scholarly journals Cost Effective Chemical Oxidative Synthesis of Soluble and Electroactive Polyaniline Salt and Its Application as Anticorrosive Agent for Steel

Materials ◽  
2019 ◽  
Vol 12 (9) ◽  
pp. 1527 ◽  
Author(s):  
Anwar-ul-Haq Ali Shah ◽  
Muhammad Kamran ◽  
Salma Bilal ◽  
Rizwan Ullah

The cost effective synthesis of electroactive polyaniline (PANI) while retaining its desirable properties is one of the most debatable and challenging tasks for researchers in the field. Herein, we report a cost effective inverse emulsion polymerization pathway for the synthesis of soluble and processable PANI salt by using diesel as a novel dispersion medium. Different reaction parameters and their effects on the properties and yield of polyaniline were optimized. The polymer exhibited a highly porous morphology and was found to be stable up to 417 °C. The PANI salt showed good solubility in common solvents, such as chloroform, N-Methyl-2-pyrrolidone (NMP), dimethyl sulphoxide (DMSO) and in a 1:3 mixtures by volume of 2-propanol and toluene. The coating of the synthesized PANI salt on stainless steel has shown good corrosion resistant behavior in marine water by reducing the corrosion rate to 67.9% as compared to uncoated stainless steel.

2022 ◽  
Author(s):  
Xiaohong Ding ◽  
Ruilai Liu ◽  
Jiapeng Hu ◽  
Jingyun Zhao ◽  
Jinjin Wu ◽  
...  

The cost-effective synthesis of flexible energy storage devices with high energy and power densities is a challenge in wearable electronics. Here, we report a facile, efficient, and scalable approach for...


2021 ◽  
Author(s):  
Thomas Delaplace ◽  
Morgan Gouriou ◽  
Denis Melot

Abstract This paper presents the investigations performed by TotalEnergies and Saipem on the cost effectiveness potential of internal plastic lining for corrosion protection of offshore production lines. Objective was to better understand for a complete EPCI cost comparison the various parameters that could have a significant impact on the potential savings associated with the use of plastic lining instead of CRAs (Corrosion Resistant Alloys) for very corrosive production fluids such as sour gases. An extensive cost comparison study between CRA lining and plastic lining for offshore production lines was performed considering sensitivity on several parameters: 3 pipe diameters, S-Lay, Reel-Lay and J-Lay installation, sensitivity to external thermal insulation requirements, mechanical and design requirements, to pipe length and fixed costs (technologies and vessels). A dedicated calculation tool for system design and cost assessment was built on purpose for this sensitivity study. Costs were assessed for the various cases, starting from pipe design, then assessing procurement costs, fabrication costs then installation costs with preliminary cycle time assessment. Project management and engineering costs have been considered to obtain comparative EPCI (as installed) cost assessments for the various study cases. Plastic lining appears to be a cost-effective solution installed in J-Lay or S-Lay in addition to reeling (up to 45% of potential cost savings on installed line compared to CRA lining). The main driver for the cost savings is associated to the procurement of the pipes and associated lining, including pipe manufacturing. Some smaller savings can also be obtained from the offshore cycle times in J-Lay and S-Lay as the CRA welding add a significant operation time in comparison with standard CS welds. The fixed additional costs associated to the plastic lining (specific tooling for example) can be quickly amortized after a few kilometers thanks to the material cost savings. Integrating them as a company investment allows to unlock costs savings even for shorter lines. The thermal contribution of the plastic liner is also interesting regarding the overall pipe insulation design. This study completes the works already performed by the industry on the offshore costs of plastic lining as it considers the whole EPCI CAPEX costs from the Contractor and Operator points of view and offshore experience. The study integrates the S-Lay and J-Lay installation methods (while previous studies mainly focused on Reel-Lay) and includes an extensive sensitivity study with various key parameters such as pipe sizes, pipe design requirements, material costs and offshore operation times to get a general overview of potential benefits associated with plastic linings for offshore production lines transporting corrosive fluids such as sour gases.


Author(s):  
Devin M. Wachowiak ◽  
Jason D. Wilson

Coal fired power plants are faced with increasingly strict air quality control laws and EPA rules. New multi-pollutant legislation is controlling a wider range of emissions, especially sulfur compounds. A significant number of flue gas desulfurization (FGD) units worldwide employ wet scrubbing to reduce sulfur dioxide emissions by more than 90 percent. Wet scrubbing has also been found to be effective at removing mercury in many cases. Due to the inherent contaminants generated by the combustion of coal, wet FGD’s require the use of corrosion resistant materials in their construction. A variety of metallic corrosion resistant alloys are currently used in these pollution control systems. This paper will review the use of AL-6XN and Zeron 100 alloys in various FGD applications around the world. Examples of AL-6XN and Zeron 100 in actual service in FGD units will be presented. AL-6XN and Zeron 100 are alloys that have been chosen for these systems when conditions are too severe for either 316L stainless steel or 2205 duplex stainless steel. Experimental data will be reviewed that supports the use of these alloys in the high chloride containing environments encountered by the many components of the pollution control systems. AL-6XN and Zeron 100 alloys have proven to be cost effective materials of construction that fill the gap between the lower alloyed stainless steels such as 317L, 904L, and 2205, and the high molybdenum and nickel based alloys such as C-276. As AL-6XN and Zeron 100 alloys are established materials of construction, they are readily available in product forms necessary to complete an FGD system.


2016 ◽  
Vol 52 (6) ◽  
pp. 1143-1146 ◽  
Author(s):  
Guiyang Li ◽  
Biao Zhang ◽  
Jun Yan ◽  
Zhonggang Wang

Microporous polyaminals are prepared from melamine with furfural and 2-thenaldehyde, respectively, which possess high uptakes for CO2, H2, aromatic and aliphatic vapors, exhibiting potential in gas storage and recovery of toxic organic vapors.


Author(s):  
Bruce A. Pint ◽  
Raphae¨lle Peraldi

As microturbine recuperators are needed to operate at higher temperatures in order to achieve higher engine operating efficiencies, a recurring problem encountered is a severe degradation in environmental resistance of type 347 stainless steel. Above 600°C, stainless steels can experience accelerated attack caused by water vapor, which is often present as a combustion product. Nickel-base alloys are less susceptible to this accelerated attack but their cost is prohibitive. In order to provide a clear, fundamental understanding of alloy composition effects on corrosion resistance of stainless steel components used in recuperators, the oxidation behavior of model alloys is being studied. A composition range of Cr and Ni contents has been identified with better corrosion resistance than type 347 stainless steel. Finer-grained alloys showed improved corrosion resistance compared to coarse-grained alloys with the same composition. It also has been demonstrated that minor alloy additions of Mn and Si are beneficial to corrosion resistance in these environments. This type of information will aid in the development of a corrosion-resistant and cost-effective recuperator material for operation at 650°–700°C.


Carbon ◽  
2015 ◽  
Vol 87 ◽  
pp. 395-408 ◽  
Author(s):  
Ludovic F. Dumée ◽  
Li He ◽  
Ziyu Wang ◽  
Phillip Sheath ◽  
Jianyu Xiong ◽  
...  

Author(s):  
James F. Mancuso

IBM PC compatible computers are widely used in microscopy for applications ranging from control to image acquisition and analysis. The choice of IBM-PC based systems over competing computer platforms can be based on technical merit alone or on a number of factors relating to economics, availability of peripherals, management dictum, or simple personal preference.IBM-PC got a strong “head start” by first dominating clerical, document processing and financial applications. The use of these computers spilled into the laboratory where the DOS based IBM-PC replaced mini-computers. Compared to minicomputer, the PC provided a more for cost-effective platform for applications in numerical analysis, engineering and design, instrument control, image acquisition and image processing. In addition, the sitewide use of a common PC platform could reduce the cost of training and support services relative to cases where many different computer platforms were used. This could be especially true for the microscopists who must use computers in both the laboratory and the office.


Phlebologie ◽  
2007 ◽  
Vol 36 (06) ◽  
pp. 309-312 ◽  
Author(s):  
T. Schulz ◽  
M. Jünger ◽  
M. Hahn

Summary Objective: The goal of the study was to assess the effectiveness and patient tolerability of single-session, sonographically guided, transcatheter foam sclerotherapy and to evaluate its economic impact. Patients, methods: We treated 20 patients with a total of 22 varicoses of the great saphenous vein (GSV) in Hach stage III-IV, clinical stage C2-C5 and a mean GSV diameter of 9 mm (range: 7 to 13 mm). We used 10 ml 3% Aethoxysklerol®. Additional varicoses of the auxiliary veins of the GSV were sclerosed immediately afterwards. Results: The occlusion rate in the treated GSVs was 100% one week after therapy as demonstrated with duplex sonography. The cost of the procedure was 207.91 E including follow-up visit, with an average loss of working time of 0.6 days. After one year one patient showed clinical signs of recurrent varicosis in the GSV; duplex sonography showed reflux in the region of the saphenofemoral junction in a total of seven patients (32% of the treated GSVs). Conclusion: Transcatheter foam sclerotherapy of the GSV is a cost-effective, safe method of treating varicoses of GSV and broadens the spectrum of therapeutic options. Relapses can be re-treated inexpensively with sclerotherapy.


2019 ◽  
Vol 2 (4) ◽  
pp. 260-266
Author(s):  
Haru Purnomo Ipung ◽  
Amin Soetomo

This research proposed a model to assist the design of the associated data architecture and data analytic to support talent forecast in the current accelerating changes in economy, industry and business change due to the accelerating pace of technological change. The emerging and re-emerging economy model were available, such as Industrial revolution 4.0, platform economy, sharing economy and token economy. Those were driven by new business model and technology innovation. An increase capability of technology to automate more jobs will cause a shift in talent pool and workforce. New business model emerge as the availabilityand the cost effective emerging technology, and as a result of emerging or re-emerging economic models. Both, new business model and technology innovation, create new jobs and works that have not been existed decades ago. The future workers will be faced by jobs that may not exist today. A dynamics model of inter-correlation of economy, industry, business model and talent forecast were proposed. A collection of literature review were conducted to initially validate the model.


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