scholarly journals Building an Organic Solar Cell: Fundamental Procedures for Device Fabrication

Energies ◽  
2019 ◽  
Vol 12 (11) ◽  
pp. 2188 ◽  
Author(s):  
Katerina Anagnostou ◽  
Minas M. Stylianakis ◽  
Konstantinos Petridis ◽  
Emmanuel Kymakis

This laboratory experiment is designed to train undergraduate students in the fundamental steps followed in engineering solution-processed organic solar cells and to offer insight on the operating principles of said device. Bulk heterojunction (BHJ) organic solar cells represent a photovoltaic architecture which has attracted a lot of attention due to its promising properties; moreover, this architecture, due to its low cost and potential, is continuously being investigated and improved. This paper is intended as a useful step-by-step guide for students and researchers to learn how to construct such a device. Another primary objective of this article is to highlight the importance of optimizing device performance through enhancing the optical, electrical, and morphological properties of the materials selected as building blocks. Once a completed organic solar cell is made, students will also learn how to investigate and assess its performance through a series of spectroscopic, electrical, and morphological characterization measurements.

2004 ◽  
Vol 19 (7) ◽  
pp. 1990-1994 ◽  
Author(s):  
Sandeep Kumar ◽  
Thomas Nann

Hybrid bulk heterojunction composites are promising material for low-cost organic solar cells. Fundamental measurements with CdTe nanocrystal/MEH-PPV poly [2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylene vinylene] composites and the first realization of a solar cell based on this material are presented. Optical and electrochemical properties are discussed as well as the current voltage characteristic of the resulting cell. It was found, that CdTe nanocrystal/MEH-PPV composites are well suited for an organic solar cell, even though the technological realization needs to be improved.


2019 ◽  
Author(s):  
Matthew Morgan ◽  
Maryam Nazari ◽  
Thomas Pickl ◽  
J. Mikko Rautiainen ◽  
Heikki M. Tuononen ◽  
...  

The electrophilic borylation of 2,5-diarylpyrazines results in the formation of boron-nitrogen doped dihydroindeno[1,2-<i>b</i>]fluorene which can be synthesized via mildly air-sensitive techniques and the end products handled readily under atmosphereic conditions. Through transmetallation via diarylzinc reagents a series of derivatives were sythesized which show broad absorption profiles that highlight the versatility of this backbone to be used in organic solar cell devices. These compounds can be synthesized in large yields, in alow number of steps and functionalized at many stages along the way providing a large depth of possibilities. Exploratory device paramaters were studied and show PCE of 2%.


Author(s):  
Jie Lv ◽  
Hua Tang ◽  
Jiaming Huang ◽  
Cenqi Yan ◽  
Kuan Liu ◽  
...  

Due to the barrierless free charge generation, low charge trapping, and high charge mobilities, the PM6:Y6 organic solar cell (OSC) achieves excellent power conversion efficiency (PCE) of 15.7%. However, the...


2015 ◽  
Vol 12 (5) ◽  
pp. 413-420
Author(s):  
Muhammad Ahsan Naveed ◽  
A. Hussain ◽  
K. Islam ◽  
P. Akhter

Organic solar cells have potential as an alternative to conventional inorganic solar cell due to low processing cost, flexibility and easy fabrication technique. The goal of this paper is to study the characteristics of the CuPc and PCBM based organic solar cell by introducing a thin layer of Ag at the interface of donor (CuPc) and Acceptor (PCBM), their photovoltaic and optical properties were investigated. The heterojunction solar cells with and without silver inter layer were fabricated through thermal deposition in HR vacuum. The OPV solar cells were characterized using current-voltage graphs, absorbance spectrum and Impedance spectroscopy. Impedance spectroscopy was taken to identify the traps using series resistance, parallel resistance, and Impedance spectrums under different frequencies. Optical behaviors of these devices have been investigated with absorbance spectrum. Introducing Ag to interfacing point produced traps and these traps causes to decreased Voc, Isc, FF, and efficiency. The effect of silver layer at donor acceptor interface was studied.


2015 ◽  
Vol 8 (2) ◽  
pp. 592-601 ◽  
Author(s):  
Bradley A. MacLeod ◽  
Bertrand J. Tremolet de Villers ◽  
Philip Schulz ◽  
Paul F. Ndione ◽  
Hyungchul Kim ◽  
...  

Interstitial zinc defects in solution-processed ZnO can be mitigated by using a diethylzinc precursor instead of zinc acetate, or by modifying the ZnO surface with a phosphonic acid, resulting in improved organic solar cell stability.


2005 ◽  
Vol 20 (12) ◽  
pp. 3167-3179 ◽  
Author(s):  
Sophie E. Gledhill ◽  
Brian Scott ◽  
Brian A. Gregg

Organic photovoltaic devices are poised to fill the low-cost, low power niche in the solar cell market. Recently measured efficiencies of solid-state organic cells are nudging 5% while Grätzel’s more established dye-sensitized solar cell technology is more than double this. A fundamental understanding of the excitonic nature of organic materials is an essential backbone for device engineering. Bound electron-hole pairs, “excitons,” are formed in organic semiconductors on photo-absorption. In the organic solar cell, the exciton must diffuse to the donor–accepter interface for simultaneous charge generation and separation. This interface is critical as the concentration of charge carriers is high and recombination here is higher than in the bulk. Nanostructured engineering of the interface has been utilized to maximize organic materials properties, namely to compensate the poor exciton diffusion lengths and lower mobilities. Excitonic solar cells have different limitations on their open-circuit photo-voltages due to these high interfacial charge carrier concentrations, and their behavior cannot be interpreted as if they were conventional solar cells. This article briefly reviews some of the differences between excitonic organic solar cells and conventional inorganic solar cells and highlights some of the technical strategies used in this rapidly progressing field, whose ultimate aim is for organic solar cells to be a commercial reality.


2019 ◽  
Vol 7 (3) ◽  
pp. 543-552 ◽  
Author(s):  
Suman Suman ◽  
Afzal Siddiqui ◽  
M. L. Keshtov ◽  
Ganesh D. Sharma ◽  
Surya Prakash Singh

In this work, two new indolo-[3,2-b]-carbazole (ICz) core-based non-fullerene acceptors (ICz-Rd2 and ICz-RdCN2) with an A–π–D–π–A backbone were designed, synthesized, and characterized and the influence of molecular engineering on the terminal end groups on their performance in organic solar cells (OSCs) was systematically examined.


RSC Advances ◽  
2015 ◽  
Vol 5 (30) ◽  
pp. 23892-23899 ◽  
Author(s):  
Seung Joo Lee ◽  
Jae-Yeon Kim ◽  
Abd. Rashid bin Mohd Yusoff ◽  
Jin Jang

We report a comprehensive study of the influence of NPs on organic solar cells by introducing Au NPs into OSCs fabricated using PEDOT:PSS:rGO. The PEDOT:PSS:rGO embedded with Au NPs had better Jsc and PCE values than the control devices.


RSC Advances ◽  
2020 ◽  
Vol 10 (42) ◽  
pp. 24882-24892 ◽  
Author(s):  
Anjusree S. ◽  
Arya K. R. ◽  
Bikas C. Das

Current imaging by C-AFM is demonstrated as a very effective tool to probe the defects in the organic solar cell active layer.


2016 ◽  
Vol 7 (9) ◽  
pp. 5798-5804 ◽  
Author(s):  
Wenhan He ◽  
Maksim Y. Livshits ◽  
Diane A. Dickie ◽  
Jianzhong Yang ◽  
Rachel Quinnett ◽  
...  

“Roller-wheel” shaped Pt-containing molecules display enhanced crystallinity and are better performing organic solar cell materials than conventional small molecules and polymers featuring “dumbbell” shaped structures.


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