scholarly journals Enhancing Electrical Conductivity of Composites of Single-Walled Carbon Nanotubes and Ethyl Cellulose with Water Vapor

Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5764
Author(s):  
Monika Rdest ◽  
Dawid Janas

Electrically conducting composites are highly sought-after materials. Their capacity to withstand mechanical deformation while simultaneously offering facile charge transport recently opened numerous exploitation fields for them. In this contribution, composites were made from single-walled carbon nanotubes (SWCNTs) and ethyl cellulose (EC). Then, a straightforward process of doping involving water vapor was developed and tested over 30 days. The inclusion of water in the EC/SWCNT network resulted in a notable increase in the electrical conductivity from 250 ± 21 S/cm to 905 ± 34 S/cm. Interestingly, doping of the material experienced remarkable stability due to the favorable surface chemistry of the EC filler.

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 65
Author(s):  
Monika Rdest ◽  
Dawid Janas

More and more electrically conducting materials are required to sustain the technological progress of civilization. Faced with the performance limits of classical materials, the R&D community has put efforts into developing nanomaterials, which can offer sufficiently high operational parameters. In this work, single-walled carbon nanotubes (SWCNTs) were doped with polyethyleneimine (PEI) to create such material. The results show that it is most fruitful to combine these components at the synthesis stage of an SWCNT network from their dispersion. In this case, the electrical conductivity of the material is boosted from 249 ± 21 S/cm to 1301 ± 56 S/cm straightforwardly and effectively.


Nanomaterials ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 1113 ◽  
Author(s):  
Bogumiła Kumanek ◽  
Tomasz Wasiak ◽  
Grzegorz Stando ◽  
Paweł Stando ◽  
Dariusz Łukowiec ◽  
...  

Despite the widespread use of sonication for individualization of nanomaterials, its destructive nature is rarely acknowledged. In this study, we demonstrated how exposure of the material to a hostile sound wave environment can be limited by the application of another preprocessing step. Single-walled carbon nanotubes (CNTs) were initially ground in a household coffee grinder, which enabled facile deagglomeration thereof. Such a simple approach enabled us to obtain high-quality CNT dispersion at reduced sonication time. Most importantly, electrical conductivity of free-standing films prepared from these dispersion was improved almost fourfold as compared with unground material eventually reaching 1067 ± 34 S/cm. This work presents a new approach as to how electrical properties of nanocarbon ensembles may be enhanced without the application of doping agents, the presence of which is often ephemeral.


2011 ◽  
Vol 306-307 ◽  
pp. 1182-1185
Author(s):  
Hong Mei Niu

Nanocomposites of single-walled carbon nanotubes modified polypyrrole (PPy/SWNTs) were synthesized successfully by in situ oxidative polymerization method in the FeCl3·6H2O solution. The morphological structure, electrical conductivity and thermal stability of the nanocomposites were characterized by TEM, SEM, FTIR and TGA. The PPy/SWNTs were 50-100 nm in diameter of PPy coating uniformly on the surface of the SWNTs. FTIR spectra revealed the presence of covalently interaction between the PPy and the carbon nanotubes. The electrical conductivity of PPy/SWNTs composite and pure PPy were 93 and 8.0×10-3 S/cm, respectively. Meanwhile, the PPy/SWNTs composites possessed higher thermal stability (65.9 wt. % weight loss at 600 °C) compared to pure PPy (81.2 wt. % weight loss at 600°C), the content of SWNTs was 15.3 wt. %.


RSC Advances ◽  
2012 ◽  
Vol 2 (9) ◽  
pp. 3634 ◽  
Author(s):  
Tomonori Ohba ◽  
Sei-ichi Taira ◽  
Kenji Hata ◽  
Katsumi Kaneko ◽  
Hirofumi Kanoh

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