scholarly journals Effects of Expansive Agents on the Early Hydration Kinetics of Cementitious Binders

Materials ◽  
2019 ◽  
Vol 12 (12) ◽  
pp. 1900 ◽  
Author(s):  
Miao Miao ◽  
Qingyang Liu ◽  
Jian Zhou ◽  
Jingjing Feng
Keyword(s):  
Fly Ash ◽  
Hydration Heat ◽  
Mineral Admixture ◽  
Mineral Admixtures ◽  
Hydration Reaction ◽  
Hydration Kinetics ◽  
Early Hydration ◽  
Expansive Agent ◽  
Mechanical Performances ◽  
Kinetics Of

The addition of expansive agents could overcome the main disadvantages of raw concrete including high brittleness and low tensile strength. Few studies have investigated the early hydration kinetics of expansive cementitious binders, though the findings from the early hydration kinetics are helpful for understanding their technical performances. In this study, mixtures of 3CaO•3Al2O3•CaSO4 and CaSO4 (i.e., ZY-type™ expansive agent) with different proportions of mineral admixtures (e.g., fly ash and slag) were added into cement pastes to investigate the early hydration kinetics mechanism of expansive cementitious binders. Early hydration heat evolution rate and cumulative hydration heat were measured by isothermal calorimeter. Kinetic parameters were estimated based on the Krstulovic–Dabic model and Knudsen equations. Mechanical performances of expansive cementitious binders were tested in order to evaluate if they met the basic requirements of shrinkage-compensating materials in technical use. The early hydration heat released from cementitious binders containing ZY-type™ expansive agent was much greater than that released by pure cement, supporting the idea that addition of the expansive agent would improve the reaction of cement. The early hydration kinetic rates were decreased due to the reactions of the mineral admixture (e.g., fly ash or slag) and the ZY-type™ expansive agent in the cement system. The hydration reaction of cementitious binders containing ZY-type™ expansive agent obeyed the Krstulovic–Dabic model well. Three processes are involved in the hydration reaction of cementitious binders containing ZY-type™ expansive agent. These are nucleation and crystal growth (NG), interactions at phase boundaries (I), and diffusion (D). The 14-day expansion rates of cementitious binders containing ZY-type™ expansive agent are in the range of 2.0 × 10−4 to 3.5 × 10−4, which could meet the basic requirements of anti-cracking performances in technical use according to Chinese industry standard JGJ/T 178-2009. This study could provide an insight into understanding the effects of expansive agents on the hydration and mechanical performances of cementitious binders.

Study on the early Hydration of Alkali-Activated Slag Cementing Materials

2014 ◽  
Vol 584-586 ◽  
pp. 1465-1469 ◽  
Author(s):  
Jin Song Shi ◽  
Xiao Hui Yuan ◽  
Hui Guo Chen
Keyword(s):  
Fly Ash ◽  
Water Glass ◽  
Coal Ash ◽  
Hydration Heat ◽  
Hydration Reaction ◽  
Early Hydration ◽  
Environment Temperature ◽  
Activated Slag ◽  
Cementing Material ◽  
Alkali Activated

The early hydration of alkali-activator slag(AAS) cementing material is studied by changing the environment temperature, the proportion of slag and fly ash, water glass module, and dosage of sodium silicate. The results show that as the temperature raise, the hydration rate and hydration heat of the AAS cementing materials will remarkably accelerate. Joining coal ash in the pure slag cementing material can effectively slowdown its hydration reaction, and the hydration heat is also reduced.

scholarly journals Cement-Based Renders Manufactured with Phase-Change Materials: Applications and Feasibility

2016 ◽  
Vol 2016 ◽  
pp. 1-6 ◽  
Author(s):  
Luigi Coppola ◽  
Denny Coffetti ◽  
Sergio Lorenzi
Keyword(s):  
Compressive Strength ◽  
Phase Change ◽  
Phase Change Materials ◽  
Residential Buildings ◽  
Setting Time ◽  
Drying Shrinkage ◽  
Hydration Kinetics ◽  
Mechanical Performances ◽  
Entrapped Air ◽  
Kinetics Of

The paper focuses on the evaluation of the rheological and mechanical performances of cement-based renders manufactured with phase-change materials (PCM) in form of microencapsulated paraffin for innovative and ecofriendly residential buildings. Specifically, cement-based renders were manufactured by incorporating different amount of paraffin microcapsules—ranging from 5% to 20% by weight with respect to binder. Specific mass, entrained or entrapped air, and setting time were evaluated on fresh mortars. Compressive strength was measured over time to evaluate the effect of the PCM addition on the hydration kinetics of cement. Drying shrinkage was also evaluated. Experimental results confirmed that the compressive strength decreases as the amount of PCM increases. Furthermore, the higher the PCM content, the higher the drying shrinkage. The results confirm the possibility of manufacturing cement-based renders containing up to 20% by weight of PCM microcapsules with respect to binder.

Effects of Fly Ash and Granular Blast-Furnace Slag on Development Rate of Strength of Concrete

2014 ◽  
Vol 629-630 ◽  
pp. 371-375
Author(s):  
Ji Wei Cai ◽  
Si Jia Yan ◽  
Gong Lei Wei ◽  
Lu Wang ◽  
Jin Jin Zhou
Keyword(s):  
Blast Furnace ◽  
Fly Ash ◽  
Blast Furnace Slag ◽  
Development Rate ◽  
Mineral Admixture ◽  
Mineral Admixtures ◽  
Conventional Concrete ◽  
Enhancing Effect ◽  
Substitution Content ◽  
Furnace Slag

Fly ash (FA) and granular blast-furnace slag (GBFS) are usual mineral admixtures to conventional concrete, and their contents substituted for Portland cement definitely affect development rate of strength of concrete. C30 and C60 concrete samples with FA and/or GBFS were prepared to study the influence of substitution content of the mineral admixtures on 3 d, 7 d and 28 d strength. The results reveal that the development rate of strength in period from 3 d to 7 d gets slow with increasing content of mineral admixtures except for concrete with only GBFS less than 20%. In the case of substituting FA as the only mineral admixture for part of cement, the development rate of strength of C30 concrete in period from 7 d to 28 d keeps roughly constant even that of C60 concrete increases. When substituting mineral admixtures in the presence of GBFS for cement within experimental range, the development rate of strength in period from 7 d to 28 d gets fast with increasing substitution content. The enhancing effect of combining FA and GBFS occurs in period from 7 d to 28 d for both C30 and C60 concretes (FA+GBFS≤40%), even occurs in period from 3 d to 7 d for C60 concrete. Based on 7 d strength and the development rate, 28 d strength of concrete can be predicted accurately.

scholarly journals Hydration Kinetics of Composite Cementitious Materials Containing Copper Tailing Powder and Graphene Oxide

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2499 ◽  
Author(s):  
Shuhua Liu ◽  
Qiaoling Li ◽  
Xinyi Zhao
Keyword(s):  
Graphene Oxide ◽  
Cementitious Materials ◽  
Heat Evolution ◽  
Hydration Heat ◽  
Hydration Kinetics ◽  
Early Hydration ◽  
Controlling Processes ◽  
Boundary Reaction ◽  
Phase Boundary Reaction ◽  
Cementitious Systems

The hydration heat evolution curves of composite cementitious materials containing copper tailing powder (CT) and graphene oxide (GO) with different contents are measured and analyzed in this paper. The hydration rate and total hydration heat of the composite cementitious materials decrease with the increase of CT dosage, but improve with the increase of CT fineness and GO dosage. The hydration process of the cementitious systems undergoes three periods, namely nucleation and crystal growth (NG), phase boundary reaction (I), and diffusion (D), which can be simulated well using the Krstulovic–Dabic model. The hydration rates of the three controlling processes of the composite cementitious system decrease with the increase of CT content, but improve slightly with the increase of CT fineness. GO enhances the controlling effect of the NG process of the cementitious systems with or without CT, thus promotes the early hydration as a whole.

scholarly journals Mechanical Properties and Microscopic Mechanism of Coral Sand-Cement Mortar

2020 ◽  
Vol 2020 ◽  
pp. 1-11 ◽  
Author(s):  
Luoxin Wang ◽  
Junshuai Mei ◽  
Jing Wu ◽  
Xingyang He ◽  
Hainan Li ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Cement Mortar ◽  
Mineral Admixture ◽  
Mineral Admixtures ◽  
Hardened Cement ◽  
Hydration Reaction ◽  
Microscopic Mechanism ◽  
X Ray ◽  
Volume Stability ◽  
Coral Sand

The workability and mechanical performance of coral sand-cement mortar (coral mortar, for short) and the modification effects of mineral admixtures on the coral mortar were studied in this paper. The results showed that the strength of coral mortar was lower than that of standard mortar, but the strength of coral mortar was improved by compositing with the mineral admixture, which can be attributed to the improvement of the microstructure and interface transition area. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR) were used to explore the microscopic mechanism involved in the mechanical properties, volume stability, and hydration of mortar. The analyses revealed that the internal curing effect of coral sand improved the mechanical properties of mortar and its ability to resist shrinkage. The uneven surface of coral sand formed a meshing state of close combination with the hardened cement mortar, which helped to improve the volume stability of mortar. The Ca2+ and Mg2+ ions from coral sand participated in the hydration reaction of cement, which contributed to generating more hydration products. Moreover, the microaggregate filling and pozzolanic effects of fly ash and slag improved the mechanical properties of coral mortar and resistance to chloride ion diffusion.

Study on the Durability of Concrete with Mineral Admixtures to Sulfate Attack by Wet-Dry Cycle Method

2011 ◽  
Vol 295-297 ◽  
pp. 165-169
Author(s):  
Guan Guo Liu ◽  
Jing Ming ◽  
Xiong Wen Zhang ◽  
Ai Bin Ma
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Sulfate Attack ◽  
Mineral Admixture ◽  
Mineral Admixtures ◽  
Partial Replacement ◽  
Change Environment ◽  
Physical Mechanisms ◽  
Chemical Attack ◽  
Tidal Area

Sulfate attack is one of several chemical and physical mechanisms of concrete deterioration. In actual situation, concrete structures always suffer from the coupled effects of multifactor such as wet-dry cycle and sulfate attack when exposed to tidal area or groundwater level change environment. Partial replacement of cement with mineral admixture is one of the efficient methods for improving concrete resistance against sulfate attack. In this regard, the resistance of concrete with fly ash and slag to sulfate attack was investigated by wet-dry cycle method. The degree of sulfate attack on specimens after different cycles was observed using scanning electron microscopy. The results of compressive strength and percentage of compressive strength evolution factor at various cycling times show an increase in the sulfate resistance of concrete with 60% of fly ash and slag than that only with 40% fly ash. The microstructural study indicates that the primary cause of deterioration of concrete under wet-dry cycle condition is swelling of the sulfate crystal rather chemical attack.

Evaluation of Fresh Properties and Rheology of Mortar Using Carbon-Free Fly Ash and Normal Fly Ash

2020 ◽  
Vol 1005 ◽  
pp. 76-81
Author(s):  
Ghawsaddin Nazari ◽  
Shunya Yamanaka ◽  
Shigeyuki Date
Keyword(s):  
Fly Ash ◽  
Setting Time ◽  
Great Influence ◽  
Mineral Admixture ◽  
Mineral Admixtures ◽  
Fresh Properties ◽  
Initial Setting Time ◽  
Usual Solution ◽  
Initial Setting ◽  
Flow Loss

Usage of mineral admixture and chemical admixture in concrete or mortar is a usual solution to reach full compaction, particularly where reinforcement blockage and lack of skilled labor happen. In this paper effect of mineral admixtures (Carbon-free fly ash, hereafter CfFA, and normal fly ash) on fresh properties and rheology of mortar have been investigated. As a result, it was confirmed that CfFA increased significantly the fluidity and air content of mortar in comparison to normal fly ash, both in 15% and 30% replacement; however, the flow loss and air stability within one hour were almost equal. In addition, the initial setting time has also been affected by variation of materials. The two mixing of 30% and 15% of CfFA had a shorter setting time in comparison to the mortar with normal fly ash. Furthermore, CfFA based mortar had a great influence on rheology of mortar. Compared to normal fly ash, CfFA Considerably decreased the plastic Viscosity and increased the productivity of the mortar, both in non-vibrated and vibrated condition, particularly those with 30% replacement.

Effects of Mineral Admixtures and Superplasticizer on Controlling Hydration Heat of Cementitious Materials

2013 ◽  
Vol 639-640 ◽  
pp. 368-371
Author(s):  
Qing Huang ◽  
Jian Yin ◽  
Wei Min Song
Keyword(s):  
Fly Ash ◽  
Release Rate ◽  
Early Stage ◽  
Cementitious Materials ◽  
Heat Evolution ◽  
Hydration Heat ◽  
Mineral Admixtures ◽  
Evolution Rate ◽  
Two Parameters ◽  
Peak Value

The effects of mineral admixtures and superplasticizer on reducing the hydration heat of cementitious material were evaluated in this study, and the heat evolution rate and hydration heat were tested as the two parameters to evaluate the effect of improvement. The results showed that the cement partly-replaced with fly ash (FA) and slag (SG) could significantly decrease the release rate of hydration heat on the early stage of hydration, and lower the peak value of the heat evolution rate. The superplasticizer (TJ-Ⅲ) could reduce the hydration heat mainly on the early stage of hydration, and extended the induction period. In comparison with slag, the fly ash had more active effects on reducing the peak value and release rate of hydration heat.

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