scholarly journals Mineralogical Analysis of Historical Mortars by FTIR

Materials ◽  
2018 ◽  
Vol 12 (1) ◽  
pp. 55
Author(s):  
M. Jordán ◽  
J. Jordá ◽  
F. Pardo ◽  
M. Montero
Keyword(s):  
Experimental Data ◽  
Detection Limit ◽  
Molar Absorptivity ◽  
Band Intensity ◽  
Equation Modeling ◽  
Ftir Analysis ◽  
Mineralogical Analysis ◽  
Molar Absorptivity Coefficient ◽  
First Time

A method for quantitative mineralogical analysis by ATR-FTIR [1] has been used first time for analysis of historical mortars. Mixtures of different minerals and gypsum were used in order to measure the minimum band intensity that must be considered for calculations and the detection limit. In this way, the molar absorptivity coefficient in the Lambert–Beer law and the components of a mixture in mol percentage can be calculated. The GAMS equation modeling environment and the NLP solver CONOPT (©ARKI Consulting and Development) were used to correlate the experimental data in the samples considered. The characterization of the vernacular mortars by FTIR analysis identifies the predominant minerals of the samples, and in conjunction with XRF and XRD, shows the exact composition of historical mortars, which will optimize the restoration and conservation of monuments, preserving our heritage.

scholarly journals High-resolution insights into the early stages of silver nucleation and growth

2015 ◽  
Vol 179 ◽  
pp. 59-77 ◽  
Author(s):  
Cornelia M. Völkle ◽  
Denis Gebauer ◽  
Helmut Cölfen
Keyword(s):  
Experimental Data ◽  
Silver Nanoparticles ◽  
Early Growth ◽  
Nucleation And Growth ◽  
Silver Clusters ◽  
Computational Tools ◽  
Analytical Characterization ◽  
Titration Assay ◽  
First Time

Nucleation and growth of silver nanoparticles has already been investigated with various experimental and computational tools. However, owing to inherent problems associated with the analytical characterization of nucleation processes, there is a general lack of experimental data regarding the earliest precursors and smallest Ag(0) clusters. Here, we address this problem by the application of Synthetic Boundary Crystallization Ultracentrifugation, utilizing a multiwavelength detector for the first time, complemented by a specialized titration assay. These techniques shed new light on silver nanoparticle precursors existing in the pre-nucleation regime, and the initially nucleated ensemble of nanoclusters. For the first time, we present experimental data of UV-Vis spectra for fractionated silver clusters. These allow for unsurpassed insights into the sequence of nucleation and early growth species as well as their optical properties.

scholarly journals Synthesis and Characterization of Aminophosphonates Zirconium as New Mesoporous Materials

2012 ◽  
Vol 9 (3) ◽  
pp. 1320-1326
Author(s):  
Liang Zhou
Keyword(s):  
Experimental Data ◽  
Zirconium Phosphate ◽  
Layer Structure ◽  
Nitrogen Adsorption ◽  
Synthesis And Characterization ◽  
Good Thermal Stability ◽  
Ft Ir ◽  
Adsorption Desorption ◽  
First Time

A serial of aminophosphonates zirconium with the different arm lengths of –(CH2)n– organic chains (n=2–6) was synthesized for the first time. These compounds are characterized by FT-IR, SEM, TEM, TG and nitrogen adsorption-desorption. And based on the experimental data, these materials not only have layer structure mesoporous and good thermal stability such as zirconium phosphate, but also can be adjusted the layer distance, pore size and pore volume. So aminophosphonates zirconium posses special excellent properties and will have potential prospect applications.

Green Crystallization and Characterization of Copper Oxide (CuO) Nanoparticles Using Anacardium occidentale Shell Liquid and their Biomedical Applications

2016 ◽  
Vol 40 ◽  
pp. 167-173 ◽  
Author(s):  
P. Velmurugan ◽  
S.H. Jang ◽  
S.C. Hong ◽  
P.I. Yi ◽  
E.S. Jung ◽  
...  
Keyword(s):  
Biomedical Applications ◽  
Ftir Analysis ◽  
Cashew Nut Shell Liquid ◽  
Cuo Nps ◽  
Cashew Nut ◽  
Cuo Nanocrystals ◽  
Cashew Nut Shell ◽  
20 Nm ◽  
First Time

For the first time, we describe the production of nanocrystalline CuO particles using cashew nut shell liquid (CNSL). The effects of CSNL dosage, reaction duration, and concentrations on copper reduction and nanoparticle formation were studied. The resulting nanoparticles were characterized using TEM, XRD and FTIR analysis. The syntheses of nano-sized CuO NPs were confirmed via TEM and XRD and show the presence of well-dispersed CuO NPs ranging from 15 to 20 nm. The results confirm that CuO nanocrystals have high antibacterial efficacy and hence have great potential in the preparation of drugs against bacteria.

TBE in Sweden

2020 ◽  
Keyword(s):  
Genetic Characterization ◽  
Immunoglobulin M ◽  
Enzyme Linked Immunosorbent Assay ◽  
Second Phase ◽  
Serum Samples ◽  
Tick Borne Encephalitis ◽  
Specific Immunoglobulin ◽  
Tick Borne Encephalitis Virus ◽  
First Time

Tick-borne encephalitis virus (TBEV) was isolated for the first time in Sweden in 1958 (from ticks and from 1 tick-borne encephalitis [TBE] patient).1 In 2003, Haglund and colleagues reported the isolation and antigenic and genetic characterization of 14 TBEV strains from Swedish patients (samples collected 1991–1994).2 The first serum sample, from which TBEV was isolated, was obtained 2–10 days after onset of disease and found to be negative for anti-TBEV immunoglobulin M (IgM) by enzyme-linked immunosorbent assay (ELISA), whereas TBEV-specific IgM (and TBEV-specific immunoglobulin G/cerebrospinal fluid [IgG/CSF] activity) was demonstrated in later serum samples taken during the second phase of the disease.

Colorimetric Determination of Fluoride in Drinking Groundwater using a Polymeric Zirconium Complex of 5-(2-Carboxyphenylazo)-8-Hydroxyquinoline

2013 ◽  
Vol 12 (7) ◽  
pp. 460-465
Author(s):  
Sameer Amereih ◽  
Zaher Barghouthi ◽  
Lamees Majjiad
Keyword(s):  
Drinking Water ◽  
Detection Limit ◽  
Complex Formation ◽  
Molar Absorptivity ◽  
Colorimetric Determination ◽  
Zirconium Complex ◽  
Reliable Determination ◽  
Percentage Recovery ◽  
Quantitation Limit

A sensitive colorimetric determination of fluoride in drinking water has been developed using a polymeric zirconium complex of 5-(2-Carboxyphenylazo)-8-Hydroxyquinoline as fluoride reagents. The method allowed a reliable determination of fluoride in range of (0.0-1.5) mg L-1. The molar absorptivity of the complex formation is 7695 ± 27 L mol-1 cm-1 at 460 nm. The sensitivity, detection limit, quantitation limit, and percentage recovery for 1.0 mg L-1 fluoride for the proposed method were found to be 0.353 ± 0.013 μg mL-1, 0.1 mg L-1, 0.3 mg L-1, and 101.7 ± 4.1, respectively.

Chemical Constituents and Antibacterial Activity of Cissus Aralioides.

2020 ◽  
Vol 17 ◽  
Author(s):  
Balogun Olaoye Solomon ◽  
Ajayi Olukayode Solomon ◽  
Owolabi Temitayo Abidemi ◽  
Oladimeji Abdulkarbir Oladele ◽  
Liu Zhiqiang
Keyword(s):  
Plant Extract ◽  
Chemical Constituents ◽  
Ethyl Acetate Fraction ◽  
Antibacterial Activities ◽  
Sub Saharan Africa ◽  
Chromatographic Purification ◽  
Whole Plant ◽  
Sub Saharan ◽  
First Time

: Cissus aralioides is a medicinal plant used in sub-Saharan Africa for treatment of infectious diseases; however the chemical constituents of the plant have not been investigated. Thus, in this study, attempt was made at identifying predominant phytochemical constituents of the plant through chromatographic purification and silylation of the plant extract, and subsequent characterization using spectroscopic and GC-MS techniques. The minimum inhibitory concentration (MICs) for the antibacterial activities of the plant extract, chromatographic fractions and isolated compounds were also examined. Chromatographic purification of the ethyl acetate fraction from the whole plant afforded three compounds: β-sitosterol (1), stigmasterol (2) and friedelin (3). The phytosterols (1 and 2) were obtained together as a mixture. The GC-MS analysis of silylated extract indicated alcohols, fatty acids and sugars as predominant classes, with composition of 24.62, 36.90 and 26.52% respectively. Results of MICs indicated that friedelin and other chromatographic fractions had values (0.0626-1.0 mg/mL) comparable with the standard antibiotics used. Characterization of natural products from C. aralioides is being reported for the first time in this study.

Green Synthesis and Spectroscopic Studies of Ag-rGO Nanocomposites for Highly Selective Mercury (II) Sensing

2018 ◽  
Vol 9 (1) ◽  
pp. 101-108 ◽  
Author(s):  
Shubhangi J. Mane-Gavade ◽  
Sandip R. Sabale ◽  
Xiao-Ying Yu ◽  
Gurunath H. Nikam ◽  
Bhaskar V. Tamhankar
Keyword(s):  
Green Synthesis ◽  
Color Change ◽  
Limit Of Detection ◽  
Aqueous Media ◽  
Suitable Condition ◽  
Cost Effective ◽  
Spectroscopic Studies ◽  
Calibration Plot ◽  
First Time

Introduction: Herein we report the green synthesis and characterization of silverreduced graphene oxide nanocomposites (Ag-rGO) using Acacia nilotica gum for the first time. Experimental: We demonstrate the Hg2+ ions sensing ability of the Ag-rGO nanocomposites form aqueous medium. The developed colorimetric sensor method is simple, fast and selective for the detection of Hg2+ ions in aqueous media in presence of other associated ions. A significant color change was noticed with naked eye upon Hg2+ addition. The color change was not observed for cations including Sr2+, Ni2+, Cd2+, Pb2+, Mg2+, Ca2+, Fe2+, Ba2+ and Mn2+indicating that only Hg2+ shows a strong interaction with Ag-rGO nanocomposites. Under the most suitable condition, the calibration plot (A0-A) against concentration of Hg2+ was linear in the range of 0.1-1.0 ppm with a correlation coefficient (R2) value 0.9998. Results & Conclusion The concentration of Hg2+ was quantitatively determined with the Limit of Detection (LOD) of 0.85 ppm. Also, this method shows excellent selectivity towards Hg2+ over nine other cations tested. Moreover, the method offers a new cost effective, rapid and simple approach for the detection of Hg2+ in water samples.

Simulation of Laminar Liquid Jets in Gaseous Crossflow Before the Onset of Primary Breakup

2011 ◽  
Author(s):  
C.-L. Ng ◽  
K. A. Sallam
Keyword(s):  
Experimental Data ◽  
Fuel Injection ◽  
Liquid Jets ◽  
Liquid Jet ◽  
Jet Breakup ◽  
Primary Breakup ◽  
Density Ratios ◽  
First Time ◽  
Two Sides ◽  
Reduced Pressures

The deformation of laminar liquid jets in gaseous crossflow before the onset of primary breakup is studied motivated by its application to fuel injection in jet afterburners and agricultural sprays, among others. Three crossflow Weber numbers that represent three different liquid jet breakup regimes; column, bag, and shear breakup regimes, were studied at large liquid/gas density ratios and small Ohnesorge numbers. In each case the liquid jet was simulated from the jet exit and ended before the location where the experimental data indicated the onset of breakup. The results show that in column and bag breakup, the reduced pressures along the sides of the jet cause the liquid to move to the sides of the jet and enhance the jet deformation. In shear breakup, the flattened upwind surface pushes the liquid towards the two sides of the jet and causing the gaseous crossflow to separate near the edges of the liquid jet thus preventing further deformation before the onset of breakup. It was also found out that in shear breakup regime, the liquid phase velocity inside the liquid jet was large enough to cause onset of ligament formation along the jet side, which was not the case in the column and bag breakup regimes. In bag breakup, downwind surface waves were observed to grow along the sides of the liquid jet triggered a complimentary experimental study that confirmed the existence of those waves for the first time.

scholarly journals Waste-Based One-Part Alkali Activated Materials

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2911
Author(s):  
Margarida Gonçalves ◽  
Inês Silveirinha Vilarinho ◽  
Marinélia Capela ◽  
Ana Caetano ◽  
Rui Miguel Novais ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Microstructural Analysis ◽  
Construction Materials ◽  
Sodium Metasilicate ◽  
High Compressive Strength ◽  
Hardened State ◽  
First Time ◽  
Furnace Slag ◽  
Alkali Activated

Ordinary Portland Cement is the most widely used binder in the construction sector; however, a very high carbon footprint is associated with its production process. Consequently, more sustainable alternative construction materials are being investigated, namely, one-part alkali activated materials (AAMs). In this work, waste-based one-part AAMs binders were developed using only a blast furnace slag, as the solid precursor, and sodium metasilicate, as the solid activator. For the first time, mortars in which the commercial sand was replaced by two exhausted sands from biomass boilers (CA and CT) were developed. Firstly, the characterization of the slag and sands (aggregates) was performed. After, the AAMs fresh and hardened state properties were evaluated, being the characterization complemented by FTIR and microstructural analysis. The binder and the mortars prepared with commercial sand presented high compressive strength values after 28 days of curing-56 MPa and 79 MPa, respectively. The mortars developed with exhausted sands exhibit outstanding compressive strength values, 86 and 70 MPa for CT and CA, respectively, and the other material’s properties were not affected. Consequently, this work proved that high compressive strength waste-based one-part AAMs mortars can be produced and that it is feasible to use another waste as aggregate in the mortar’s formulations: the exhausted sands from biomass boilers.

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