scholarly journals Upgrading Sustainable Polyurethane Foam Based on Greener Polyols: Succinic-Based Polyol and Mannich-Based Polyol

Materials ◽  
2020 ◽  
Vol 13 (14) ◽  
pp. 3170 ◽  
Author(s):  
Ferdinando de Luca Bossa ◽  
Letizia Verdolotti ◽  
Vincenzo Russo ◽  
Pietro Campaner ◽  
Andrea Minigher ◽  
...  
Keyword(s):  
Renewable Resources ◽  
Raw Materials ◽  
Morphological Structure ◽  
Synthetic Polymers ◽  
Polyurethane Foams ◽  
Partial Replacement ◽  
Gravimetric Analysis ◽  
Degradation Behavior ◽  
Thermal Degradation Behavior ◽  
Suitable Amount

It is well known that the traditional synthetic polymers, such as Polyurethane foams, require raw materials that are not fully sustainable and are based on oil-feedstocks. For this reason, renewable resources such as biomass, polysaccharides and proteins are still recognized as one of the most promising approaches for substituting oil-based raw materials (mainly polyols). However, polyurethanes from renewable sources exhibit poor physical and functional performances. For this reason, the best technological solution is the production of polyurethane materials obtained through a partial replacement of the oil-based polyurethane precursors. This approach enables a good balance between the need to improve the sustainability of the polymer and the need to achieve suitable performances, to fulfill the technological requirements for specific applications. In this paper, a succinic-based polyol sample (obtained from biomass source) was synthesized, characterized and blended with cardanol-based polyol (Mannich-based polyol) to produce sustainable rigid polyurethane foams in which the oil-based polyol is totally replaced. A suitable amount of catalysts and surfactant, water as blowing reagent and poly-methylene diphenyl di-isocyanate as isocyanate source were used for the polyurethane synthesis. The resulting foams were characterized by means of infrared spectroscopy (FTIR) to control the cross-linking reactions, scanning electron microscopy (SEM) to evaluate the morphological structure and thermal gravimetric analysis (TGA) and thermal conductivity to evaluate thermal degradation behavior and thermal insulation properties.

Furan-based polyesters from renewable resources: Crystallization and thermal degradation behavior of poly(hexamethylene 2,5-furan-dicarboxylate)

2015 ◽  
Vol 67 ◽  
pp. 383-396 ◽  
Author(s):  
George Z. Papageorgiou ◽  
Vasilios Tsanaktsis ◽  
Dimitrios G. Papageorgiou ◽  
Konstantinos Chrissafis ◽  
Stylianos Exarhopoulos ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Renewable Resources ◽  
Degradation Behavior ◽  
Thermal Degradation Behavior

Thermal degradation behavior of rigid polyurethane foams prepared with different fire retardant concentrations and blowing agents

Polymer ◽  
2002 ◽  
Vol 43 (24) ◽  
pp. 6471-6479 ◽  
Author(s):  
Zhong Tang ◽  
M.Mercedes Maroto-Valer ◽  
John M Andrésen ◽  
John W Miller ◽  
Mark L Listemann ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Fire Retardant ◽  
Polyurethane Foams ◽  
Degradation Behavior ◽  
Rigid Polyurethane Foams ◽  
Blowing Agents ◽  
Thermal Degradation Behavior

scholarly journals Greener Nanocomposite Polyurethane Foam Based on Sustainable Polyol and Natural Fillers: Investigation of Chemico-Physical and Mechanical Properties

Materials ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 211 ◽  
Author(s):  
Ferdinando De Luca Bossa ◽  
Chiara Santillo ◽  
Letizia Verdolotti ◽  
Pietro Campaner ◽  
Andrea Minigher ◽  
...  
Keyword(s):  
Environmental Sustainability ◽  
Raw Materials ◽  
Physical And Mechanical Properties ◽  
Polyurethane Foams ◽  
Walnut Shell ◽  
Blowing Agent ◽  
Suitable Amount ◽  
Pu Foams ◽  
Natural Fillers ◽  
Mannich Polyol

Nowadays, the chemical industry is looking for sustainable chemicals to synthesize nanocomposite bio-based polyurethane foams, PUs, with the aim to replace the conventional petrochemical precursors. Some possibilities to increase the environmental sustainability in the synthesis of nanocomposite PUs include the use of chemicals and additives derived from renewable sources (such as vegetable oils or biomass wastes), which comprise increasingly wider base raw materials. Generally, sustainable PUs exhibit chemico-physical, mechanical and functional properties, which are not comparable with those of PUs produced from petrochemical precursors. In order to enhance the performances, as well as the bio-based aspect, the addition in the polyurethane formulation of renewable or natural fillers can be considered. Among these, walnut shells and cellulose are very popular wood-based waste, and due to their chemical composition, carbohydrate, protein and/or fatty acid, can be used as reactive fillers in the synthesis of Pus. Diatomite, as a natural inorganic nanoporous filler, can also be evaluated to improve mechanical and thermal insulation properties of rigid PUs. In this respect, sustainable nanocomposite rigid PU foams are synthesized by using a cardanol-based Mannich polyol, MDI (Methylene diphenyl isocyanate) as an isocyanate source, catalysts and surfactant to regulate the polymerization and blowing reactions, H2O as a sustainable blowing agent and a suitable amount (5 wt%) of ultramilled walnut shell, cellulose and diatomite as filler. The effect of these fillers on the chemico-physical, morphological, mechanical and functional performances on PU foams has been analyzed.

scholarly journals Greener Nanocomposite Polyurethane Foam Based on Sustainable Polyol and Natural Fillers: Investigation of Chemico-Physical and Mechanical Properties

2019 ◽  
Author(s):  
Ferdinando De Luca Bossa ◽  
Chiara Santillo ◽  
Letizia Verdolotti ◽  
Pietro Campaner ◽  
Andrea Minigher ◽  
...  
Keyword(s):  
Environmental Sustainability ◽  
Raw Materials ◽  
Physical And Mechanical Properties ◽  
Polyurethane Foams ◽  
Walnut Shell ◽  
Blowing Agent ◽  
Suitable Amount ◽  
Pu Foams ◽  
Natural Fillers ◽  
Mannich Polyol

Nowadays, the chemical industry is looking for sustainable chemicals to synthesize nanocomposite bio-based polyurethane foams, PUs, with the aim to replace the conventional petrochemical precursors. Some possibilities to increase the environmental sustainability in the synthesis of nanocomposite PUs include the use of chemicals and additives derived from renewable sources (such as vegetable oils or biomass wastes) which comprise an increasing wider base raw materials. Generally, sustainable PUs exhibit chemico-physical, mechanical and functional properties which are not comparable with those of PUs produced from petrochemical precursors. In order to enhance the performances as well as the bio-based aspect, the addition in the polyurethane formulation of renewable or natural fillers can be considered. Among these, walnut shells and cellulose are very popular wood-based waste and due to their chemical composition, carbohydrate, protein and/or fatty acid, can be used as reactive fillers in the synthesis of PUs, diatomite as natural inorganic nanoporous filler can be also evaluated to improve mechanical and thermal insulation properties of rigid PUs. In this respect, sustainable nanocomposite rigid PU foams are synthesized by using a cardanol-based Mannich polyol, MDI as isocyanate source, catalysts and surfactant to regulate the polymerization and blowing reactions, H2O as sustainable blowing agent and suitable amount (5wt%) of ultramilled walnut shell, cellulose and diatomite as filler. The effect of these fillers on the chemico-physical, morphological, mechanical and functional performances on PU foams has been analyzed.

scholarly journals Polyurethane Composite Foams Synthesized Using Bio-Polyols and Cellulose Filler

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3474
Author(s):  
Katarzyna Uram ◽  
Milena Leszczyńska ◽  
Aleksander Prociak ◽  
Anna Czajka ◽  
Michał Gloc ◽  
...  
Keyword(s):  
Cross Sections ◽  
Raw Materials ◽  
Polyurethane Foams ◽  
Degree Of Crystallinity ◽  
X Ray Diffraction ◽  
Polyurethane Composite ◽  
Composite Foams ◽  
Closed Cell ◽  
Ft Ir ◽  
The Fourier Transform

Rigid polyurethane foams were obtained using two types of renewable raw materials: bio-polyols and a cellulose filler (ARBOCEL® P 4000 X, JRS Rettenmaier, Rosenberg, Germany). A polyurethane system containing 40 wt.% of rapeseed oil-based polyols was modified with the cellulose filler in amounts of 1, 2, and 3 php (per hundred polyols). The cellulose was incorporated into the polyol premix as filler dispersion in a petrochemical polyol made using calenders. The cellulose filler was examined in terms of the degree of crystallinity using the powder X-ray diffraction PXRD -and the presence of bonds by means of the fourier transform infrared spectroscopy FT-IR. It was found that the addition of the cellulose filler increased the number of cells in the foams in both cross-sections—parallel and perpendicular to the direction of the foam growth—while reducing the sizes of those cells. Additionally, the foams had closed cell contents of more than 90% and initial thermal conductivity coefficients of 24.8 mW/m∙K. The insulation materials were dimensionally stable, especially at temperatures close to 0 °C, which qualifies them for use as insulation at low temperatures.

scholarly journals Alkali-Hydrothermal Treatment of K-Rich Igneous Rocks for Their Direct Use as Potassic Fertilizers

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 140
Author(s):  
Aaron Mbissik ◽  
Abdellatif Elghali ◽  
Muhammad Ouabid ◽  
Otmane Raji ◽  
Jean-Louis Bodinier ◽  
...  
Keyword(s):  
Hydrothermal Treatment ◽  
Inductively Coupled Plasma ◽  
Structural Changes ◽  
Raw Materials ◽  
Hydrothermal Process ◽  
Atomic Emission ◽  
Igneous Rocks ◽  
Gravimetric Analysis ◽  
African Countries ◽  
Naoh Solution

Due to the increasing demand for conventional sources of potassium (K) and their inaccessibility by African countries, K-rich igneous rocks are increasingly studied as potential alternative sources. In this study, six potassic igneous rocks (syenites and trachytes) from the Tamazeght, Jbel Boho, Ait Saoun, and El Glo’a regions (Morocco) were sampled and characterized. Then they were hydrothermally treated to enhance their K release for potential use as potassic fertilizers. The raw materials are mainly formed by microcline (up to 74%), orthoclase (20–68%), albite (36–57%), biotite-muscovite (15–23%), and titanite, calcite, hematite, and apatite as accessory minerals. These samples were crushed and milled to reach a particle size <150 µm and mixed with 4 N NaOH solution in an autoclave. The liquid/solid (L/S) ratio was about 44 mL/50 g. The powders were allowed to react with the solution at 170 °C for 7 h. For all tests, NaOH reacted completely with the powders and no liquid was observed after the treatment. X-ray diffraction (XRD), thermal gravimetric analysis (TGA), infrared spectroscopy (IRTF), and scanning electron microscopy (SEM-EDS) were carried out on treated samples to characterize the mineralogical and structural changes due to the alkali-hydrothermal treatment. Indeed, the treated samples revealed the presence of sodic neoformed phases such as thermonatrite, sodalite, analcime, and cancrinite. The treated material was leached for a week using deionized water and the elements released were measured using inductively coupled plasma–atomic emission spectroscopy (ICP-AES). The hydrothermal process showed a strong effect on structure breakdown as well as on the release of K and other nutrients such as P, Fe, Si, Mg, and Ca. Therefore, the alkali-hydrothermal treatment allowed the release of 50.5 wt% K. Moreover, the release of Mg, Ca, Fe, P, K, and Si were significantly increased. Mg, Ca, Fe, P, K, and Si release within raw materials was about (0.5–3.6), (3.5–31.4), (0.01–0.4), (0.01–0.3), (20–55), and (4.6–8) mg/kg, respectively, whereas treated samples showed a higher release of these elements. Quantitatively, Mg, Ca, Fe, P, K, and Si releases were about (10–11.8), (60–70), (7–20), (1.2–15), (218–1278), and (1119–2759) mg/kg, respectively. Consequently, the treated igneous rocks (syenite and trachyte) could be directly used as potassic fertilizers that would also be a source of other nutrients.

Natural Polymers for Biodegradable Dressings to Save the Environment

2021 ◽  
Vol 6 (2) ◽  
Keyword(s):  
Greenhouse Gas Emissions ◽  
Greenhouse Gas ◽  
Renewable Resources ◽  
Raw Materials ◽  
Current System ◽  
Future Generations ◽  
Natural Polymers ◽  
Surgical Masks ◽  
By Products ◽  
Global Water

The current fashion system uses high volumes of non-renewable resources to produce clothes, being responsible for 10% of the global greenhouse gas emissions into the atmosphere every year and 20%of the global water wasted. At the same time people are buying 60%more clothing than 15 Years ago, which going in the landfills, causes 92 million tons of waste each year. This waste has been further increased by the surgical masks used for COVID-19 pandemic. Thus, a new way of designing and producing clothing needs to be incorporated into the current system to facilitate its recycling making it more circular. New tissues, therefore, are proposed made by natural polysaccharides, embedded by micro- Nano capsules of chitin Nano fibrils and Nano lignin all obtained as by- products from food and forestry waste respectively. Thus, pollution and waste will be reduced and the natural raw materials will be maintained for the future generations.

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