scholarly journals Strength and Microstructure of Class-C Fly Ash and GGBS Blend Geopolymer Activated in NaOH & NaOH + Na2SiO3

Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 59 ◽  
Author(s):  
Sasui Sasui ◽  
Gyuyong Kim ◽  
Jeongsoo Nam ◽  
Tomoyuki Koyama ◽  
Sant Chansomsak
Keyword(s):  
Fly Ash ◽  
Setting Time ◽  
Strength Loss ◽  
Ash Content ◽  
Compact Structure ◽  
Granulated Blast Furnace Slag ◽  
Silica Source ◽  
Class C ◽  
Xrd Patterns ◽  
Furnace Slag

In this paper, class-C fly ash (FA) and ground granulated blast-furnace slag (GGBS)-based geopolymer activated in NaOH and NaOH + Na2SiO3 was studied regarding setting time, compressive strength, porosity, microstructure, and formation of crystalline phases. When comparing the effects of alkali type on the FA and GGBS geopolymer composites, results revealed that NaOH has a lesser effect in developing strength and denser microstructure than does NaOH + Na2SiO3, since the addition of Na2SiO3 provides the silica source to develop more compact structure. Incorporation of Na2SiO3 reduced the crystallinity and the paste was more amorphous compared to NaOH activated pastes. The class-C FA and GGBS blends resulted in prolonged setting time, reduced strength, and loose matrix with the increase in fly ash content. The un-reactivity of calcium in blends was observed with increasing fly ash content, leading to strength loss. It is evident from XRD patterns that calcium in fly ash did not contribute in forming C-S-H bond, but formation of crystalline calcite was observed. Furthermore, XRD analyses revealed that the reduction in fly ash leads to the reduction in crystallinity, and SEM micrographs showed the unreactive fly ash particles, which hinder the formation of a denser matrix.

scholarly journals Properties of non-standard fly ash – slag cements containing calcareous fly ash

2013 ◽  
Vol 12 (3) ◽  
pp. 215-222
Author(s):  
Katarzyna Synowiec
Keyword(s):  
Fly Ash ◽  
Blast Furnace Slag ◽  
Strength Class ◽  
Setting Time ◽  
Heat Of Hydration ◽  
Initial Setting Time ◽  
Granulated Blast Furnace Slag ◽  
Unfavorable Effect ◽  
Initial Setting ◽  
Furnace Slag

The paper presents the tests results of the properties of non - standard fly ash - slag cements composition. Both natural (unprocessed) and activated by grinding calcareous fly ash was used. It was found that the calcareous fly ash next to the granulated blast furnace slag may be a component of low - clinker cements (ca. 40%). Those cements are characterized by low heat of hydration and overdue of initial setting time in comparison with Ordinary Portland Cement, moreover they have an unfavorable effect on consistency and its upkeep in time. Production of fly ash - slag cements is possible for strength class 32,5 N when the component of cement is raw fly ash, and for strength classes 32,5 N, 32,5 R and 42,5 N when ground fly ash was used. Fly ash activated by grinding was characterized by higher activity.

scholarly journals Protective Geopolymer Coatings Containing Multi-Componential Precursors: Preparation and Basic Properties Characterization

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3448
Author(s):  
Chenhui Jiang ◽  
Aiying Wang ◽  
Xufan Bao ◽  
Zefeng Chen ◽  
Tongyuan Ni ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Blast Furnace ◽  
Fly Ash ◽  
Portland Cement ◽  
Adhesive Strength ◽  
Blast Furnace Slag ◽  
Setting Time ◽  
Rapid Test ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

This paper presents an experimental investigation on geopolymer coatings (GPC) in terms of surface protection of civil structures. The GPC mixtures were prepared with a quadruple precursor simultaneously containing fly ash (FA), ground granulated blast-furnace slag (GBFS), metakaolin (MK), and Portland cement (OPC). Setting time, compressive along with adhesive strength and permeability, were tested and interpreted from a perspective of potential applications. The preferred GPC with favorable setting time (not shorter than 120 min) and desirable compressive strength (not lower than 35 MPa) was selected from 85 mixture formulations. The results indicate that balancing strength and setting behavior is viable with the aid of the multi-componential precursor and the mixture design based on total molar ratios of key oxides or chemical elements. Adhesive strength of the optimized GPC mixtures was ranged from 1.5 to 3.4 MPa. The induced charge passed based on a rapid test of coated concrete specimens with the preferred GPC was 30% lower than that of the uncoated ones. Setting time of GPC was positively correlated with η[Si/(Na+Al)]. An abrupt increase of setting time occurred when the molar ratio was greater than 1.1. Compressive strength of GPC was positively affected by mass contents of ground granulated blast furnace slag, metakaolin and ordinary Portland cement, and was negatively affected by mass content of fly ash, respectively. Sustained seawater immersion impaired the strength of GPC to a negligible extent. Overall, GPC potentially serves a double purpose of satisfying the usage requirements and achieving a cleaner future.

Utilization of fly ash and ground granulated blast furnace slag as an alternative silica source in reactive powder concrete

Fuel ◽  
2008 ◽  
Vol 87 (12) ◽  
pp. 2401-2407 ◽  
Author(s):  
Halit Yazıcı ◽  
Hüseyin Yiğiter ◽  
Anıl Ş. Karabulut ◽  
Bülent Baradan
Keyword(s):  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Reactive Powder Concrete ◽  
Granulated Blast Furnace Slag ◽  
Silica Source ◽  
Reactive Powder ◽  
Furnace Slag

Influence of Mineral Admixtures on Chloride Diffusion Coefficient of Self-Compacting Concrete

2013 ◽  
Vol 405-408 ◽  
pp. 2876-2880
Author(s):  
Jian Bo Xiong ◽  
Peng Ping Li ◽  
Sheng Nian Wang
Keyword(s):  
Diffusion Coefficient ◽  
Fly Ash ◽  
Cementitious Materials ◽  
Ash Content ◽  
Mineral Admixtures ◽  
Chloride Diffusion ◽  
Chloride Diffusion Coefficient ◽  
Self Compacting Concrete ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

The influence of mineral admixtures on workability of fresh concrete and chloride ion permeability resistance of hardened concrete for C50 self-compacting concrete was investigated by means of the Natural Immersion Test. The results showed that the chloride diffusion coefficient in fly ash concrete decreased first and then increased with increasing fly ash content in cementitious materials, when fly ash content was 30% or 40%, it got the lowest value at 28 days or 90 days, respectively. The chloride diffusion coefficient in specimens decreased with increasing the ground granulated blast furnace slag content in cementitious materials, but it changed little when the replacement was in ranges of 50% to 60%. Furthermore, for the specimens which replaced by fly ash and ground granulated blast furnace slag, the chloride diffusion coefficient decreased first and then increased with increasing the fly ash content in complex cementitious, and when fly ash content was 10% or 20%, it got the lowest value at 28 days or 90 days, respectively.

scholarly journals Optimizing Mixtures of Alkali Aluminosilicate Cement Based on Ternary By-Products

2021 ◽  
Vol 7 (7) ◽  
pp. 1264-1274
Author(s):  
Hoang Vinh Long
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Raw Materials ◽  
Setting Time ◽  
Raw Material ◽  
Optimal Composition ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag ◽  
By Products

Portland cement is a popular binder but causes many adverse effects on the environment. That is due to the large consumption of raw materials and energy during production while emitting vast amounts of CO2. In recent years, Alkali Aluminosilicate Cement (AAC) has drawn much attention in research and development and promises to become a binder that can replace the traditional cement. In many studies of this binder, the content of the ingredients is often gradually changed to determine the optimal composition. The object of this paper is to optimize the composition of AAC using a combination of three by-products as the primary raw material, including Rush Husk Ash (RHA), Fly Ash (FA), and Ground Granulated Blast-Furnace Slag (GGBS). The investigation was conducted based on the critical parameter SiO2/Al2O3, and the D-optimal design. The FA and the GGBS were industrial product form, while the RHA was ground in a ball mill for 2 hours before mixing. The results show that this type of binder has setting time and soundness to meet standard cement requirements. While comparing to Portland cement, the AAC has a faster setting time, slower development of compressive strength in the early stages but a higher strength at the age of 56 days. According to the highest compressive strength at 28 days and high fly ash content, the optimal composition was RHA of 27.8%, FA of 41.8%, and GGBS of 15.4%, corresponding to the ratio SiO2/Al2O3 of 3.83. In addition, compressive strength at 28 days of the mortar specimens with the optimal binder and the ratio of water/ cement at 0.32 reached 63 MPa. Doi: 10.28991/cej-2021-03091724 Full Text: PDF

scholarly journals Orthogonal Experimental Studies on Preparation of Mine-Filling Materials from Carbide Slag, Granulated Blast-Furnace Slag, Fly Ash, and Flue-Gas Desulphurisation Gypsum

2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Mingyue Wu ◽  
Xiangming Hu ◽  
Qian Zhang ◽  
Weimin Cheng ◽  
Zunxiang Hu
Keyword(s):  
Blast Furnace ◽  
Fly Ash ◽  
Flue Gas ◽  
Blast Furnace Slag ◽  
Raw Materials ◽  
Setting Time ◽  
Fgd Gypsum ◽  
Granulated Blast Furnace Slag ◽  
Carbide Slag ◽  
Furnace Slag

Environmentally friendly and cheap composite green cementitious materials have been prepared from carbide slag, fly ash, flue-gas desulphurisation (FGD) gypsum, and granulated blast-furnace slag (GBFS) without using cement clinker. Orthogonal testing was used to investigate the effects of the raw materials on the amount of water required for reaching standard consistency and consistency, setting time, slump value, and strength of the produced materials after curing for 7 d and 28 d. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques were used for the analysis of the sample microstructure and hydration products as well as for the exploration of possible hydration mechanisms. We found that, among the utilised raw materials, the addition of FGD gypsum had the most significant effect on the setting time and amount of water required for reaching standard consistency and consistency, while the addition of GBFS deeply affected the slump value. The optimal activation results were obtained when the mass ratio of carbide slag : fly ash : GBFS : FGD gypsum was equal to 12.1 : 60.6 : 18.2 : 9.1.

scholarly journals Incorporation of Waste Glass as an Activator in Class-C Fly Ash/GGBS Based Alkali Activated Material

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3906
Author(s):  
Sasui Sasui ◽  
Gyuyong Kim ◽  
Jeongsoo Nam ◽  
Arie van Riessen ◽  
Hamin Eu ◽  
...  
Keyword(s):  
Fly Ash ◽  
Strength Loss ◽  
Waste Glass ◽  
Main Reaction ◽  
Main Reaction Product ◽  
X Ray ◽  
Granulated Blast Furnace Slag ◽  
Alkali Solutions ◽  
Class C ◽  
Alkali Activated

In this study, an alkaline activator was synthesized by dissolving waste glass powder (WGP) in NaOH-4M solution to explore its effects on the formation of alkali-activated material (AAM) generated by Class-C fly ash (FA) and ground granulated blast furnace slag (GGBS). The compressive strength, flexure strength, porosity and water absorption were measured, and X-ray diffraction (XRD) and scanning electron microscopy with energy dispersive X-ray (SEM-EDX) were used to study the crystalline phases, hydration mechanism and microstructure of the resulting composites. Results indicated that the composition of alkali solutions and the ratios of FA/GGBS were significant in enhancing the properties of the obtained AAM. As the amount of dissolved WGP increased in alkaline solution, the silicon concentration increased, causing the accelerated reactivity of FA/GGBS to develop Ca-based hydrate gel as the main reaction product in the system, thereby increasing the strength and lowering the porosity. Further increase in WGP dissolution led to strength loss and increased porosity, which were believed to be due to the excessive water demand of FA/GGBS composites to achieve optimum mixing consistency. Increasing the GGBS proportion in a composite appeared to improve the strength and lower the porosity owing to the reactivity of GGBS being higher than that of FA, which contributed to develop C-S-H-type hydration.

scholarly journals Effect of Flue Gas Desulfurization Gypsum on the Properties of Calcium Sulfoaluminate Cement Blended with Ground Granulated Blast Furnace Slag

Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 382 ◽  
Author(s):  
Danying Gao ◽  
Zhenqing Zhang ◽  
Yang Meng ◽  
Jiyu Tang ◽  
Lin Yang
Keyword(s):  
Blast Furnace ◽  
Mechanical Strength ◽  
Flue Gas ◽  
Blast Furnace Slag ◽  
Setting Time ◽  
Flue Gas Desulfurization ◽  
Calcium Sulfoaluminate Cement ◽  
Calcium Sulfoaluminate ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

This work aims to investigate the effect of additional flue gas desulfurization gypsum (FGDG) on the properties of calcium sulfoaluminate cement (CSAC) blended with ground granulated blast furnace slag (GGBFS). The hydration rate, setting time, mechanical strength, pore structure and hydration products of the CSAC-GGBFS mixture containing FGDG were investigated systematically. The results show that the addition of FGDG promotes the hydration of the CSAC-GGBFS mixture and improves its mechanical strength; however, the FGDG content should not exceed 6%.

scholarly journals Effect of Mineral Admixtures on the Performance of Low-Quality Recycled Aggregate Concrete

Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 596
Author(s):  
Yasuhiro Dosho
Keyword(s):  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Recycled Aggregate Concrete ◽  
Recycled Aggregate ◽  
Mineral Admixtures ◽  
Structural Concrete ◽  
Aggregate Concrete ◽  
Granulated Blast Furnace Slag ◽  
Furnace Slag

To improve the application of low-quality aggregates in structural concrete, this study investigated the effect of multi-purpose mineral admixtures, such as fly ash and ground granulated blast-furnace slag, on the performance of concrete. Accordingly, the primary performance of low-quality recycled aggregate concrete could be improved by varying the replacement ratio of the recycled aggregate and using appropriate mineral admixtures such as fly ash and ground granulated blast-furnace slag. The results show the potential for the use of low-quality aggregate in structural concrete.

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