scholarly journals On the Microstructure and Isothermal Oxidation of the Si-22Fe-12Cr-12Al-10Ti-5Nb (at.%) Alloy

Materials ◽  
2019 ◽  
Vol 12 (11) ◽  
pp. 1806 ◽  
Author(s):  
Ofelia Hernández-Negrete ◽  
Panos Tsakiropoulos
Keyword(s):  
Bond Coat ◽  
Cast Alloy ◽  
Isothermal Oxidation ◽  
Self Healing ◽  
Intermetallic Alloys ◽  
High Temperature Materials ◽  
Unknown Phase ◽  
Silica Scale ◽  
Two Phases ◽  
Bond Coat Alloys

Nb-silicide based alloys are new ultra-high temperature materials that could replace Ni-based superalloys. Environmentally resistant coating system (s) with αAl2O3 or SiO2 forming bond coat alloys that are chemically compatible with the Nb-silicide based alloy substrates are needed. This paper makes a contribution to the search for non-pesting bond coat alloys. The microstructure and isothermal oxidation at 800 °C of the silicide-based alloy Si-22Fe-12Cr-12Al-10Ti-5Nb (OHC2) were studied. The cast alloy exhibited macrosegregation of all elements. The microstructures in the cast alloy and after the heat treatment at 800 °C consisted of the same phases, namely TM6Si5, TM5Si3 (TM = transition metal), FeSi2Ti, Fe3Al2Si3, (Fe,Cr)(Si,Al), and an unknown phase of dark contrast. The latter two phases were not stable at 950 °C, where the TMSi2 was formed. There was evidence of endothermic reaction(s) below 1200 °C and liquation at 1200 °C. The alloy followed parabolic oxidation kinetics after the first hour of isothermal oxidation at 800 °C, did not pest, and formed a self-healing scale, in which the dominant oxide was Al2O3. The alloy was compared with other alumina or silica scale-forming intermetallic alloys and approaches to the design of bond coat alloys were suggested.

scholarly journals Microstructures and Isothermal Oxidation of the Alumina Scale Forming Nb1.45Si2.7Ti2.25Al3.25Hf0.35 and Nb1.35Si2.3Ti2.3Al3.7Hf0.35 Alloys

Materials ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 759 ◽  
Author(s):  
Mohammad Ghadyani ◽  
Claire Utton ◽  
Panos Tsakiropoulos
Keyword(s):  
Solid Solution ◽  
Cast Alloy ◽  
Alumina Scale ◽  
Isothermal Oxidation ◽  
Intermetallic Alloys ◽  
High Entropy ◽  
Heat Treated ◽  
Composite Silicide ◽  
Definition Of ◽  
Selection Of

Coating system(s) will be required for Nb-silicide based alloys. Alumina forming alloys that are chemically compatible with the Nb-silicide based alloy substrate could be components of such systems. The intermetallic alloys Nb1.45Si2.7Ti2.25Al3.25Hf0.35 (MG5) and Nb1.35Si2.3Ti2.3Al3.7Hf0.35 (MG6) were studied in the cast, heat treated and isothermally oxidised conditions at 800 and 1200 °C to find out if they are αAl2O3 scale formers. A (Al/Si)alloy versus Nb/(Ti + Hf)alloy map, which can be considered to be a map for Multi-Principle Element or Complex Concentrated Nb-Ti-Si-Al-Hf alloys, and a [Nb/(Ti + Hf)]Nb5Si3 versus [Nb/(Ti + Hf)]alloy map were constructed making use of the alloy design methodology NICE and data from a previously studied alloy, and were used to select the alloys MG5 and MG6 that were expected (i) not to pest, (ii) to form αAl2O3 scale at 1200 °C, (iii) to have no solid solution, (iv) to form only hexagonal Nb5Si3 and (v) to have microstructures consisting of hexagonal Nb5Si3, Ti5Si3, Ti5Si4, TiSi silicides, and tri-aluminides and Al rich TiAl. Both alloys met the requirements (i) to (v). The alumina scale was able to self-heal at 1200 °C. Liquation in the alloy MG6 at 1200 °C was linked with the formation of a eutectic like structure and the TiAl aluminide in the cast alloy. Key to the oxidation of the alloys was the formation (i) of “composite” silicide grains in which the Nb5Si3 core was surrounded by the Ti5Si4 and TiSi silicides, and (ii) of tri-aluminides with high Al/Si ratio, particularly at 1200 °C and very low Nb/Ti ratio forming in-between the “composite” silicide grains. Both alloys met the “standard definition” of high entropy alloys (HEAs). Compared with HEAs with bcc solid solution and intermetallics, the VEC values of both the alloys were outside the range of reported values. The parameters VEC,  and  of Nb-Ti-Si-Al-Hf coating alloys and non-pesting Nb-silicide based alloys were compared and trends were established. Selection of coating alloys with possible “layered” structures was discussed and alloy compositions were proposed.

scholarly journals On the Microstructure and Properties of the Nb-23Ti-5Si-5Al-5Hf-5V-2Cr-2Sn (at.%) Silicide-Based Alloy—RM(Nb)IC

Metals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1868
Author(s):  
Nikos Vellios ◽  
Paul Keating ◽  
Panos Tsakiropoulos
Keyword(s):  
Oxidation Kinetics ◽  
Cast Alloy ◽  
Lamellar Microstructure ◽  
Isothermal Oxidation ◽  
Surface Areas ◽  
Young’S Moduli ◽  
Heat Treated ◽  
Two Temperatures ◽  
Intermetallic Composite ◽  
Two Phases

The microstructure, isothermal oxidation, and hardness of the Nb-23Ti-5Si-5Al-5Hf-5V-2Cr-2Sn alloy and the hardness and Young’s moduli of elasticity of its Nbss and Nb5Si3 were studied. The alloy was selected using the niobium intermetallic composite elaboration (NICE) alloy design methodology. There was macrosegregation of Ti and Si in the cast alloy. The Nbss, aNb5Si3, gNb5Si3, and HfO2 phases were present in the as-cast or heat-treated alloy plus TiN in the near-the-surface areas of the latter. The vol.% of Nbss was about 80%. There were Ti- and Ti-and-Hf-rich areas in the solid solution and the 5-3 silicide, respectively, and there was a lamellar microstructure of these two phases. The V partitioned to the Nbss, where the solubilities of Al, Cr, Hf, and V increased with increasing Ti concentration. At 700, 800, and 900 °C, the alloy did not suffer from catastrophic pest oxidation; it followed parabolic oxidation kinetics in the former two temperatures and linear oxidation kinetics in the latter, where its mass change was the lowest compared with other Sn-containing alloys. An Sn-rich layer formed in the interface between the scale and the substrate, which consisted of the Nb3Sn and Nb6Sn5 compounds at 900 °C. The latter compound was not contaminated with oxygen. Both the Nbss and Nb5Si3 were contaminated with oxygen, with the former contaminated more severely than the latter. The bulk of the alloy was also contaminated with oxygen. The alloying of the Nbss with Sn increased its elastic modulus compared with Sn-free solid solutions. The hardness of the alloy, its Nbss, and its specific room temperature strength compared favourably with many refractory metal-complex-concentrated alloys (RCCAs). The agreement of the predictions of NICE with the experimental results was satisfactory.

Precipitation of NiHfsi phase in NiAl single crystals containing Hf

1995 ◽  
Vol 53 ◽  
pp. 532-533
Author(s):  
A. Garg ◽  
R. D. Noebe ◽  
R. Darolia
Keyword(s):  
High Temperature ◽  
Single Crystals ◽  
High Temperature Strength ◽  
Bridgman Technique ◽  
Shell Mold ◽  
Third Phase ◽  
Unknown Phase ◽  
Transmission Electron ◽  
Two Phases ◽  
Nial Matrix

Small additions of Hf to NiAl produce a significant increase in the high-temperature strength of single crystals. Hf has a very limited solubility in NiAl and in the presence of Si, results in a high density of G-phase (Ni16Hf6Si7) cuboidal precipitates and some G-platelets in a NiAl matrix. These precipitates have a F.C.C structure and nucleate on {100}NiAl planes with almost perfect coherency and a cube-on-cube orientation-relationship (O.R.). However, G-phase is metastable and after prolonged aging at high temperature dissolves at the expense of a more stable Heusler (β'-Ni2AlHf) phase. In addition to these two phases, a third phase was shown to be present in a NiAl-0.3at. % Hf alloy, but was not previously identified (Fig. 4 of ref. 2 ). In this work, we report the morphology, crystal-structure, O.R., and stability of this unknown phase, which were determined using conventional and analytical transmission electron microscopy (TEM).Single crystals of NiAl containing 0.5at. % Hf were grown by a Bridgman technique. Chemical analysis indicated that these crystals also contained Si, which was not an intentional alloying addition but was picked up from the shell mold during directional solidification.

NONDESTRUCTIVE IMPEDANCE SPECTROSCOPY EVALUATION OF THE BOND COAT OXIDATION IN THERMAL BARRIER COATINGS

2007 ◽  
Vol 14 (05) ◽  
pp. 935-943 ◽  
Author(s):  
L. YANG ◽  
Y. C. ZHOU ◽  
W. G. MAO ◽  
Q. X. LIU
Keyword(s):  
Impedance Spectroscopy ◽  
Thermal Barrier Coatings ◽  
Bond Coat ◽  
Equivalent Circuit Model ◽  
Isothermal Oxidation ◽  
Thermally Grown Oxide ◽  
Thermal Barrier ◽  
Air Plasma ◽  
Barrier Coatings ◽  
Plasma Sprayed

In this paper, the impedance spectroscopy technique was employed to examine nondestructively the isothermal oxidation of air plasma sprayed (APS) thermal barrier coatings (TBCs) in air at 800°C. Scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX) were also used to characterize the microstructure evolution of TBCs. After oxidation, the thermally grown oxide (TGO), which was mainly composed of alumina as confirmed by EDX, formed at the upper ceramic coat/bond coat interface, the lower bond coat/substrate interface, and the bond coat. Impedance diagrams obtained from impedance measurements at room temperature were analyzed according to the equivalent circuit model proposed for the TBCs. Various observed electrical responses relating to the growth of oxides and the sintering of YSZ were explained by simulating the impedance spectra of the TBCs.

Isothermal Oxidation of René N5 at 1150°C

2018 ◽  
Author(s):  
Megan Walker ◽  
Xiao Huang
Keyword(s):  
Single Crystal ◽  
Exposure Time ◽  
Bond Coat ◽  
Isothermal Oxidation ◽  
Oxidation Behaviour ◽  
Single Crystal Superalloy ◽  
Short Term ◽  
Alumina Layer ◽  
Spinel Layer ◽  
Oxide Spallation

In this study, single crystal superalloy René N5 was exposed in air at 1150 °C for up to 16 hours to evaluate the alloy’s short-term oxidation behaviour and the potential for developing a no-bond coat TBC system. The results showed that after 1 hour of exposure, a three layered oxide developed on the surface, consisting of spinel, Ta-containing oxide and alumina just above the substrate. After 4 hours of exposure, oxide spallation occurred; this became more pronounced after 16 hours. The oxide spallation took place between the top spinel layer and alumina layer, where Ta-rich oxide was more abundant. All samples tested for 0.5, 1, 2, 4 and 16 hours developed alumina near the substrate while the occurrence of NiO, spinel and Ta-oxides varied, depending upon the exposure time.

Thermal Fatigue Damage Evaluation of EB-PVD TBC Specimens - Its Potential and Problems

2009 ◽  
Vol 631-632 ◽  
pp. 91-96
Author(s):  
Masakazu Okazaki ◽  
S. Yamagishi ◽  
Motoki Sakaguchi ◽  
T. Okamura
Keyword(s):  
Fatigue Damage ◽  
Thermal Fatigue ◽  
Bond Coat ◽  
Physical Vapor Deposition ◽  
Ring Shape ◽  
Evolution Behavior ◽  
Experimental Findings ◽  
Failure Life ◽  
Superalloy In738lc ◽  
Bond Coat Alloys

Thermal fatigue damage evolution behavior in thermal barrier coatings (TBCs) was studied, by employing the originally designed two dimensional ring-shape TBC specimen. The TBC specimen consisted of Ni-based superalloy IN738LC substrate, bond coat, and 8 wt.% Y2O3-stabilized ZrO2 (YSZ) top coat. The top coat was fabricated by electron-beam physical vapor deposition (EB-PVD) method with 250 micron-meters in thickness. Three kinds of MCrAlY bond coat alloys were specified as an experimental variable. Through the work, special attention was paid not only to the failure life of TBC specimen, but also to the underlying failure mechanisms. Some problems have been also pointed out, on feeding back these experimental findings to engineering applications.

Structure/property observations for Al–Ti–Cr intermetallic alloys

1994 ◽  
Vol 9 (2) ◽  
pp. 255-258 ◽  
Author(s):  
J.L. Klansky ◽  
J.P. Nic ◽  
D.E. Mikkola
Keyword(s):  
Mechanical Properties ◽  
Single Phase ◽  
Intermetallic Alloys ◽  
Structure Property ◽  
Multiphase Alloys ◽  
Microstructures And Mechanical Properties ◽  
Two Phases ◽  
The Individual

The microstructures and mechanical properties of single phase and multiphase alloys are reported for Al-rich intermetallic alloys containing up to 45 at. % Ti and as much as 68 at. % Cr. Among the individual phases formed in these alloys, TiAl and tau (Al67Cr8Ti25) had both the lowest hardnesses and the greatest resistance to cracking. Additionally, the presence of these two phases in multiphase alloys improved mechanical properties.

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