scholarly journals The Effect of Superabsorbent Polymer and Nano-Silica on the Properties of Blended Cement

Crystals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1394
Author(s):  
Renuka Senthil Muthalvan ◽  
Suraj Ravikumar ◽  
Siva Avudaiappan ◽  
Mugahed Amran ◽  
Radhamanohar Aepuru ◽  
...  

Incorporating superabsorbent polymer (SAP), which has the abilities of absorption and desorption in cement mortar, can achieve the effect of internal curing. It is expected that the incorporation of nano-silica will improve the workability and strength in cement mortar/concrete. Hence, this study aims to examine the effect of SAP and nano-silica on the properties of blended cement paste. The experimental investigations via several tests such as consistency, setting time, compressive strength, UPV, and acid test were performed. Based on energy-dispersive X-ray analysis (EDX) test and scanning electron microscopy (SEM) test results, the morphology of hydration products and mineral compositions of cement paste were further analysed, and the mechanism of SAP with 0.2% and 0.3% and NS with lower percentages ranging from 0.5% to 2% on the performance of cement paste was studied. The results exhibited that incorporating SAP in various percentages from 0.5% to 2% prolonged the initial setting time, reduced the fluidity, and increased the water content and formation of pores. In addition, various percentages ranging from 0.5% to 2% of NS were added; thereby, an increase in the hydration process and refining the microstructure was found. The microscopic test results showed that the blended cement paste can effectively improve the denser microstructure and refine the pore structure.

2017 ◽  
Vol 2017 ◽  
pp. 1-9
Author(s):  
Yanping Sheng ◽  
Bin Xue ◽  
Haibin Li ◽  
Yunyan Qiao ◽  
Huaxin Chen ◽  
...  

A new type of alkali-free liquid accelerator for shotcrete was prepared. Specifically, the setting time and strength and shrinkage performance of two kinds of Portland cement with the accelerator were fully investigated. Moreover, the accelerating mechanism of alkali-free liquid accelerator and the hydration process of the shotcrete with accelerator were explored. Results show that alkali-free liquid accelerator significantly shortened the setting time of cement paste, where the initial setting time of cement paste with 8 wt% of the accelerator was about 3 min and the final setting time was about 7 min. Compressive strength at 1 day of cement mortar with the accelerator could reach 23.4 MPa, which increased by 36.2% compared to the strength of cement mortar without the accelerator, and the retention rate of 28-day compressive strength reached 110%. In addition, the accelerator still shows a good accelerating effect under low temperature conditions. However, the shrinkage rate of the concrete increased with the amount of the accelerator. 5~8% content of accelerator is recommended for shotcrete in practice. XRD and SEM test results showed that the alkali-free liquid accelerator promoted the formation of ettringite crystals due to the increase of Al3+ and SO42- concentration.


Author(s):  
Jemimah Carmichael Milton ◽  
Prince Arulraj Gnanaraj

Nano technology plays a very vital role in all the areas of research. The incorporation of nano materials in concrete offers many advantages and improves the workability, the strength and durability properties of concrete. In this study an attempt has been made to carry out an experimental investigation on concrete in which cement was replaced with nano sized cement. Ordinary Portland cement of 53 grade was ground in a ball grinding mill to produce nano cement. The characterization of nano cement was studied using Scanning Electron Microscope (SEM), Brunauer Emmett–Teller (BET), Energy Dispersive X ray microanalysis (EDAX) and Fourier Transform Infrared Spectroscopy (FTIR). From the characterization studies, it was confirmed that particles were converted to nano size, the specific surface area increased and the chemical composition remained almost the same. The properties of cement paste with and without nano cement were found. For the experimental study, cement was replaced with 10%, 20%, 30%, 40% and 50% of nano cement. Cement mortar of ratio 1:3 and concrete of grades M20, M30, M40 and M50 were used. Compressive strength of cement mortar and concrete with different percentages of nano cement was found. The cement mortar was also subjected to micro structural study. It was found that the strength increased even up to the replacement level of 50%. Further increase in the replacement is not possible since the addition of nano cement reduces the initial and final setting time of cement paste. At 50% replacement level, the initial setting time got reduced to 30 minutes which the least permitted value as per IS 12269: 2013. The increase in strength was due to the fact that nano cement acts not only as a filler material but also the reactivity increased due to the higher specific surface area. The SEM image shows the formation of additional C-S-H gel. The percentage increase in compressive strength was found to increase up to 32%. The workability of concrete with nano cement was found to be significantly more than that of the normal cement concrete.


2009 ◽  
Vol 405-406 ◽  
pp. 122-126
Author(s):  
Qiu Hua Rao ◽  
Xiao Ma

This paper presents an investigation on the effects of self-combustible gangue powder on the water requirement of normal consistency and setting time of blended cement paste. It was observed that the water requirement of paste increased, when self-combustible gangue powder were substituted partially for cement. It was found that self-combustible gangue powder have little effect on the setting time of blended cement paste with dosage from 10% to 30%,and this means the range of dosage is a appropriate mix content.


Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1611
Author(s):  
Gintautas Skripkiūnas ◽  
Asta Kičaitė ◽  
Harald Justnes ◽  
Ina Pundienė

The effect of calcium nitrate (CN) dosages from 0 to 3% (of cement mass) on the properties of fresh cement paste rheology and hardening processes and on the strength of hardened concrete with two types of limestone-blended composite cements (CEM II A-LL 42.5 R and 42.5 N) at different initial (two-day) curing temperatures (−10 °C to +20 °C) is presented. The rheology results showed that a CN dosage up to 1.5% works as a plasticizing admixture, while higher amounts demonstrate the effect of increasing viscosity. At higher CN content, the viscosity growth in normal early strength (N type) cement pastes is much slower than in high early strength (R type) cement pastes. For both cement-type pastes, shortening the initial and final setting times is more effective when using 3% at +5 °C and 0 °C. At these temperatures, the use of 3% CN reduces the initial setting time for high early strength paste by 7.4 and 5.4 times and for normal early strength cement paste by 3.5 and 3.4 times when compared to a CN-free cement paste. The most efficient use of CN is achieved at −5 °C for compressive strength enlargement; a 1% CN dosage ensures the compressive strength of samples at a −5 °C initial curing temperature, with high early strength cement exceeding 3.5 MPa but being less than the required 3.5 MPa in samples with normal early strength cement.


2020 ◽  
Author(s):  
Moruf O. Yusuf ◽  
Sami I. Shamsah ◽  
Khaled A. Al‐Sodani ◽  
Salihu Lukman

2022 ◽  
Vol 152 ◽  
pp. 106657
Author(s):  
M. Frías ◽  
S. Martínez-Ramírez ◽  
R. Vigil de la Villa ◽  
R. García-Giménez ◽  
M.I. Sánchez de Rojas

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