scholarly journals Valorization of Powder Obtained from Marble Sludge Waste and Its Suitability as a Mineral Filler

Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 619
Author(s):  
Omrane Benjeddou ◽  
Mamdooh Alwetaishi

Stone industry has generated about 200 million tons of marble waste by marble processing industries whether in the form of sludge or solid blocks. The accumulated marble wastes contaminate water and air and have harmful effects on human health, plants, and animals. This study focuses on exploring the uses of powder obtained by drying and grinding marble sludge waste, generated from marble manufacturing processes, as a mineral filler for other construction materials. First, physical characterization was performed on marble sludge. Second, the powder preparation process was presented. Thereafter, a set of tests was carried out to identify the chemical, mineralogical, and physical properties of marble powder. By doing so, tests such as chemical analysis, calcium carbonate content, and methylene blue test, as well as mineralogical characterization using X-ray diffraction (XRD), Atterberg limits, particle size analysis, densities, Blaine specific surface, hydraulic property, as well as reaction with admixture, cement, and activity index were conducted. In the last part of this work, the obtained powder properties are compared to the standards requirements to confirm its suitability as mineral filler. The test results showed that the obtained marble powder is too rich in calcite; it is poor of any clay minerals fraction; it is very well graded; it is not reactive; and it does not have any effects on concrete strength; consequently, it can be considered as a mineral filler.

1983 ◽  
Vol 63 (2) ◽  
pp. 259-269 ◽  
Author(s):  
K. GHEBRE-EGZIABHIER ◽  
R. J. ST. ARNAUD

The nature and distribution of carbonate minerals in the upper Qu’Appelle basin in south-central Saskatchewan were investigated. The equivalent carbonate content and calcite:dolomite ratios of the deposits reflect the mechanisms of glacial deposition and some differences in the sources of the original parent material. The particle size analysis shows that the Qu’Appelle Lake sediments are more clayey than the surrounding soils and till deposits. Mg-bearing calcites occur only in the fine-sized fraction of the carbonate accumulation horizons. However, most of the upper Qu’Appelle Lake sediments contain appreciable amounts of sand-sized Mg-bearing calcites. The marked increase in carbonate content of the sediments relative to the adjacent soils and deposits is partially due to direct precipitation of calcite from the supersaturated lake waters. In this respect, a good correlation exists between the lake water ionic activity products for CaCO3 and the relative equivalent carbonatic mineral contents of the sediments. Key words: Mg-bearing calcite, dolomite, IAP, erosion


Cerâmica ◽  
2017 ◽  
Vol 63 (366) ◽  
pp. 253-262 ◽  
Author(s):  
N. I. Alvarez Acevedo ◽  
M. C. G. Rocha ◽  
L. C. Bertolino

Abstract Characterization studies of clays are often performed to identify possible markets for these materials. Bearing this in mind, two samples of natural clays from the Southeast region of Brazil were studied. Conventional techniques of characterization were used. Granulometric analysis and determination of cationic exchange capacity of these clays were also performed. Nitrogen adsorption-desorption measurements were used to determine the Brunauer-Emmett-Teller specific surface area, and Barrett-Joyner-Halenda and t-plot pore size analysis were carried out. The results obtained were similar for the two clays. Both present high clay fraction (above 80 wt%) composed of illite, kaolinite and quartz minerals. Stratified illite-smectite structures were also observed. Traces of calcite were detected in one of the clay samples, while traces of montmorillonite were observed in the other sample. These results were corroborated by the low cationic exchange capacity values obtained for both clays. These clays showed good adsorptive properties, evidenced by their specific surface areas, with predominantly mesoporous structures and slit-like pores. According to their features, these clays have potential use as adsorbents to replace more expensive materials due to their easy availability and low cost.


2015 ◽  
Vol 820 ◽  
pp. 65-70
Author(s):  
I.D.S. Pereira ◽  
V.N.F. Lisboa ◽  
I.A. Silva ◽  
J.M.R. Figueirêdo ◽  
G.A. Neves ◽  
...  

Bentonite exhibt a range of industrial applications moving millions of dollars on the market per year. Among several applications if highlights it is use for petroleum drilling fluids. Thus, this work aims to characterize physical, mineralogical and technologically, the bentonitics clays of Sossego County, Paraíba, Brazil. Mineralogical characterization of clays was done through the following techniques: particle size analysis by laser diffraction, thermogravimetric and differential thermal analysis, chemical analysis and x-ray diffraction. The clays were turned in by treatment with sodium in Na2CO3 and then determined whether the apparent viscosity, plastic and volume of filtrate of clay-water dispersions. The results showed that the samples are of polycationic, showing levels of MgO, CaO and K2O, similar to those from Boa Vista County, Paraíba, Brazil, and consist of clay mineral kaolinite, quartz and esmec. The clays showed rheological properties that indicate potential for use in drilling fluids.


Author(s):  
M Bourourou ◽  
A Bouzenzana ◽  
T Batouche ◽  
A Benselhoub

Purpose. In order to fully exploit the metal and facilitate its method of processing, we need an accurate knowledge of its composition, granular distribution, and association with unimportant and penalizing elements that we would like to get rid of, compared to the distribution of the element to extract by flotation method. Methodology. The present experimental work proposes an approach to the mineralogical, chemical and particle size characterization, several analyzes have been carried out by Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM/EDS), X-ray Diffraction (XRD), Optical Microscopy (OM), Particle Size-Fraction Analysis (PSFA), and X-ray Fluorescence (XRF). These analyzes were submitted on samples of lead-zinc of different sizes as well as well-prepared fine powder of this ore; the zinc content of the raw material is about 5% Zn. Findings. The results obtained by the mineralogical characterization and the particle size analysis reveal a very varied and irregular texture of the ore, consisting mainly of sulphides (sphalerite, galena, pyrite, marcasite), associated with carbonate gangue, mainly dolomite and calcite. The theoretical dimensions of the particles found in the fine grain size classes [-1 +0.053] mm. In addition, the conditions of the pulp using the following reagents: CuSO4 activator, PAX collector, CaO regulator and the pine oil foamed, along with a pH modifier between 10.5 and 12 (11.8 optimal), improve the content of sulphide minerals, and increased the concentrate of sphalerite (ZnS) by foam Flotation with a maximum recovery and economically appropriate content (54% Zn concentrate). Originality. Depending on the results of the analysis performed and the complete collection of data obtained in the laboratory, we aim to optimize the process of treating lead-zinc sulphide ore and give a more detailed reference source to specialists, researchers and metallurgists in field of mining in general and in the treatment of polymetallic lead-zinc ore in the area studied in particular. Practical value. Benefit the values of beneficial minerals (concentrate of zinc and others sulphide), from different types of raw materials. The latter focuses on flotation as the main successful technique in the extraction of this type of lead-zinc minerals, but it requires constant research and careful examination of its elements and values in order to excel in this field of polymetallic-sulphide ore processing.


Void free mass, congested reinforcement, reduced section, and surface finishes are the present demand in the construction sector that can be fulfilled using Self Compacting Concrete (SCC). It flows under self-weight and develops a homogeneous dense mass of concrete without external energy (Vibration). The research described in this research examined the making of SCC with readily available materials. The most crucial distinction is the presence of filler material and small aggregate size in the SCC mixture. To obtain the benefit of filler material, reduced cement content, improve workability and strength in SCC, two fillers selected from a group of natural inert by-product, limestone powder (LP), and marble powder (MP). For this purpose, mortar cube prepared as per BS 3892 with two fillers, LP and MP by 10%, 15%, and 20% of replacement with a different combination. Present work also investigates the pozzolanic and filler effect of partial replacement in mortars by strength activity index (SAI), also tried to develop the relationship between fresh SCC slump flow and V-flow spread time. The observed value in the SAI test for the sixteen samples of a mineral filler of 10%,15%, and 20% replacement compared with a normal mix, all samples have the value lower than the control mix of 80% as per BS 3892. It is due to the effect of the filler on the microstructure and the presence of superplasticizer. From these results, it is concluded that filler, LP, and MP does not contribute to pozzolanic reaction, and it is still unhydrated at the age of 28 days.


2015 ◽  
Vol 814 ◽  
pp. 579-582
Author(s):  
Su Ping Cui ◽  
Ling Ling Liu ◽  
Ya Li Wang ◽  
Hui Wang ◽  
Shi Jie Dong

Granulated blast furnace slag (GBFS) is a by-product of ironmaking and widely used in the cement and concrete. GBFS samples with different ratio of SiO2/Al2O3 were prepared under the laboratory conditions and ground by the agate ball mill at different times. Then they were characterized by laser particle size analysis (LPSA), scanning electron microscopy (SEM), Bertrand surface method and mechanical testing. It was found that the activity index of GBFS clearly increased with the decrease of the GBFS particle size. In the case of the average particle size about 32μm, the activity indices were irregular with the increase of SiO2/Al2O3 ratio, whereas for the average particle size about 11μm, the activity indices decreased with the increase of SiO2/Al2O3 ratio.


2008 ◽  
Vol 1107 ◽  
Author(s):  
Mira K. Markovaara-Koivisto ◽  
Nuria Marcos ◽  
David Read ◽  
Antero Lindberg ◽  
Marja SiitariKauppi ◽  
...  

AbstractInterpretation of trace metal mobility in geological environments is often hampered by conflicting data from alternative experimental protocols and the lack of detailed mineralogical characterization of the host medium. To illustrate this issue, the release of uranium, thorium and the rare earth elements (REE) was investigated in polished rock slab samples from the U-Th deposit at the Palmottu Natural Analogue study site (SW Finland) by means of leaching experiments. The samples were sequentially leached with artificial groundwater of moderately high carbonate content at pH8, and nitric acid solutions at pH5 and pH3. The mineralogy and composition of the U, Th and REE mineral phases was studied using SEM-WDS and EDAX methods before and after each leaching step. In parallel, leaching was carried out on crushed material of the same samples and the leachates analysed by ICP-MS.The most notable U minerals are uraninite, uranophane and two secondary U-Pb phases. Thorium occurs predominantly in monazite and at lower concentrations in uraninite. Accessory thorite is also present, which together with monazite contains most of the REE. Differential leaching of the elements was noted across all phases on the timescale of the experiments. Uraninite is partly dissolved at pH3. The main secondary uranium phase, uranophane, was stable in moderately acidic solution, but easily dissolved in the artificial groundwater and at pH3. Some release of REE was observed although the main REE-bearing phase, monazite, showed no evidence of degradation.This study provides insights in the preferential release of radionuclides in granitic bedrock. An understanding of these processes is essential when assessing the safety of a spent fuel repository. Once released from the primary waste form U is expected to precipitate as secondary phases within micro fractures, as observed at Palmottu and numerous other deposits.


2020 ◽  
Author(s):  
Kannika Wangritthikraikul ◽  
Smith Leknettip ◽  
Sakonvan Chawchai

<p>Peatlands have played an important role in the global carbon cycle. Tropical peatlands are one of the largest reserves of terrestrial organic carbon. Present-day tropical peat swamp forests are, however, under the threat of anthropogenic disturbance or have already been widely degraded. In Southeast Asia, very large areas of peatland have been deforested, drained, converted to extensive and intensive agricultural land uses and exposed to regular wildfires. Khuan Kreng peat swamp is the second largest protected wetland in Thailand. Recent studies in Khuan Kreng peat swamp has focused on present day drought and forest fires, but there is still lack of paleoenvironmental data. In this study, sediment and peat sequences were collected from Forest Fire Control Station area in Khuan Kreng peat swamp, and geochemical data (loss on ignition, grain size analysis and carbonate content) were analyzed. The age of early Holocene were determined based on plant macrofossils using Radiocarbon Dating (<sup>14</sup>C). The preliminary results indicate that this area was Tidal flats. The study of sediment/peat sequences using geochemical data can improve our understanding how past environmental have affected Khuan Kreng peat swamp ecosystems.</p>


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