scholarly journals Structural and Magnetic Properties Study of Fe2O3/NiO/Ni2FeO4 Nanocomposites

Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 613
Author(s):  
Zakia Alhashem ◽  
Chawki Awada ◽  
Faheem Ahmed ◽  
Ashraf H. Farha

In the current work, the nanocomposites that consist chiefly of three components—α-Fe2O3, NiO and Ni2FeO4, in two different ratios 2:2:1 (FNN-221) and 2:1:1 (FNN-211), respectively—were produced. The synthesis was done in two steps by following the chemical co-precipitation and mechanical ball-milling route. The presence of individual phase was identified from the XRD data without the detection of any additional impurities. The phase fraction of each component estimated from the profile fitting of XRD patterns were found to be 41.2%, 39.7%, 19.1% in FNN-221 sample and 49.5%, 26.4%, 24.1% for FNN-211 sample, respectively, which were consistent with the experimental values. The total magnetization at 300 K was obtained to be 13.41 emu/g and 10.95 emu/g for FNN-221 and FNN-211 samples, respectively. In FNN-211 compound the zero field coercivity (HC) expanded towards the higher field values thereby signifying the exchange bias behavior. Furthermore, the exchange bias field (Hex) for FNN-211 was obtained as 35.1 Oe.

2020 ◽  
Vol 49 (14) ◽  
pp. 4502-4517 ◽  
Author(s):  
G. C. Pandey ◽  
K. Nemkovski ◽  
Y. Su ◽  
Chandana Rath

NiCr2−xFexO4 (x = 0 and 0.2) polycrystalline ceramics have been synthesized successfully through a simple co-precipitation technique to study the evolution of structural and magnetic properties by doping Fe.


2014 ◽  
Vol 875-877 ◽  
pp. 272-276 ◽  
Author(s):  
Chao Jing ◽  
Ye Jun Yang ◽  
Dong Hua Yu ◽  
Zhe Li ◽  
Xiao Long Wang ◽  
...  

We report the exchange bias properties in the bulk Ni45Co5Mn38Sn12quaternary Heusler alloy. The ferromagnetic (FM) –antiferromagnetic (AFM) interactions get reinforced after the Co substitution for Ni in the Ni-Mn-Sn alloy, which increase the exchange bias field (HE). A maximum shift in hysteresis loops of 306 Oe was observed in the 10 kOe field cooled sample. The origin of this large exchange bias field has been discussed. Magnetic hysteresis loop obtained in the zero field cooled (ZFC) mode shows double-shifted loop, and the reason of this phenomenon has been explained in detail.


2018 ◽  
Vol 2018 ◽  
pp. 1-11
Author(s):  
Eman S. Al-Hwaitat ◽  
Sami H. Mahmood ◽  
Mahmoud Al–Hussein ◽  
Ibrahim Bsoul

We report on the synthesis and characterization of Ba3[Cu0.8−xZnxMn0.2]2Fe24O41 (x = 0.0, 0.2, 0.4, 0.6, and 0.8) barium hexaferrites. The samples were prepared by high-energy ball-milling technique and double-sintering approach. The effects of Zn substitution for Cu on the structural and magnetic properties of the prepared samples were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), and vibrating sample magnetometer (VSM). XRD patterns of the samples revealed the presence of a major Z-type hexaferrite phase, together with secondary M-type and Y-type phases. The magnetic results indicated that the saturation magnetization increased slightly with increasing the Zn content, while the coercivity and magnetocrystalline anisotropy field exhibited a decreasing tendency with the increase of Zn content. The thermomagnetic curves revealed the complex magnetic structure of the prepared samples and confirmed that the Curie temperature of the magnetic phases decreased with increasing x as a result of the reduction of the strength of the superexchange interactions.


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