scholarly journals The Growth of Photoactive Porphyrin-Based MOF Thin Films Using the Liquid-Phase Epitaxy Approach and their Optoelectronic Properties

Materials ◽  
2019 ◽  
Vol 12 (15) ◽  
pp. 2457 ◽  
Author(s):  
Ngongang Ndjawa ◽  
Tchalala ◽  
Shekhah ◽  
Khan ◽  
Mansour ◽  
...  
Keyword(s):  
Thin Films ◽  
Solar Cells ◽  
Liquid Phase ◽  
Liquid Phase Epitaxy ◽  
Metal Organic Framework ◽  
Device Fabrication ◽  
Optoelectronic Properties ◽  
Molecular Alteration ◽  
Wide Range ◽  
Light Absorbers

This study reports on the optoelectronic properties of porphyrin-based metal–organic framework (MOF) thin films fabricated by a facile liquid-phase epitaxy approach. This approach affords the growth of MOF thin films that are free of morphological imperfections, more suitable for optoelectronic applications. Chemical modifications such as the porphyrin ligand metallation have been found to preserve the morphology of the grown films making this approach particularly suitable for molecular alteration of MOF thin film optoelectronic properties without compromising its mesoscale morphology significantly. Particularly, the metallation of the ligand was found to be effective to tune the MOF bandgap. These porphyrin-based MOF thin films were shown to function effectively as donor layers in solar cells based on a Fullerene-C60 acceptor. The ability to fabricate MOF solar cells free of a liquid-phase acceptor greatly simplifies device fabrication and enables pairing of MOFs as light absorbers with a wide range of acceptors including non-fullerene acceptors.

scholarly journals Progress in Thin Film Solar Cells Based onCu2ZnSnS4

2011 ◽  
Vol 2011 ◽  
pp. 1-10 ◽  
Author(s):  
Hongxia Wang
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solar Cells ◽  
Research Area ◽  
Thin Film Solar Cells ◽  
Environment Impact ◽  
Wide Range ◽  
Czts Thin Films ◽  
New Research ◽  
Light Absorbers

The research in thin film solar cells has been dominated by light absorber materials based on CdTe and Cu(In,Ga)Se2(CIGS) in the last several decades. The concerns of environment impact of cadmium and the limited availability of indium in those materials have driven the research towards developing new substitute light absorbers made from earth abundant, environment benign materials. Cu2ZnSnS4(CZTS) semiconductor material has emerged as one of the most promising candidates for this aim and has attracted considerable interest recently. Significant progress in this relatively new research area has been achieved in the last three years. Over 130 papers on CZTS have been published since 2007, and the majority of them are on the preparation of CZTS thin films by different methods. This paper, will review the wide range of techniques that have been used to deposit CZTS semiconductor thin films. The performance of the thin film solar cells using the CZTS material will also be discussed.

Irradiation Induced Changes in Semiconducting Thin Films

2013 ◽  
Vol 341 ◽  
pp. 181-210 ◽  
Author(s):  
S.K. Tripathi
Keyword(s):  
Thin Films ◽  
Solar Cells ◽  
Heavy Ions ◽  
Semiconductor Device ◽  
High Energy ◽  
Device Fabrication ◽  
Electrical Performance ◽  
Radiation Environment ◽  
Extended Defects ◽  
Semiconducting Thin Films

High-energy electron, proton, neutron, photon and ion irradiation of semiconductor diodes and solar cells has long been a topic of considerable interest in the field of semiconductor device fabrication. The inevitable damage production during the process of irradiation is used to study and engineer the defects in semiconductors. In a strong radiation environment in space, the electrical performance of solar cells is degraded due to direct exposure to energetically charged particles. A considerable amount of work has been reported on the study of radiation damage in various solar cell materials and devices in the recent past. In most cases, high-energy heavy ions damage the material by producing a large amount of extended defects, but high-energy light ions are suitable for producing and modifying the intrinsic point defects. The defects can play a variety of electronically active roles that affect the electrical, structural and optical properties of a semiconductor. This review article aims to present an overview of the advancement of research in the modification of glassy semiconducting thin films using different types of radiations (light, proton and swift heavy ions). The work which has been done in our laboratory related to irradiation induced effects in semiconducting thin films will also be compared with the existing literature.

Domain engineering in LiNbO3 thin films grown by liquid phase epitaxy

2003 ◽  
Author(s):  
Ji-Won Son ◽  
Yin Yuen ◽  
Sergei S. Orlov ◽  
Bill Phillips ◽  
Ludwig Galambos ◽  
...  
Keyword(s):  
Thin Films ◽  
Liquid Phase ◽  
Liquid Phase Epitaxy ◽  
Domain Engineering
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