scholarly journals Single Chiral Skyrmions in Ultrathin Magnetic Films

Materials ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 2238 ◽  
Author(s):  
Arantxa Aranda ◽  
Konstantin Guslienko
Keyword(s):  
Crystal Structure ◽  
Ultrathin Films ◽  
Magnetic Films ◽  
Critical Value ◽  
Wall Model ◽  
Cubic Crystal ◽  
Out Of Plane ◽  
The Stability ◽  
The One ◽  
Isotropic Exchange

The stability and sizes of chiral skyrmions in ultrathin magnetic films are calculated accounting for the isotropic exchange, Dzyaloshinskii–Moriya exchange interaction (DMI), and out-of-plane magnetic anisotropy within micromagnetic approach. Bloch skyrmions in ultrathin magnetic films with B20 cubic crystal structure (MnSi, FeGe) and Neel skyrmions in ultrathin films and multilayers Co/X (X = Ir, Pd, Pt) are considered. The generalized DeBonte ansatz is used to describe the inhomogeneous skyrmion magnetization. The single skyrmion metastability/instability area, skyrmion radius, and skyrmion width are found analytically as a function of DMI strength d . It is shown that the single chiral skyrmions are metastable in infinite magnetic films below a critical value of DMI d c , and do not exist at d > d c . The calculated skyrmion radius increases as d increases and diverges at d → d c − 0 , whereas the skyrmion width increases monotonically as d increases up to d c without any singularities. The calculated skyrmion width is essentially smaller than the one calculated within the generalized domain wall model.

scholarly journals On the stability for three-dimensional disturbances of viscous fluid flow between parallel walls

1933 ◽  
Vol 142 (847) ◽  
pp. 621-628 ◽  
Keyword(s):  
Reynolds Number ◽  
Three Dimensional ◽  
Finite Size ◽  
Critical Value ◽  
The Stability ◽  
The One ◽  
Von Mises ◽  
Shearing Motion ◽  
Determining Factor ◽  
Good Agreement

The turbulence problem is still unsolved, through a number of valuable papers have been published on it comparatively recently. But, since Hopf and von Mises proved that uniform shearing motion between two parallel planes was stable for infinitesimal disturbances but unstable for disturbances of a finite size has become more and more widely held. Von mises suggested that the reoughness of the walls might be the determining factor, but the experiments of Schiller have shown that the degree of roughness of the walls is of negligible influence on the critical value of Reynold's number. He concluded that the breakdown of laminar flow depended primarily on the size of the initial disturbance, in agreement eith Osborne Reynold's view. Important papers have been published by Noether and Tollmien, whose conclusions are in contradiction to one another. On the one hand, Noether, by a formal investigation of the asymptotic solutions of the equation governing the two-dimensional disturbances of flow between parallel walls, claims to have proved that all velocity profiles are stable for all values of Reynolds' number. On the other hand, Tollmien has determined a critical value of Reynolds' number for the flow past a flat plate placed edgeways to the stream. This value is in good agreement with the experimental results. There are, however, certain points in his analysis which are not clear and it would be useful to know if the method gave results in agreement with those derived more strictly.

Relative stability of LI2, DO22, and DO23 structures in MAl3 compounds

1989 ◽  
Vol 4 (5) ◽  
pp. 1060-1063 ◽  
Author(s):  
A. E. Carlsson ◽  
P. J. Meschter
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Energy Difference ◽  
Group Iv ◽  
Group V ◽  
Group Iii ◽  
Densities Of States ◽  
Electronic Densities ◽  
The Stability ◽  
The One

The structural energy differences between cubic LI2 and tetragonal DO22 crystal structures are calculated for MAl3 compounds, where M is a group III, IV, or V transition metal. The stability of the DO22 structure relative to L12 increases rapidly as the transition-metal d-electron count increases. Typical values of E(DO22) – E(L12) are 0.1–0.15 eV/atom (9600–14500 J/g-atom) for group III,  0.05 eV/atom ( 4800 J/g-atom) for group IV, and ∼ –0.2 eV/atom (∼ –19000 J/g-atom) for group V trialuminides. Similar trends are calculated for the DO23/L12 energy difference. The calculated electronic densities of states (DOS) show that each structure has a minimum in the DOS distribution at a characteristic d-electron count. The preferred crystal structure for a given compound is the one in which the Fermi level lies in the minimum.

Use of a Lyophilized Reference Plasma to Compare Coagulation Test Procedures

1975 ◽  
Vol 34 (02) ◽  
pp. 426-444 ◽  
Author(s):  
J Kahan ◽  
I Nohén
Keyword(s):  
Oral Anticoagulant Therapy ◽  
Repeated Measurements ◽  
Test Procedures ◽  
Coagulation Activity ◽  
Close Relationship ◽  
Measured Activity ◽  
Test Materials ◽  
The Difference ◽  
The Stability ◽  
The One

SummaryIn 4 collaborative trials, involving a varying number of hospital laboratories in the Stockholm area, the coagulation activity of different test materials was estimated with the one-stage prothrombin tests routinely used in the laboratories, viz. Normotest, Simplastin-A and Thrombotest. The test materials included different batches of a lyophilized reference plasma, deep-frozen specimens of diluted and undiluted normal plasmas, and fresh and deep-frozen specimens from patients on long-term oral anticoagulant therapy.Although a close relationship was found between different methods, Simplastin-A gave consistently lower values than Normotest, the difference being proportional to the estimated activity. The discrepancy was of about the same magnitude on all the test materials, and was probably due to a divergence between the manufacturers’ procedures used to set “normal percentage activity”, as well as to a varying ratio of measured activity to plasma concentration. The extent of discrepancy may vary with the batch-to-batch variation of thromboplastin reagents.The close agreement between results obtained on different test materials suggests that the investigated reference plasma could be used to calibrate the examined thromboplastin reagents, and to compare the degree of hypocoagulability estimated by the examined PIVKA-insensitive thromboplastin reagents.The assigned coagulation activity of different batches of the reference plasma agreed closely with experimentally obtained values. The stability of supplied batches was satisfactory as judged from the reproducibility of repeated measurements. The variability of test procedures was approximately the same on different test materials.

Structure, Stability and Water Adsorption on Ultra-Thin TiO2 Supported on TiN

2019 ◽  
Author(s):  
Jose Julio Gutierrez Moreno ◽  
Marco Fronzi ◽  
Pierre Lovera ◽  
alan O'Riordan ◽  
Mike J Ford ◽  
...  
Keyword(s):  
Density Functional ◽  
Water Adsorption ◽  
Chemical Potential ◽  
Energy Gap ◽  
Molecular Water ◽  
Structure Stability ◽  
Ambient Conditions ◽  
Rutile Structure ◽  
The Stability ◽  
The One

<p></p><p>Interfacial metal-oxide systems with ultrathin oxide layers are of high interest for their use in catalysis. In this study, we present a density functional theory (DFT) investigation of the structure of ultrathin rutile layers (one and two TiO<sub>2</sub> layers) supported on TiN and the stability of water on these interfacial structures. The rutile layers are stabilized on the TiN surface through the formation of interfacial Ti–O bonds. Charge transfer from the TiN substrate leads to the formation of reduced Ti<sup>3+</sup> cations in TiO<sub>2.</sub> The structure of the one-layer oxide slab is strongly distorted at the interface, while the thicker TiO<sub>2</sub> layer preserves the rutile structure. The energy cost for the formation of a single O vacancy in the one-layer oxide slab is only 0.5 eV with respect to the ideal interface. For the two-layer oxide slab, the introduction of several vacancies in an already non-stoichiometric system becomes progressively more favourable, which indicates the stability of the highly non-stoichiometric interfaces. Isolated water molecules dissociate when adsorbed at the TiO<sub>2</sub> layers. At higher coverages the preference is for molecular water adsorption. Our ab initio thermodynamics calculations show the fully water covered stoichiometric models as the most stable structure at typical ambient conditions. Interfacial models with multiple vacancies are most stable at low (reducing) oxygen chemical potential values. A water monolayer adsorbs dissociatively on the highly distorted 2-layer TiO<sub>1.75</sub>-TiN interface, where the Ti<sup>3+</sup> states lying above the top of the valence band contribute to a significant reduction of the energy gap compared to the stoichiometric TiO<sub>2</sub>-TiN model. Our results provide a guide for the design of novel interfacial systems containing ultrathin TiO<sub>2</sub> with potential application as photocatalytic water splitting devices.</p><p></p>

scholarly journals Stability of a one-dimensional morphoelastic model for post-burn contraction

2021 ◽  
Vol 83 (3) ◽  
Author(s):  
Ginger Egberts ◽  
Fred Vermolen ◽  
Paul van Zuijlen
Keyword(s):  
Wound Healing ◽  
Residual Stresses ◽  
Truncation Error ◽  
Signaling Molecules ◽  
Discrete Problem ◽  
One Dimensional ◽  
Stability Constraint ◽  
Biological Interpretation ◽  
The Stability ◽  
The One

AbstractTo deal with permanent deformations and residual stresses, we consider a morphoelastic model for the scar formation as the result of wound healing after a skin trauma. Next to the mechanical components such as strain and displacements, the model accounts for biological constituents such as the concentration of signaling molecules, the cellular densities of fibroblasts and myofibroblasts, and the density of collagen. Here we present stability constraints for the one-dimensional counterpart of this morphoelastic model, for both the continuous and (semi-) discrete problem. We show that the truncation error between these eigenvalues associated with the continuous and semi-discrete problem is of order $${{\mathcal {O}}}(h^2)$$ O ( h 2 ) . Next we perform numerical validation to these constraints and provide a biological interpretation of the (in)stability. For the mechanical part of the model, the results show the components reach equilibria in a (non) monotonic way, depending on the value of the viscosity. The results show that the parameters of the chemical part of the model need to meet the stability constraint, depending on the decay rate of the signaling molecules, to avoid unrealistic results.

scholarly journals Stability of nonaxisymmetric ferrofluid flow in rotating cylinders with magnetic field

2005 ◽  
Vol 2005 (23) ◽  
pp. 3727-3737 ◽  
Author(s):  
Jitender Singh ◽  
Renu Bajaj
Keyword(s):  
Magnetic Field ◽  
Applied Magnetic Field ◽  
Critical Value ◽  
Annular Space ◽  
Rotating Cylinders ◽  
The Stability

Effect of an axially applied magnetic field on the stability of a ferrofluid flow in an annular space between two coaxially rotating cylinders with nonaxisymmetric disturbances has been investigated numerically. The critical value of the ratioΩ∗of angular speeds of the two cylinders, at the onset of the first nonaxisymmetric mode of disturbance, has been observed to be affected by the applied magnetic field.

scholarly journals Generalization of intrinsic ductile-to-brittle criteria by Pugh and Pettifor for materials with a cubic crystal structure

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
O. N. Senkov ◽  
D. B. Miracle
Keyword(s):  
Crystal Structure ◽  
Shear Modulus ◽  
Bulk Modulus ◽  
Single Crystal ◽  
Elastic Constants ◽  
Mechanical Analysis ◽  
Quantum Mechanical ◽  
Modulus Ratio ◽  
Cubic Crystal ◽  
The Difference

AbstractTwo classical criteria, by Pugh and Pettifor, have been widely used by metallurgists to predict whether a material will be brittle or ductile. A phenomenological correlation by Pugh between metal brittleness and its shear modulus to bulk modulus ratio was established more than 60 years ago. Nearly four decades later Pettifor conducted a quantum mechanical analysis of bond hybridization in a series of intermetallics and derived a separate ductility criterion based on the difference between two single-crystal elastic constants, C12–C44. In this paper, we discover the link between these two criteria and show that they are identical for materials with cubic crystal structures.

scholarly journals Out-of-plane local mechanism analysis with finite element method

2021 ◽  
Vol 8 (1) ◽  
pp. 130-136
Author(s):  
Roberto Spagnuolo
Keyword(s):  
Finite Element ◽  
Masonry Walls ◽  
Finite Element Models ◽  
Mechanism Analysis ◽  
Fem Method ◽  
Local Mechanism ◽  
Out Of Plane ◽  
Smeared Crack ◽  
The Stability ◽  
No Tension Material

Abstract The stability check of masonry structures is a debated problem in Italy that poses serious problems for its extensive use. Indeed, the danger of out of plane collapse of masonry walls, which is one of the more challenging to evaluate, is traditionally addressed not using finite element models (FEM). The power of FEM is not properly used and some simplified method are preferred. In this paper the use of the thrust surface is suggested. This concept allows to to evaluate the eccentricity of the membrane stresses using the FEM method. For this purpose a sophisticated, layered, finite element with a no-tension material is used. To model a no-tension material we used the smeared crack method as it is not mesh-dependent and it is well known since the early ’80 in an ASCE Report [1]. The described element has been implemented by the author in the program Nòlian by Softing.

scholarly journals One-Dimensional Organic–Inorganic Material (C6H9N2)2BiCl5: From Synthesis to Structural, Spectroscopic, and Electronic Characterizations

2021 ◽  
Vol 22 (4) ◽  
pp. 2030
Author(s):  
Hela Ferjani ◽  
Hammouda Chebbi ◽  
Mohammed Fettouhi
Keyword(s):  
Hydrogen Bonding ◽  
Density Functional ◽  
Crystal Packing ◽  
Diffuse Reflectance Spectrum ◽  
Enrichment Ratio ◽  
One Dimensional ◽  
Organic Part ◽  
Fukui Indices ◽  
The Stability ◽  
The One

The new organic–inorganic compound (C6H9N2)2BiCl5 (I) has been grown by the solvent evaporation method. The one-dimensional (1D) structure of the allylimidazolium chlorobismuthate (I) has been determined by single crystal X-ray diffraction. It crystallizes in the centrosymmetric space group C2/c and consists of 1-allylimidazolium cations and (1D) chains of the anion BiCl52−, built up of corner-sharing [BiCl63−] octahedra which are interconnected by means of hydrogen bonding contacts N/C–H⋯Cl. The intermolecular interactions were quantified using Hirshfeld surface analysis and the enrichment ratio established that the most important role in the stability of the crystal structure was provided by hydrogen bonding and H···H interactions. The highest value of E was calculated for the contact N⋯C (6.87) followed by C⋯C (2.85) and Bi⋯Cl (2.43). These contacts were favored and made the main contribution to the crystal packing. The vibrational modes were identified and assigned by infrared and Raman spectroscopy. The optical band gap (Eg = 3.26 eV) was calculated from the diffuse reflectance spectrum and showed that we can consider the material as a semiconductor. The density functional theory (DFT) has been used to determine the calculated gap, which was about 3.73 eV, and to explain the electronic structure of the title compound, its optical properties, and the stability of the organic part by the calculation of HOMO and LUMO energy and the Fukui indices.

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