed increment in the area/count, the rate of rouleaux formation could be estimated. The effects of shear rates, hematocrits, plasma proteins, and pH were quantified. The rate of rouleaux formation in autologous plasma increased by (1) lowering the shear rates (1.9 less than or equal to gamma less than or equal to 15 s-1),2) increasing the hematocrit (up to 0.6%), 3) adding human fibrinogen (up to 600 mg/dl) or gamma-globulin, and 4) increasing pH. The transformation to echinocytes or to stomatocytes decreased the rate of rouleaux formation. The pH effect was explained by the increase in mean corpuscular volume at lower pH rather than by the changes in the electrostatic repulsion or in the protein binding.


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