scholarly journals Physical and Mechanical Properties of Poplar Wood Modified by Glucose-Urea-Melamine Resin/Sodium Silicate Compound

Forests ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 127
Author(s):  
Qiangqiang Liu ◽  
Haojia Du ◽  
Wenhua Lyu

In order to improve the performance of soft plantation wood, an environmentally friendly wood modifier was developed. First, using urea and melamine as crosslinking agents, the glucose-urea-melamine resin (MUG) was prepared with glucose under the catalysis of inorganic acid and metal ions. Then MUG, sodium silicate, and distilled water were mixed and stirred at 40 °C to prepare MUG resin/sodium silicate compound modifier (G20S10, G10S20, the subscript number represents the mass percentage of the component in the solution.). Then plantation poplar wood (Populus tomentosa) was impregnated and modified with them. Their physical and mechanical properties were tested and compared with those of the wood treated with sodium silicate of 20% mass fraction (S20). Infrared analysis showed that the amino resin characteristic structure (CO-NH-) existed in MUG, and the absorption peak of the furan ring (C=C) appeared. Compared with S20 modified wood, the shrinkage degree of G10S20 or G20S10 modified wood is reduced, their moisture absorption is decreased, and their dimensional stability is improved. MUG resin/sodium silicate compound modifier can effectively enhance the wood’s density, modulus of elasticity, modulus of rupture, and compression strength. SEM analysis showed that there were columnar and granular solid substances attached to the cell wall, cell lumen, intercellular space, and vessel of G20S10 modified wood. EDX showed that the number of Si elements on the cell wall was significantly increased compared with the control, indicating that the modifier effectively entered the wood cell wall. The G20S10 can greatly improve the wood’s physical and mechanical properties through an organic–inorganic compound synergistic effect. It is a green, non-formaldehyde, low cost wood modifier with broad application prospects.

Author(s):  
Qiangqiang Liu ◽  
Haojia Du ◽  
Wenhua Lyu

In order to improve the performance of soft plantation wood, an environmentally friendly inorganic-organic hybrid wood modifier was developed. First, using urea and melamine as crosslinking agents, the waterborne glucose silicone resin (MUG) was prepared with glucose under the catalysis of inorganic acid and metal ions. Then MUG resin was diluted to 10% and 20% mass fraction, and compounded with sodium silicate (S) of 20% and 10% mass fraction, so the inorganic-organic hybrid G10S20 and G20S10 wood modifier were obtained respectively. Then plantation poplar wood (Populus tomentosa) were impregnated and modified with them. Their physical and mechanical properties were tested and compared with those of the wood treated with S of 20% mass fraction (S20). Infrared analysis showed that amino resin characteristic structure (CO-NH-) existed in MUG resin. The resin has good permeability. Compared with S20 modified wood, the degree of shrinkage of G10S20 or G20S10 modified wood is reduced, their moisture absorption is reduced, and their dimensional stability is improved. Waterborne glucose silicone modifier can effectively improve the wood density, modulus of elasticity, modulus of rapture and compression strength. SEM analysis showed that the cell wall of G20S10 modified wood was significantly thicker than the untreated wood, and there were columnar and granular solid substances attached in some cell cavities, ducts and corners, etc. EDX showed that the number of Si elements on the cell wall was significantly increased compared with the control, indicating that the modifier effectively entered the wood cell wall. The waterborne glucose silicone resin can greatly improve the physical and mechanical properties of wood through organic-inorganic hybridization. It is a green, non-formaldehyde, eco-friendly, low cost, compound wood modifier with broad application prospects.


Holzforschung ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Jianfeng Xu ◽  
Xiaoyan Li ◽  
Ling Long ◽  
Ru Liu

AbstractIn this work, a novel waterborne hyperbranched polyacrylate (HBPA) dispersed organo-montmorillonite (OMMT) emulsion was synthesized and used for the treatment of wood in a vacuum environment in order to enhance the physical and mechanical properties of the wood. The sapwood of Cathay poplar (Populus cathayana Rehd.) and Radiata pine (Pinus radiata D.Don) were used as the samples for experimentation. The results showed that the physical and mechanical properties of the wood improved significantly due to the successful penetration of the OMMT and HBPA into the wood cell wall. From it was also observed that OMET completely exfoliated from the HBPA matrix and formed a hydrophobic film covering on the inside walls of the cell lumen. Further, it was observed that the poplar sample displayed better mechanical properties than the pine sample because the pine has a more compact structure when compared to poplar and contains rosin. Furthermore, it was also observed that the mechanical properties of the modified wood sample gradually improved with an increase in the concentration of the emulsion. However, excessive concentration (>4 wt%) did not lead to further improvement.


2014 ◽  
Vol 926-930 ◽  
pp. 242-245
Author(s):  
Yong Wang ◽  
Ze Jun Chen ◽  
La Yun Deng ◽  
You Hua Fan

The paper based on a comparative study between poplar wood and modified poplar wood, concerning dimensional stability, physical and mechanical properties. The result showed that air-dry density and ASE value of modified wood samples were increasing in different levels with change of the modifier concentration, compared with untreated poplar wood. The air-dry density of modified wood reached 0.41 g/cm3 with increase of 5.3% compared to poplar wood. ASE reached 47.8% and the water-absorption ratio decreased by 38% at most when the modifier concentration was 30 wt.%. Moreover, the MOE and MOR of modified poplar wood increased up to 27.4% and 13% respectively when the modifier concentration was 25 wt.%. The SEM spectrum showed some wood rays and the gaps between staggered fibers were filled by modifier.


2012 ◽  
Vol 576 ◽  
pp. 314-317
Author(s):  
Sinin Hamdan ◽  
M. Saiful Islam

Five types of selected tropical light hardwoods were chemically modified with benzene diazonium salt to improve their physical and mechanical properties. Benzene diazonium salt underwent a coupling reaction with wood which was confirmed through FT-IR analysis. The compressive modulus of the treated wood increased, whereas modulus of rupture was shown to decrease on treatment. The modified wood samples had higher hardness (Shore D) values compared to that of the control ones.


2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Chatree Homkhiew ◽  
Surasit Rawangwong ◽  
Worapong Boonchouytan ◽  
Wiriya Thongruang ◽  
Thanate Ratanawilai

The aim of this work is to investigate the effects of rubberwood sawdust (RWS) size and content as well as the ratio of natural rubber (NR)/high-density polyethylene (HDPE) blend on properties of RWS reinforced thermoplastic natural rubber (TPNR) composites. The addition of RWS about 30–50 wt% improved the modulus of the rupture and tensile strength of TPNR composites blending with NR/HDPE ratios of 60/40 and 50/50. TPNR composites reinforced with RWS 80 mesh yielded better tensile strength and modulus of rupture than the composites with RWS 40 mesh. The TPNR/RWS composites with larger HDPE content gave higher tensile, flexural, and Shore hardness properties and thermal stability as well as lower water absorption. The TPNR/RWS composites with larger plastic content were therefore suggested for applications requiring high performance of thermal, physical, and mechanical properties.


2017 ◽  
Vol 41 (1) ◽  
Author(s):  
Mírian de Almeida Costa ◽  
Cláudio Henrique Soares Del Menezzi

ABSTRACT Thermo-mechanical treatment is a technique for wood modification in which samples are densified by means of heat and mechanical compression, applied perpendicularly to fibers, which under different combinations of time, temperature, and pressure increases wood density and thus improve some of its properties. This study aimed to treat thermo-mechanically parica plywood and observe the effects on its physical and mechanical properties. Specimens were submitted to two treatments, 120 and 150 ºC, remaining under pressure for seven minutes and, subsequently, under zero pressure for 15 minutes. Results showed a significant increase in specific mass from 0.48 g cm-3 to an average of 0.56 g cm-3, and a compression ratio of about 31.7% on average. Physical properties also varied significantly and results showed that treated samples swelled and absorbed more water than those untreated, leading to a greater thickness non-return rate. This indicates the proposed thermal treatments did not release the internal compressive stress generated during panel pressing, not improving its dimensional stability as a result. On the other hand, mechanical properties were positively affected, leading to an increase of 27.5% and 51.8% in modulus of rupture after treatments at 120 and 150 ºC, respectively. Modulus of elasticity and glue-line shear strength did not vary statistically and Janka hardness was 29.7% higher after treatment at 150 ºC.


Forests ◽  
2021 ◽  
Vol 12 (11) ◽  
pp. 1462
Author(s):  
Ján Iždinský ◽  
Zuzana Vidholdová ◽  
Ladislav Reinprecht

In recent years, the production and consumption of thermally modified wood (TMW) has been increasing. Offcuts and other waste generated during TMWs processing into products, as well as already disposed products based on TMWs can be an input recycled raw material for production of particleboards (PBs). In a laboratory, 16 mm thick 3-layer PBs bonded with urea-formaldehyde (UF) resin were produced at 5.8 MPa, 240 °C and 8 s pressing factor. In PBs, the particles from fresh spruce wood and mixed particles from offcuts of pine, beech, and ash TMWs were combined in weight ratios of 100:0, 80:20, 50:50 and 0:100. Thickness swelling (TS) and water absorption (WA) of PBs decreased with increased portion of TMW particles, i.e., TS after 24 h maximally about 72.3% and WA after 24 h maximally about 64%. However, mechanical properties of PBs worsened proportionally with a higher content of recycled TMW—apparently, the modulus of rupture (MOR) up to 55.5% and internal bond (IB) up to 46.2%, while negative effect of TMW particles on the modulus of elasticity (MOE) was milder. Decay resistance of PBs to the brown-rot fungus Serpula lacrymans (Schumacher ex Fries) S.F.Gray increased if they contained TMW particles, maximally about 45%, while the mould resistance of PBs containing TMW particles improved only in the first days of test. In summary, the recycled TMW particles can improve the decay and water resistance of PBs exposed to higher humidity environment. However, worsening of their mechanical properties could appear, as well.


2019 ◽  
Vol 7 (1) ◽  
Author(s):  
. Erma ◽  
Fadiilah H Usman ◽  
. Muflihati

Physical and mechanical properties of wood is one of the basic properties that need to be known in the selection of wood, because the physical and mechanical properties of wood are not the same height on the stem. Increased wood demand gives the opportunity to use wood that is not yet known for its marketing, one of which is Salam wood (Syzygium polianthum (Wight) Walp). The purpose of this research was to determine the physical and mechanical properties of Salam wood based on the height of the stem so that Salam wood can be optimally utilized by testing based on Classification SNI – 5 PKKI 1961. Methods of making test and test examples based on British Standard Methods No. 373-1957. The results showed that Salam wood has physical properties with an average  brown colour, the moisture content 3,13 % , density  0,58 kg/cm2 , Depreciation 2,59 %. Salam has mechanical properties with an average height position stem from base to tip with Modulus of Elastiscity (MOE)  97.701,54 , Modulus of Rupture (MOR) 659,18  and  Modulus Crushing  Streang 342,86 . Salam can be classified into strong class III and based on its properties and mechanics, it is suitable for use as a lightweight construction and furniture.Keywords: Density, depreciation, MCS, MOE, moisture content, MOR


2018 ◽  
Vol 7 (1) ◽  
Author(s):  
Mayang Archila ◽  
Farah Diba ◽  
Dina Setyawati ◽  
. Nurhaida

The objective of this research is to evaluate the effect of the number of composite layers on the quality of the composite board from sago bark waste and plastic waste, and the number of composite layers that produce the best quality on composite board. The composite board is made with size 30 cm x 30 cm x 1 cm. The composition and division of the material was carried out manually with the polypropylene distribution divided into three parts: the front and rear respectively of 15%, and the center 70% of the plastic weight. Target density of composite boards was 0.7 g / cm3. The treatment used is based on the number of layers composing, which is 5 layers, 7 layers, 9 layers, 11 layers and 13 layers. After mixed the sago bark particle and waste of polypropylene, the materials then compressed with hot press at 180oC with pressure about ± 25 kg / cm2 for 10 minutes. The composite boards then tested the quality included physical and mechanical properties. Testing of physical and mechanical properties refers to JIS A 5908-2003 standard. Physical properties consist of density, moisture content, thickness swelling, and water absorption. Mechanical properties consist of modulus of rupture, modulus of elasticity, internal bonding, and modulus of screw holding strength. The study used a completely randomized design experiment consisting of 5 treatments and 3 replications. The results showed the average value of composite density was range between 0.6962 – 0.7896 g/cm3, the moisture content was range between 4.3388 % - 6.8066%, the thickness swelling was range between 8.2605% - 11.9615%, and water absorption was range between 17.2380% - 22.3867%. The average value of modulus of rupture was range between 60,0632 kg/cm2 – 64,4068 kg/cm2, the modulus of elasticity was range between 17935,1813g/cm2 – 32841,8278 kg/cm2, the internal bonding was range between 1,9268 kg/cm2  - 5,4119 kg/cm2, and the modulus of screw holding strength was range between 78,2530 kg/cm2 – 92,9677 kg/cm2. The composite board made from sago stem bark waste and polypropylene waste plastic with 13 layers treatment is the best composite board and fulfilled the JIS A 5908-2003 standard. Keywords: bark of sago, composite boards, layer of composite, polypropylenes plastic, waste


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