scholarly journals Silicon Oxycarbide-Graphite Electrodes for High-Power Energy Storage Devices

Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4302
Author(s):  
Dominik Knozowski ◽  
Magdalena Graczyk-Zajac ◽  
Grzegorz Trykowski ◽  
Monika Wilamowska-Zawłocka

Herein we present a study on polymer-derived silicon oxycarbide (SiOC)/graphite composites for a potential application as an electrode in high power energy storage devices, such as Lithium-Ion Capacitor (LIC). The composites were processed using high power ultrasound-assisted sol-gel synthesis followed by pyrolysis. The intensive sonication enhances gelation and drying process, improving the homogenous distribution of the graphitic flakes in the preceramic blends. The physicochemical investigation of SiOC/graphite composites using X-ray diffraction, 29Si solid state NMR and Raman spectroscopy indicated no reaction occurring between the components. The electrochemical measurements revealed enhanced capacity (by up to 63%) at high current rates (1.86 A g−1) recorded for SiOC/graphite composite compared to the pure components. Moreover, the addition of graphite to the SiOC matrix decreased the value of delithiation potential, which is a desirable feature for anodes in LIC.

Author(s):  
Yabin An ◽  
Tengyu Liu ◽  
Chen Li ◽  
Xiong Zhang ◽  
Tao Hu ◽  
...  

As a promising energy storage system, lithium-ion capacitor (LIC) shows tremendous potential for energy storage devices with high energy density and power density. However, limited by the poor rate performance...


Materials ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3191
Author(s):  
Shunji Nakata

The charging efficiency of a lithium-ion capacitor (LIC) is an important problem. Until now, due to the stepwise charging method, the charging efficiency of 95.5% has been realized. However, the problem is that the issue of what level the charging efficiency can be increased to, is yet to be well investigated. In this article, the problem is investigated under the galvanostatic charging condition. The charging efficiency is measured as a function of the charging current. As a result, it can be more than 99.5% when the charging is quasi-static, in other words, an adiabatic process is realized. Next, the problem of how much energy can be taken out from the energy-stored capacitor is investigated with a load resistor circuit. It is clarified that the discharging energy from the capacitor is equal to the stored energy in the case when a load resistor is used and the discharging is quasi-static. It is confirmed that LICs are suitable for use as energy storage devices.


Nano Letters ◽  
2011 ◽  
Vol 11 (9) ◽  
pp. 3785-3791 ◽  
Author(s):  
Bor Z. Jang ◽  
Chenguang Liu ◽  
David Neff ◽  
Zhenning Yu ◽  
Ming C. Wang ◽  
...  

Author(s):  
Dhanasekar Kesavan ◽  
Vimal Kumar Mariappan ◽  
Karthikeyan Krishnamoorthy ◽  
Sang-Jae Kim

In this study, we report a facile carbothermal method for the preparation of boron-oxy-carbide (BOC) nanostructures and explore their properties towards electrochemical energy storage devices.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4000
Author(s):  
Eunhwan Kim ◽  
Juyeon Han ◽  
Seokgyu Ryu ◽  
Youngkyu Choi ◽  
Jeeyoung Yoo

For decades, improvements in electrolytes and electrodes have driven the development of electrochemical energy storage devices. Generally, electrodes and electrolytes should not be developed separately due to the importance of the interaction at their interface. The energy storage ability and safety of energy storage devices are in fact determined by the arrangement of ions and electrons between the electrode and the electrolyte. In this paper, the physicochemical and electrochemical properties of lithium-ion batteries and supercapacitors using ionic liquids (ILs) as an electrolyte are reviewed. Additionally, the energy storage device ILs developed over the last decade are introduced.


Author(s):  
Yunping Wu ◽  
Wei Wei ◽  
Tianyi Ding ◽  
Sheng Chen ◽  
Rui Zhai ◽  
...  

Two-dimensional (2D) heterostructures combine the advantageous features of different 2D materials and represent advanced electrode architectures for development of efficient energy storage devices. However, the common 2D heterostructures made by...


Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3586
Author(s):  
Qi An ◽  
Xingru Zhao ◽  
Shuangfu Suo ◽  
Yuzhu Bai

Lithium-ion capacitors (LICs) have been widely explored for energy storage. Nevertheless, achieving good energy density, satisfactory power density, and stable cycle life is still challenging. For this study, we fabricated a novel LIC with a NiO-rGO composite as a negative material and commercial activated carbon (AC) as a positive material for energy storage. The NiO-rGO//AC system utilizes NiO nanoparticles uniformly distributed in rGO to achieve a high specific capacity (with a current density of 0.5 A g−1 and a charge capacity of 945.8 mA h g−1) and uses AC to provide a large specific surface area and adjustable pore structure, thereby achieving excellent electrochemical performance. In detail, the NiO-rGO//AC system (with a mass ratio of 1:3) can achieve a high energy density (98.15 W h kg−1), a high power density (10.94 kW kg−1), and a long cycle life (with 72.1% capacity retention after 10,000 cycles). This study outlines a new option for the manufacture of LIC devices that feature both high energy and high power densities.


Physchem ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 26-44
Author(s):  
Chiara Ferrara ◽  
Riccardo Ruffo ◽  
Piercarlo Mustarelli

Extended interphases are playing an increasingly important role in electrochemical energy storage devices and, in particular, in lithium-ion and lithium metal batteries. With this in mind we initially address the differences between the concepts of interface and interphase. After that, we discuss in detail the mechanisms of solid electrolyte interphase (SEI) formation in Li-ion batteries. Then, we analyze the methods for interphase characterization, with emphasis put on in-situ and operando approaches. Finally, we look at the near future by addressing the issues underlying the lithium metal/electrolyte interface, and the emerging role played by the cathode electrolyte interphase when high voltage materials are employed.


RSC Advances ◽  
2019 ◽  
Vol 9 (60) ◽  
pp. 35045-35049
Author(s):  
Xu Chen ◽  
Jian Zhou ◽  
Jiarui Li ◽  
Haiyan Luo ◽  
Lin Mei ◽  
...  

High-performance lithium ion batteries are ideal energy storage devices for both grid-scale and large-scale applications.


Author(s):  
Nilimapriyadarsini Swain ◽  
Saravanakumar Balasubramaniam ◽  
Manab Kundu ◽  
Lukas Schmidt-Mende ◽  
Ananthakumar Ramadoss

Supercapacitors have emerged as an outstanding candidate among numerous energy storage devices because of their long-term cycle life, high power density, and minimal safety concerns. As we know, the lower...


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