scholarly journals Effective Doping of Single-Walled Carbon Nanotubes with Polyethyleneimine

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 65
Author(s):  
Monika Rdest ◽  
Dawid Janas

More and more electrically conducting materials are required to sustain the technological progress of civilization. Faced with the performance limits of classical materials, the R&D community has put efforts into developing nanomaterials, which can offer sufficiently high operational parameters. In this work, single-walled carbon nanotubes (SWCNTs) were doped with polyethyleneimine (PEI) to create such material. The results show that it is most fruitful to combine these components at the synthesis stage of an SWCNT network from their dispersion. In this case, the electrical conductivity of the material is boosted from 249 ± 21 S/cm to 1301 ± 56 S/cm straightforwardly and effectively.

Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5764
Author(s):  
Monika Rdest ◽  
Dawid Janas

Electrically conducting composites are highly sought-after materials. Their capacity to withstand mechanical deformation while simultaneously offering facile charge transport recently opened numerous exploitation fields for them. In this contribution, composites were made from single-walled carbon nanotubes (SWCNTs) and ethyl cellulose (EC). Then, a straightforward process of doping involving water vapor was developed and tested over 30 days. The inclusion of water in the EC/SWCNT network resulted in a notable increase in the electrical conductivity from 250 ± 21 S/cm to 905 ± 34 S/cm. Interestingly, doping of the material experienced remarkable stability due to the favorable surface chemistry of the EC filler.


2013 ◽  
Vol 51 (2) ◽  
pp. 137-144
Author(s):  
Naesung Lee ◽  
Jeung Choon Goak ◽  
Tae Yang Kim ◽  
Jongwan Jung ◽  
Young-Soo Seo ◽  
...  

2012 ◽  
Vol 2 (2) ◽  
pp. 200-209 ◽  
Author(s):  
Jurgen Bachl ◽  
Thimo Huber ◽  
Dennis Kuhbeck ◽  
Eva-Maria Schon ◽  
Gabriele Brunner ◽  
...  

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3808 ◽  
Author(s):  
Blazej Podlesny ◽  
Bogumila Kumanek ◽  
Angana Borah ◽  
Ryohei Yamaguchi ◽  
Tomohiro Shiraki ◽  
...  

Single-walled carbon nanotubes (SWCNTs) remain one of the most promising materials of our times. One of the goals is to implement semiconducting and metallic SWCNTs in photonics and microelectronics, respectively. In this work, we demonstrated how such materials could be obtained from the parent material by using the aqueous two-phase extraction method (ATPE) at a large scale. We also developed a dedicated process on how to harvest the SWCNTs from the polymer matrices used to form the biphasic system. The technique is beneficial as it isolates SWCNTs with high purity while simultaneously maintaining their surface intact. To validate the utility of the metallic and semiconducting SWCNTs obtained this way, we transformed them into thin free-standing films and characterized their thermoelectric properties.


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