scholarly journals Tribological and Dynamical Mechanical Behavior of Prototyped PLA-Based Polymers

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3615
Author(s):  
Dumitru Nedelcu ◽  
Simona-Nicoleta Mazurchevici ◽  
Ramona-Iuliana Popa ◽  
Nicoleta-Monica Lohan ◽  
Demófilo Maldonado-Cortés ◽  
...  
Keyword(s):  
Fused Deposition Modeling ◽  
Bending Strength ◽  
Base Material ◽  
Biodegradable Materials ◽  
Human Society ◽  
Technological Parameters ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Fused Deposition ◽  
3D Printed

It is essential to combine current state-of-the-art technologies such as additive manufacturing with current ecological needs. Due to the increasing demand for non-toxic biodegradable materials and products, human society has been searching for new materials. Consequently, it is compulsory to identify the qualities of these materials and their behavior when subjected to various external factors, to find their optimal solutions for application in various fields. This paper refers to the biodegradable Polylactic acid (PLA)-based filament (commercially known as Extrudr BDP (Biodegradable Plastic) Flax) compared with the biodegradable composite material PLA-lignin filament whose constituent’s trade name is Arboblend V2 Nature as a lignin base material and reinforcement with Extrudr BDP Pearl, a PLA based polymer, 3D printed by Fused Deposition Modeling technology. Certain mechanical properties (tensile strength, bending strength and DMA—Dynamic Mechanical Analysis) were also determined. The tribology behavior (friction coefficient and wear), the structure and the chemical composition of the biodegradable materials were investigated by SEM—Scanning Electron Microscopy, EDX—Energy Dispersive X-Ray Analysis, XRD—X-Ray Diffraction Analysis, FTIR—Fourier Transform Infrared Spectrometer and TGA—Thermogravimetric Analysis. The paper also refers to the influence of technological parameters on the 3D printed filaments made of Extrudr BDP Flax and the optimization those of technological parameters. The thermal behavior during the heating of the sample was analyzed by Differential scanning calorimetry (DSC). As a result of the carried-out research, we intend to recommend these biodegradable materials as possible substituents for plastics in as many fields of activity as possible.

Development of three-dimensional printing filaments based on poly(lactic acid)/hydroxyapatite composites with potential for tissue engineering

2021 ◽  
pp. 002199832098856
Author(s):  
Marcela Piassi Bernardo ◽  
Bruna Cristina Rodrigues da Silva ◽  
Luiz Henrique Capparelli Mattoso
Keyword(s):  
Tissue Engineering ◽  
Lactic Acid ◽  
Fused Deposition Modeling ◽  
Three Dimensional ◽  
Poly Lactic Acid ◽  
Scanning Calorimetry ◽  
Three Dimensional Printing ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
3D Printed

Injured bone tissues can be healed with scaffolds, which could be manufactured using the fused deposition modeling (FDM) strategy. Poly(lactic acid) (PLA) is one of the most biocompatible polymers suitable for FDM, while hydroxyapatite (HA) could improve the bioactivity of scaffold due to its chemical composition. Therefore, the combination of PLA/HA can create composite filaments adequate for FDM and with high osteoconductive and osteointegration potentials. In this work, we proposed a different approache to improve the potential bioactivity of 3D printed scaffolds for bone tissue engineering by increasing the HA loading (20-30%) in the PLA composite filaments. Two routes were investigated regarding the use of solvents in the filament production. To assess the suitability of the FDM-3D printing process, and the influence of the HA content on the polymer matrix, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) were performed. The HA phase content of the composite filaments agreed with the initial composite proportions. The wettability of the 3D printed scaffolds was also increased. It was shown a greener route for obtaining composite filaments that generate scaffolds with properties similar to those obtained by the solvent casting, with high HA content and great potential to be used as a bone graft.

scholarly journals Effect of Porosity on Mechanical Properties of 3D Printed Polymers: Experiments and Micromechanical Modeling Based on X-Ray Computed Tomography Analysis

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1154 ◽  
Author(s):  
Wang ◽  
Zhao ◽  
Fuh ◽  
Lee
Keyword(s):  
Computed Tomography ◽  
Mechanical Properties ◽  
Additive Manufacturing ◽  
Fused Deposition Modeling ◽  
Micromechanical Model ◽  
Micromechanical Modeling ◽  
X Ray ◽  
Fused Deposition ◽  
3D Printed ◽  
X Ray Computed

Additive manufacturing (commonly known as 3D printing) is defined as a family of technologies that deposit and consolidate materials to create a 3D object as opposed to subtractive manufacturing methodologies. Fused deposition modeling (FDM), one of the most popular additive manufacturing techniques, has demonstrated extensive applications in various industries such as medical prosthetics, automotive, and aeronautics. As a thermal process, FDM may introduce internal voids and pores into the fabricated thermoplastics, giving rise to potential reduction on the mechanical properties. This paper aims to investigate the effects of the microscopic pores on the mechanical properties of material fabricated by the FDM process via experiments and micromechanical modeling. More specifically, the three-dimensional microscopic details of the internal pores, such as size, shape, density, and spatial location were quantitatively characterized by X-ray computed tomography (XCT) and, subsequently, experiments were conducted to characterize the mechanical properties of the material. Based on the microscopic details of the pores characterized by XCT, a micromechanical model was proposed to predict the mechanical properties of the material as a function of the porosity (ratio of total volume of the pores over total volume of the material). The prediction results of the mechanical properties were found to be in agreement with the experimental data as well as the existing works. The proposed micromechanical model allows the future designers to predict the elastic properties of the 3D printed material based on the porosity from XCT results. This provides a possibility of saving the experimental cost on destructive testing.

scholarly journals Charaterizations of 3D printed re-entrant pattern/aramid knit composite prepared by various tilting angles

2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Imjoo Jung ◽  
Hyelim Kim ◽  
Sunhee Lee
Keyword(s):  
Tensile Properties ◽  
Poisson’S Ratio ◽  
Fused Deposition Modeling ◽  
Bending Strength ◽  
Thermoplastic Polyurethane ◽  
Poisson's Ratio ◽  
Fused Deposition ◽  
Initial Modulus ◽  
3D Printed ◽  
Composite Fabrics

AbstractThis study intended to compare and analyze the Poisson's ratio and mechanical properties of aramid knit (ARNT), 3D printed auxetic re-entrant pattern (3DP-RE), and 2 types of composite fabrics manufactured with ARNT and 3DP-RE. Specimens were manufactured by 3D printing the re-entrant pattern with a CFDM (conveyor fused deposition modeling) 3D printer and TPU (thermoplastic polyurethane) filament, combining with aramid knit in 2 ways. Then, Poisson's ratio, bending, compression, and tensile properties were tested. As a result of Poisson's ratio, 3DP-RE and its 2 types of composite fabric showed negative Poisson's ratio at all angles and deformed stable at 0° and 90° than the bias direction. The bending strength confirmed that the composite fabric showed a lower value. But, the strain at max bending strength was greater than a substrate fabric. At the compression properties, it has been confirmed that compression strength and toughness are improved when manufacturing composite fabrics. As a result of tensile properties, 3DP-RE and composite fabrics were significantly more initial modulus, elongation and toughness than ARNT and were shown to be the largest in gradient 90°. Therefore, it is confirmed that the performance is excellent when fabricated as a 3DP-RE/ARNT composite fabric, and based on the results of studies, we intend to use it as the basic data for composite fabrics of auxetic structure suitable for shoe uppers.

Effect of heat treatment on crystallinity and mechanical properties of flexible structures 3D printed with fused deposition modeling

2021 ◽  
pp. 152808372110649
Author(s):  
Ajay Jayswal ◽  
Sabit Adanur
Keyword(s):  
Heat Treatment ◽  
Tensile Strength ◽  
Ultimate Tensile Strength ◽  
Fused Deposition Modeling ◽  
Scanning Calorimetry ◽  
Fused Deposition ◽  
Dog Bone ◽  
Heat Treated ◽  
Deposition Modeling ◽  
3D Printed

Fused Deposition Modeling (FDM) is a widely used 3D printing technique, which works based on the principle of melted polymer extrusion through nozzle(s) and depositing them on a build plate layer by layer. However, products manufactured with this method lack proper mechanical strength. In this work, 2/1 twill weave fabric structures are 3D printed using poly (lactic) acid (PLA). The ultimate tensile strength in the warp and weft directions and the modulus (stiffnesses) are measured for non-heat-treated (NHT) samples. The printed samples were heat-treated (HT) to improve the strength and stiffness. The variation in ultimate tensile strength is statistically insignificant in warp direction at all temperatures; however, the tensile strength in weft direction decreased after heat treatment. The modulus in warp direction increased by 31% after heat treatment while in the weft direction it decreased after heat treatment. Differential scanning calorimetry (DSC) tests showed the highest crystallinity at 125°C. The properties of the twill fabrics were compared with a standard dog-bone (DB) specimen using uniaxial tensile tests, Differential scanning calorimetry tests, and optical microscope (OM). For dog-bone specimens, the maximum values of crystallinity, ultimate tensile strength, and modulus were found to be at 125°C. The maximum crystallinity percentages are higher than that of the NHT samples. The ultimate tensile strength of NHT DB specimen 3D printed in horizontal orientation improved after heat treatment. The ultimate tensile strength of DB samples in vertical directions increased after heat treatment as well. The stiffness increased in both directions for DB samples.

Silane-Treated Muscovite as Reinforcement for 3D-Printed ABS via Fused Deposition Modeling

2021 ◽  
Vol 877 ◽  
pp. 67-72
Author(s):  
Niño B. Felices ◽  
Bryan B. Pajarito
Keyword(s):  
Thermal Properties ◽  
Fused Deposition Modeling ◽  
Acrylonitrile Butadiene Styrene ◽  
Mechanical And Thermal Properties ◽  
Scanning Calorimetry ◽  
Mechanical Reinforcement ◽  
Fused Deposition ◽  
The Matrix ◽  
Deposition Modeling ◽  
3D Printed

Epoxysilane-treated muscovite (ETM) was used as reinforcing filler to 3D-printed acrylonitrile butadiene styrene (ABS) via fused deposition modeling (FDM). Its effects to the mechanical and thermal properties of ABS were investigated. ETM was loaded at 1, 3, and 5wt%. ABS/ETM composites were characterized via scanning electron microscopy (SEM), tensile test, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Mechanical reinforcement of ABS was observed for ABS/ETM composites loaded at 1 and 3 wt% wherein it was noted that the tensile strength and elastic modulus increased by up to 83.6% and 76.6%, respectively. Reinforcement was brought by interfacial adhesion of ETM with the ABS matrix. There was a sharp decline in mechanical properties for ABS/ETM composites loaded at 5wt% due to agglomeration of ETM in the matrix and discontinuities in the printed layers. The glass transition temperature (Tg) of ABS increased and the onset of its degradation shifted towards higher temperatures with the addition of ETM. It can be concluded that the addition of ETM to ABS for FDM 3D printing improved its mechanical and thermal properties.

Influence of nozzle temperature and volumetric filling on the mechanical properties of 3D-printed PEEK

2020 ◽  
Vol 62 (4) ◽  
pp. 351-356
Author(s):  
Danny Vogel ◽  
Volker Weißmann ◽  
Leo Rührmund ◽  
Harald Hansmann ◽  
Rainer Bader
Keyword(s):  
Mechanical Properties ◽  
Fused Deposition Modeling ◽  
Bending Strength ◽  
Layer By Layer ◽  
Bending Properties ◽  
Filling Degree ◽  
Fused Deposition ◽  
3D Printed ◽  
Injection Molded ◽  
Nozzle Temperature

Abstract Fused deposition modeling is a layer-by-layer 3D printing technology used to additively manufacture polymers. A major benefit of 3D-printed polymers is the option of tailoring their mechanical properties by varying the process parameters. In addition, the present study investigates the influence of the filling degree (50 % or 100 %) and the nozzle temperature during manufacturing on the mechanical properties of 3D-printed poly-ether-ether-ketone (PEEK) material. PEEK samples were built either compact (filling degree 100 %) or closed-cell porous (filling degree 50 %), using three different nozzle temperatures (390 °C, 430 °C and 470 °C). In static bending tests, the bending properties were evaluated and compared with injection molded PEEK samples. Bending strength and modulus increased up to 21.1 %, when the nozzle temperature was increased and up to 40.8 % when the volumetric filling was altered. The results indicate that nozzle temperature and volumetric filling can be altered to tailor the bending properties of 3D-printed PEEK for particular applications. However, the mechanical properties of the 3D-printed samples determined in the current study could not achieve those of the properties of the injection molded PEEK.

Characterization of PLA/TPU composite filaments manufactured for 3D printing with FDM

2021 ◽  
pp. 089270572110625
Author(s):  
Ajay Jayswal ◽  
Sabit Adanur
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Thermoplastic Polyurethane ◽  
Tensile Tests ◽  
Optical Microscope ◽  
Mechanical Analysis ◽  
Uniaxial Tensile ◽  
Scanning Calorimetry ◽  
Fused Deposition ◽  
3D Printed

Polylactic acid (PLA) and thermoplastic polyurethane (TPU) were mixed in different proportions and extruded through twin-screw and single-screw extruders to obtain composite filaments to be used for 3D printing with fused deposition modeling (FDM) method. The properties of the filaments were characterized using uniaxial tensile tests, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), rheology, polarized optical microscope (POM), and scanning electron microscope (SEM). 3D printed samples from composite filaments were tested using dynamic mechanical analysis (DMA). It was found that the tensile strength and modulus of the filaments decrease while elongation at break increases with the increasing TPU content in the composite. The analysis also showed a partial miscibility of the polymer constituents in the solution of composite filaments. Finally, a flexible structure, plain weave fabric, was designed and 3D printed using the composite filaments developed which proved that the filaments are well suited for 3D printing.

scholarly journals Bioactive Potential of 3D-Printed Oleo-Gum-Resin Disks:B. papyrifera,C. myrrha, andS. benzoinLoading Nanooxides—TiO2, P25, Cu2O, and MoO3

2017 ◽  
Vol 2017 ◽  
pp. 1-16 ◽  
Author(s):  
Diogo José Horst ◽  
Sergio Mazurek Tebcherani ◽  
Evaldo Toniolo Kubaski ◽  
Rogério de Almeida Vieira
Keyword(s):  
Pure State ◽  
Fused Deposition Modeling ◽  
Metal Oxide Nanoparticles ◽  
Scanning Calorimetry ◽  
Fused Deposition ◽  
Deposition Modeling ◽  
Microscopy Analysis ◽  
3D Printed ◽  
Bioactive Potential ◽  
Hot Melt

This experimental study investigates the bioactive potential of filaments produced via hot melt extrusion (HME) and intended for fused deposition modeling (FDM) 3D printing purposes. The oleo-gum-resins from benzoin, myrrha, and olibanum in pure state and also charged with 10% of metal oxide nanoparticles, TiO2, P25, Cu2O, and MoO3, were characterized by ultraviolet-visible (UV-Vis) and Fourier transform infrared (FTIR) spectroscopy, energy-dispersive X-ray microanalysis (EDXMA), scanning electron microscopy (SEM), and differential scanning calorimetry (DSC). Disks were 3D-printed into model geometries (10 × 5 mm) and the disk-diffusion methodology was used for the evaluation of antimicrobial and antifungal activity of materials in study against the clinical isolates:Staphylococcus aureus, Pseudomonas aeruginosa, Escherichia coli, andCandida albicans. Due to their intrinsic properties, disks containing resins in pure state mostly prevent surface-associated growth; meanwhile, disks loaded with 10% oxides prevent planktonic growth of microorganisms in the susceptibility assay. The microscopy analysis showed that part of nanoparticles was encapsulated by the biopolymeric matrix of resins, in most cases remaining disorderly dispersed over the surface of resins. Thermal analysis shows that plant resins have peculiar characteristics, with a thermal behavior similar to commercial available semicrystalline polymers, although their structure consists of a mix of organic compounds.

Effect of Silane-Treated Wollastonite on Mechanical and Thermal Properties of 3D-Printed ABS via Fused Deposition Modeling

2021 ◽  
Vol 877 ◽  
pp. 61-66
Author(s):  
Niño B. Felices ◽  
Bryan B. Pajarito
Keyword(s):  
Thermal Properties ◽  
Fused Deposition Modeling ◽  
Acrylonitrile Butadiene Styrene ◽  
Filler Loading ◽  
Mechanical And Thermal Properties ◽  
Scanning Calorimetry ◽  
Fused Deposition ◽  
Uniform Dispersion ◽  
Deposition Modeling ◽  
3D Printed

The effect of the addition of epoxysilane-treated wollastonite (ETW) to the mechanical and thermal properties of 3D-printed acrylonitrile butadiene styrene (ABS) via fused deposition modeling (FDM) was investigated. The loading of ETW was varied at 1, 3, and 5wt%. The 3D-printed composites were evaluated by scanning electron microscopy (SEM) tensile test, shore D hardness, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The addition of ETW increases the tensile strength, elastic modulus, and toughness of ABS by up to 46.6, 56.2, and 53.7 %, respectively. The shore D hardness increases with increasing ETW. Morphological analysis show that this improvement in mechanical properties is a result of the high aspect ratio of the fillers, the uniform dispersion of ETW in the ABS matrix, and the orientation of ETW particles toward the direction of tensile stress. The glass transition temperature (Tg) of the composites increases and the onset of degradation slightly shifted to higher temperature with an increase in filler loading. The addition of ETW to ABS matrix in FDM 3D printing improved the mechanical and thermal properties of ABS.

Analysis of Correlation Between Contrast and Component of Polylatic Acid Composite for Fused Deposition Modeling 3D Printing

2020 ◽  
Vol 20 (8) ◽  
pp. 5107-5111
Author(s):  
Kyu-Hyon Son ◽  
Jung-Hun Kim ◽  
Dong-Eun Kim ◽  
Min-Sik Kang ◽  
Joo-Heon Song ◽  
...  
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Three Dimensional ◽  
Disruptive Technology ◽  
X Ray ◽  
Fused Deposition ◽  
Potential Applicability ◽  
Deposition Modeling ◽  
3D Printed ◽  
Cie Lab

Additive manufacturing or three-dimensional (3D) printing is considered a disruptive technology for producing components with topologically optimized complex geometries as well as functionalities that are not achievable by traditional methods. 3D printing is expected to revolutionize the manufacturing of components. While several 3D printing systems are available, printing based on fused-deposition modeling (FDM) using thermoplastics is particularly widespread because of the simplicity and potential applicability of the method. In this study, we report the analysis of correlation between contrast and component of polylactic acid (PLA) based composite for FDM 3D printing. The pre-fabricated white composite and black composite were mixed in the fraction of 100:0, 90:10, 75:25, 50:50, 25:75, and 0:100% (v/v) and the obtained mixture was extruded using HX-35 3D filament extrusion line. The samples in different contrast were printed in disk like shape, and the gray scale filaments and 3D printed samples were measured the morphology and components using a field emission scanning electron microscope and energy dispersive X-ray spectroscopy. The CIE-lab values of the samples were measured using a colorimeter and the correlation between CIE-lab values and the components were analyzed. Although the component of Ti was linearly increased, the CIE-lab values show a clear exponential increase by increasing the white composite.

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