scholarly journals Process-Related Changes in Polyetherimide Joined by Friction-Based Injection Clinching Joining (F-ICJ)

Materials ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1027
Author(s):  
André B. Abibe ◽  
Marilia Sônego ◽  
Leonardo B. Canto ◽  
Jorge F. dos Santos ◽  
Sergio T. Amancio-Filho
Keyword(s):  
Mechanical Strength ◽  
Physical Aging ◽  
Mechanical Performance ◽  
Base Material ◽  
Chain Scission ◽  
Size Exclusion ◽  
Lap Shear ◽  
Local Strength ◽  
Exclusion Chromatography ◽  
Static Mechanical

This work presents a comprehensive study on the effects of the Friction-based Injection Clinching Joining (F-ICJ) process on the microstructure and local properties of the stake head. The manuscript evaluates the consequences on the quasi-static mechanical performance of hybrid joints of amorphous polyetherimide (PEI) with aluminium AA6082. Through an overlay of microhardness map on a cross-polarized transmitted-light optical microscopy (CP-TLOM) image, two lower-strength microstructural zones in the PEI stake head were observed: a plastically-deformed zone (PDZ) and a thermo-mechanically-affected zone (PTMAZ). When compared to the base material, PDZ and PTMAZ have a reduction of 12%–16% and 8%–12%, respectively, in local mechanical properties. The reduced local strength was associated with distinct volumes of loosely packed PEI chains with unsteady chain conformation and thus larger free volume in the affected regions. The mechanical strength reduction is reversible through physical aging by thermal annealing the joints, which additionally shows that process-induced thermomechanical degradation of PEI by chain scission, as evidenced by size exclusion chromatography (SEC) analysis, does not appear to affect local mechanical strength. An evaluation of typical loading regimes of staked joints in lap shear (average ultimate force of 1419 ± 43 N) and cross tensile (average ultimate force of 430 ± 44 N) testing indicates that the process-induced changes of PEI do not compromise the global mechanical performance of such a structure. These findings provide a better understanding of the relationships between processing, microstructure, and properties for further F-ICJ process optimization.

scholarly journals Chemical and physical interactions of regenerated cellulose yarns and isocyanate-based matrix systems

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Bernhard Ungerer ◽  
Ulrich Müller ◽  
Antje Potthast ◽  
Enrique Herrero Acero ◽  
Stefan Veigel
Keyword(s):  
Mechanical Performance ◽  
Tensile Force ◽  
Tensile Modulus ◽  
Tensile Tests ◽  
Size Exclusion ◽  
Regenerated Cellulose ◽  
Hydrolytic Cleavage ◽  
Yarn Twist ◽  
Exclusion Chromatography ◽  
Physical And Chemical

AbstractIn the development of structural composites based on regenerated cellulose filaments, the physical and chemical interactions at the fibre-matrix interphase need to be fully understood. In the present study, continuous yarns and filaments of viscose (rayon) were treated with either polymeric diphenylmethane diisocyanate (pMDI) or a pMDI-based hardener for polyurethane resins. The effect of isocyanate treatment on mechanical yarn properties was evaluated in tensile tests. A significant decrease in tensile modulus, tensile force and elongation at break was found for treated samples. As revealed by size exclusion chromatography, isocyanate treatment resulted in a significantly reduced molecular weight of cellulose, presumably owing to hydrolytic cleavage caused by hydrochloric acid occurring as an impurity in pMDI. Yarn twist, fibre moisture content and, most significantly, the chemical composition of the isocyanate matrix were identified as critical process parameters strongly affecting the extent of reduction in mechanical performance. To cope with the problem of degradative reactions an additional step using calcium carbonate to trap hydrogen ions is proposed.

Influence of Filler Amount and Content on the Mechanical Performance of Joints Bonded with Metal Powder Filled Adhesive

2013 ◽  
Vol 773-774 ◽  
pp. 226-233
Author(s):  
Nergizhan Kavak ◽  
Erhan Altan
Keyword(s):  
Surface Roughness ◽  
Mechanical Strength ◽  
Shear Test ◽  
Mechanical Performance ◽  
Bonded Joints ◽  
Aluminium Powder ◽  
Lap Shear ◽  
Lap Shear Test ◽  
Adhesive Bonded Joints ◽  
Single Lap Shear Test

The objective of this study is to investigate the surface roughness that effect the capability of adhesive with adding aluminium powder and 63/37 Sn-Pb soft solder powder to the epoxy to increase the mechanical strength of joints. The adhesive strength of the joints was determined by utilizing the single-lap shear test. As seen from the experiments, the surface roughness has an important effect on the strength of adhesive bonded joints. Experimental results show that joints prepared by adhesive which was modified, adding in the amount of 5 wt% 63/37 Sn-Pb powder have more mechanical strength than joints compared to one which is prepared by adding aluminium powder with different ratios as 5, 25,50 wt%.

scholarly journals The Influence of Clamping Pressure on Joint Formation and Mechanical Performance of Ti6Al4V/CF-PEEK Friction-Riveted Joints

Materials ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 745 ◽  
Author(s):  
Natascha Z. Borba ◽  
Jorge F. dos Santos ◽  
Sergio T. Amancio-Filho
Keyword(s):  
Mechanical Strength ◽  
Friction Force ◽  
Mechanical Performance ◽  
Image Correlation ◽  
Squeezing Flow ◽  
Joint Formation ◽  
Pull Out ◽  
Lap Shear ◽  
Riveted Joints ◽  
Clamping Pressure

This work aims at investigating the influence of pre-set clamping pressure on the joint formation and mechanical strength of overlapping direct-friction-riveted joints. A pneumatic fixture device was developed for this work, with clamping pressure varying from 0.2 MPa to 0.6 MPa. A case study on overlapping joints using Ti6Al4V rivets and woven carbon fiber-reinforced polyether-ether-ketone (CF-PEEK) parts were produced. Digital image correlation and microscopy revealed the expected compressive behavior of the clamping system and the continuous pressure release upon the joining process owing to the rivet plastic deformation and the polymer squeezing flow. Two preferential paths of material flow were identified through the alternate replacement of the upper and lower composite parts by a poly-methyl-methacrylate (PMMA) plate—the composite upward and squeezing flow between the parts which induced their separation. The ultimate lap shear forces up to 6580 ± 383 N were achieved for the direct-friction-riveted CF-PEEK overlap joints. The formation of a gap to accommodate squeezed polymer between the composite parts during the process had no influence on the joint mechanical performance. The increase in the clamping pressure for joints produced with a low friction force did not affect the joint-anchoring efficiency and consequently the joint strength. On the other hand, the combined effect of a high-friction force and clamping pressure induced the inverted bell shape of the plastically deformed rivet tip, a lower anchoring efficiency, and the delamination of the composite, all of which decrease the mechanical strength by 31%. Therefore, the higher the friction force and clamping pressure, the more defects would be generated in the composite parts and the more changes in the shape of the plastically deformed rivet tip, leading to a lower level of quasi-static mechanical performance. All the joints failed by initial bearing of the composite and final rivet pull-out. The findings of this work can contribute to further improvement of the clamping design for industrial application.

scholarly journals Evaluation of Electron Induced Crosslinking of Masticated Natural Rubber at Different Temperatures

Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1279
Author(s):  
Huang ◽  
Gohs ◽  
Müller ◽  
Zschech ◽  
Wießner
Keyword(s):  
Natural Rubber ◽  
Elevated Temperatures ◽  
Sol Gel ◽  
Complex Viscosity ◽  
Chain Scission ◽  
Nitrogen Atmosphere ◽  
Size Exclusion ◽  
Reactive Blending ◽  
Exclusion Chromatography ◽  
Branched Chains

In this work, natural rubber (NR) was masticated using an internal mixer to fit the requirements of reactive blending with polylactide and characterized by size exclusion chromatography (SEC), Fourier-transform infrared (FT-IR) spectroscopy and dynamic rheology measurements. Subsequently, the effect of elevated temperatures (25 °C, 80 °C, and 170 °C) on the electron beam (EB) induced crosslinking and degradation of masticated natural rubber (mNR) in a nitrogen atmosphere without adding crosslinking agents has been investigated. The sol gel investigation showed that the gel dose of mNR slightly increased with increasing irradiation temperature, which is also confirmed by the swelling test. The chain scission to crosslinking ratio (Gs/Gx) was found to be less than 1 for irradiated mNR at 25 °C and 80 °C, suggesting a dominating crosslinking behavior of mNR. However, a significant increase of Gs/Gx ratio (~1.12) was observed for mNR irradiated at 170 °C due to the enhanced thermal degradation behavior at high temperature. A remarkably improved elasticity (higher complex viscosity, higher storage modulus, and longer relaxation time) for EB modified mNR was demonstrated by dynamic rheological analysis. Particularly, the samples modified at higher temperatures represented more pronounced elasticity behavior which resulted from the higher number of branches and/or the longer branched chains.

CHARACTERIZATION OF A NEW LCAT MUTATION CAUSING FAMILIAL LCAT DEFICIENCY (FLD) AND THE ROLE OF APOE AS A MODIFIER GENE OF THE FLD PHENOTYPE

2009 ◽  
Vol 32 (6S) ◽  
pp. 3
Author(s):  
A Baass ◽  
H Wassef ◽  
M Tremblay ◽  
L Bernier ◽  
R Dufour ◽  
...  
Keyword(s):  
Modifier Gene ◽  
Size Exclusion ◽  
Plasma Lipoproteins ◽  
Lipoprotein Profile ◽  
Exclusion Chromatography ◽  
Low Hdl ◽  
Lcat Deficiency ◽  
Apoe Genotypes

Introduction: LCAT (lecithin:cholesterol acyltransferase ) is an enzyme which plays an essential role in cholesterol esterification and reverse cholesterol transport. Familial LCAT deficiency (FLD) is a disease characterized by a defect in LCAT resulting in extremely low HDL-C, premature corneal opacities, anemia as well as proteinuria and renal failure. Method: We have identified two brothers presenting characteristics of familial LCAT deficiency. We sequenced the LCAT gene, measured the lipid profile as well as the LCAT activity in 15 members of this kindred. We also characterized the plasma lipoproteins by agarose gel electrophoresis and size exclusion chromatography and sequenced several candidate genes related to dysbetalipoproteinemia in this family. Results: We have identified the first French Canadian kindred with familial LCAT deficiency. Two brothers affected by FLD, were homozygous for a novel LCAT mutation. This c.102delG mutation occurs at the codon for His35 causing a frameshift that stops transcription at codon 61 abolishing LCAT enzymatic activity both in vivo and in vitro. It has a dramatic effect on the lipoprotein profile, with an important reduction of HDL-C in both heterozygotes (22%) and homozygotes (88%) and a significant decrease in LDL-C in heterozygotes (35%) as well as homozygotes (58%). Furthermore, the lipoprotein profile differed markedly between the two affected brothers who had different APOE genotypes. We propose that APOE could be an important modifier gene explaining heterogeneity in lipoprotein profiles observed among FLD patients. Our results suggest that a LCAT-/- genotype associated with an APOE ?2 allele could be a novel mechanism leading to dysbetalipoproteinemia.

Structure of a shear-thickening polysaccharide extracted from the New Zealand black tree fern, Cyathea medullaris

2020 ◽  
Author(s):  
M Wee ◽  
M Mastrangelo ◽  
Susan Carnachan ◽  
Ian Sims ◽  
K Goh
Keyword(s):  
New Zealand ◽  
Uronic Acid ◽  
Average Molecular Weight ◽  
Shear Thickening ◽  
Water Soluble ◽  
Size Exclusion ◽  
Resonance Spectroscopy ◽  
Tree Fern ◽  
13C Nuclear Magnetic Resonance ◽  
Exclusion Chromatography

A shear-thickening water-soluble polysaccharide was purified from mucilage extracted from the fronds of the New Zealand black tree fern (Cyathea medullaris or 'mamaku' in Māori) and its structure characterised. Constituent sugar analysis by three complementary methods, combined with linkage analysis (of carboxyl reduced samples) and 1H and 13C nuclear magnetic resonance spectroscopy (NMR) revealed a glucuronomannan comprising a backbone of 4-linked methylesterified glucopyranosyl uronic acid and 2-linked mannopyranosyl residues, branched at O-3 of 45% and at both O-3 and O-4 of 53% of the mannopyranosyl residues with side chains likely comprising terminal xylopyranosyl, terminal galactopyranosyl, non-methylesterified terminal glucopyranosyl uronic acid and 3-linked glucopyranosyl uronic acid residues. The weight-average molecular weight of the purified polysaccharide was ~1.9×106Da as determined by size-exclusion chromatography coupled with multi-angle laser light scattering (SEC-MALLS). The distinctive rheological properties of this polysaccharide are discussed in relation to its structure. © 2014 Elsevier B.V.

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