scholarly journals Recent Trends in Pharmaceuticals Removal from Water Using Electrochemical Oxidation Processes

Environments ◽  
2021 ◽  
Vol 8 (8) ◽  
pp. 85
Author(s):  
Georgios Bampos ◽  
Athanasia Petala ◽  
Zacharias Frontistis

Nowadays, the research on the environmental applications of electrochemistry to remove recalcitrant and priority pollutants and, in particular, drugs from the aqueous phase has increased dramatically. This literature review summarizes the applications of electrochemical oxidation in recent years to decompose pharmaceuticals that are often detected in environmental samples such as carbamazapine, sulfamethoxazole, tetracycline, diclofenac, ibuprofen, ceftazidime, ciprofloxacin, etc. Similar to most physicochemical processes, efficiency depends on many operating parameters, while the combination with either biological or other physicochemical methods seems particularly attractive. In addition, various strategies such as using three-dimensional electrodes or the electrosynthesis of hydrogen peroxide have been proposed to overcome the disadvantages of electrochemical oxidation. Finally, some guidelines are proposed for future research into the applications of environmental electrochemistry for the degradation of xenobiotic compounds and micropollutants from environmental matrices. The main goal of the present review paper is to facilitate future researchers to design their experiments concerning the electrochemical oxidation processes for the degradation of micropollutants/emerging contaminants, especially, some specific drugs considering, also, the existing limitations of each process.

Water ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2340
Author(s):  
Brandon Chuan Yee Lee ◽  
Fang Yee Lim ◽  
Wei Hao Loh ◽  
Say Leong Ong ◽  
Jiangyong Hu

The management of contaminants of emerging concern (CECs) in water bodies is particularly challenging due to the difficulty in detection and their recalcitrant degradation by conventional means. In this review, CECs are characterized to give insights into the potential degradation performance of similar compounds. A two-pronged approach was then proposed for the overall management of CECs. Light-driven oxidation processes, namely photo/Fenton, photocatalysis, photolysis, UV/Ozone were discussed. Advances to overcome current limitations in these light-driven processes were proposed, focusing on recent trends and innovations. Light-based detection methodology was also discussed for the management of CECs. Lastly, a cost–benefit analysis on various light-based processes was conducted to access the suitability for CECs degradation. It was found that the UV/Ozone process might not be suitable due to the complication with pH adjustments and limited light wavelength. It was found that EEO values were in this sequence: UV only > UV/combination > photocatalyst > UV/O3 > UV/Fenton > solar/Fenton. The solar/Fenton process has the least computed EEO < 5 kWh m−3 and great potential for further development. Newer innovations such as solar/catalyst can also be explored with potentially lower EEO values.


Water ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2445
Author(s):  
Lizeth Urán-Duque ◽  
Julio César Saldarriaga-Molina ◽  
Ainhoa Rubio-Clemente

In this work, the recent trends in the application of the sulfate radical-based advanced oxidation processes (SR-AOPs) for the treatment of wastewater polluted with emerging contaminants (ECs) and pathogenic load were systematically studied due to the high oxidizing power ascribed to these technologies. Additionally, because of the economic benefits and the synergies presented in terms of efficiency in ECs degradation and pathogen inactivation, the combination of the referred to AOPs and conventional treatments, including biological processes, was covered. Finally, the barriers and limitations related to the implementation of SR-AOPs were described, highlighting the still scarce full-scale implementation and the high operating-costs associated, especially when solar energy cannot be used in the oxidation systems.


2010 ◽  
Vol 26 (1) ◽  
pp. 3-10 ◽  
Author(s):  
Nale Lehmann-Willenbrock ◽  
Simone Kauffeld

In research on trust in the organizational context, there is some agreement evolving that trust should be measured with respect to various foci. The Workplace Trust Survey (WTS) by Ferres (2002) provides reliable assessment of coworker, supervisor, and organizational trust. By means of a functionally equivalent translation, we developed a German version of the questionnaire (G-WTS) comprising 21 items. A total of 427 employees were surveyed with the G-WTS and questionnaires concerning several work-related attitudes and behaviors and 92 of these completed the survey twice. The hypothesized three-dimensional conceptualization of organizational trust was confirmed by confirmatory factor analysis. The G-WTS showed good internal consistency and retest reliability values. Concerning convergent validity, all of the three G-WTS dimensions positively predicted job satisfaction. In terms of discriminant validity, Coworker Trust enhanced group cohesion; Supervisor Trust fostered innovative behavior, while Organizational Trust was associated with affective commitment. Theoretical and practical contributions as well as opportunities for future research with the G-WTS are discussed.


2021 ◽  
Vol 11 (15) ◽  
pp. 7016
Author(s):  
Pawel S. Dabrowski ◽  
Cezary Specht ◽  
Mariusz Specht ◽  
Artur Makar

The theory of cartographic projections is a tool which can present the convex surface of the Earth on the plane. Of the many types of maps, thematic maps perform an important function due to the wide possibilities of adapting their content to current needs. The limitation of classic maps is their two-dimensional nature. In the era of rapidly growing methods of mass acquisition of spatial data, the use of flat images is often not enough to reveal the level of complexity of certain objects. In this case, it is necessary to use visualization in three-dimensional space. The motivation to conduct the study was the use of cartographic projections methods, spatial transformations, and the possibilities offered by thematic maps to create thematic three-dimensional map imaging (T3DMI). The authors presented a practical verification of the adopted methodology to create a T3DMI visualization of the marina of the National Sailing Centre of the Gdańsk University of Physical Education and Sport (Poland). The profiled characteristics of the object were used to emphasize the key elements of its function. The results confirmed the increase in the interpretative capabilities of the T3DMI method, relative to classic two-dimensional maps. Additionally, the study suggested future research directions of the presented solution.


2021 ◽  
Vol 13 (2) ◽  
pp. 563
Author(s):  
Bing Ran ◽  
Scott Weller

Despite the growing utility and prevalence of social entrepreneurship, an accepted definition remains elusive and infeasible. Yet, it is imperative that the principles guiding social entrepreneurship are identified so that common ground is established to facilitate future research. On the basis of a systematic literature review, this conceptual paper proposes a theoretical framework outlining social entrepreneurship as a three-dimensional framework as a function of continua of “social” and “business” logics, “beneficial” and “detrimental” social change logics, and “innovation” and “mundane” logics. The framework accommodates the fuzziness and ambiguity associated with social entrepreneurship whilst remaining a workable, identifiable construct. By accounting for the shifting logics practiced by social entrepreneurship that both influence and are influenced by the organizational environment, this framework provides an exit strategy for the definitional elusiveness of social entrepreneurship. The resultant structures and functions of social entrepreneurship are shaped by these constraints as reflected by the fluidity and flexibility endorsed by the framework. Four avenues for future research regarding social entrepreneurship are recommended on the basis of the framework proposed in this article.


2021 ◽  
Vol 11 (13) ◽  
pp. 5956
Author(s):  
Elena Parra ◽  
Irene Alice Chicchi Giglioli ◽  
Jestine Philip ◽  
Lucia Amalia Carrasco-Ribelles ◽  
Javier Marín-Morales ◽  
...  

In this article, we introduce three-dimensional Serious Games (3DSGs) under an evidence-centered design (ECD) framework and use an organizational neuroscience-based eye-tracking measure to capture implicit behavioral signals associated with leadership skills. While ECD is a well-established framework used in the design and development of assessments, it has rarely been utilized in organizational research. The study proposes a novel 3DSG combined with organizational neuroscience methods as a promising tool to assess and recognize leadership-related behavioral patterns that manifest during complex and realistic social situations. We offer a research protocol for assessing task- and relationship-oriented leadership skills that uses ECD, eye-tracking measures, and machine learning. Seamlessly embedding biological measures into 3DSGs enables objective assessment methods that are based on machine learning techniques to achieve high ecological validity. We conclude by describing a future research agenda for the combined use of 3DSGs and organizational neuroscience methods for leadership and human resources.


Machines ◽  
2021 ◽  
Vol 9 (1) ◽  
pp. 13
Author(s):  
Yuhang Yang ◽  
Zhiqiao Dong ◽  
Yuquan Meng ◽  
Chenhui Shao

High-fidelity characterization and effective monitoring of spatial and spatiotemporal processes are crucial for high-performance quality control of many manufacturing processes and systems in the era of smart manufacturing. Although the recent development in measurement technologies has made it possible to acquire high-resolution three-dimensional (3D) surface measurement data, it is generally expensive and time-consuming to use such technologies in real-world production settings. Data-driven approaches that stem from statistics and machine learning can potentially enable intelligent, cost-effective surface measurement and thus allow manufacturers to use high-resolution surface data for better decision-making without introducing substantial production cost induced by data acquisition. Among these methods, spatial and spatiotemporal interpolation techniques can draw inferences about unmeasured locations on a surface using the measurement of other locations, thus decreasing the measurement cost and time. However, interpolation methods are very sensitive to the availability of measurement data, and their performances largely depend on the measurement scheme or the sampling design, i.e., how to allocate measurement efforts. As such, sampling design is considered to be another important field that enables intelligent surface measurement. This paper reviews and summarizes the state-of-the-art research in interpolation and sampling design for surface measurement in varied manufacturing applications. Research gaps and future research directions are also identified and can serve as a fundamental guideline to industrial practitioners and researchers for future studies in these areas.


Author(s):  
Yuan Gao ◽  
Xiaoguang Duan ◽  
Bin Li ◽  
Qianqian Jia ◽  
Yang Li ◽  
...  

Persulfate-based advanced oxidation processes are promising technologies to solve water pollution. In this work, single iron atoms are anchored in three-dimensional N-doped carbon nanosheets by a chemical vapor deposition (CVD)...


2021 ◽  
pp. 1-38
Author(s):  
Yingya Jia ◽  
Anne S. Tsui ◽  
Xiaoyu Yu

ABSTRACT Optimal or rational decision making is not possible due to informational constraints and limits in computation capability of humans (March & Simon, 1958; March, 1978). This bounded rationality serves as a filtering process in decision making among business executives (Hambrick & Mason, 1984). In this study, we propose the concept of CEO reflective capacity as a behavior-oriented cognitive capability that may overcome to some extent the pervasive limitation of bounded rationality in executive decision-making. Following Hinkin's (1998) method and two executive samples, we developed and validated a three-dimensional measure of CEO reflective capacity. Based on two-wave surveys of CEOs and their executive-subordinates in 213 Chinese small-medium sized firms, we tested and confirmed three hypotheses on how CEO reflective capacity is related to a firm's sustainability performance (including economic, societal, and environmental dimensions) through the mediating mechanisms of strategic decision comprehensiveness and CEO behavioral complexity. We discuss the contribution of this study to the literature on the upper echelons and information processing perspectives. We also identify the implications for future research on strategic leadership and managerial cognition in complex and dynamic contexts.


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