scholarly journals Modulation Effect of Hardness on the Friction Coefficient and Its Mechanism Analysis of ZrB2/Mo Multilayers Synthesized by Magnetron Sputtering

Crystals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 69
Author(s):  
Tingjia Zhang ◽  
Lei Dong ◽  
Jie Wu ◽  
Dejun Li
Keyword(s):  
Friction Coefficient ◽  
Magnetron Sputtering ◽  
Mechanism Analysis ◽  
Friction Behavior ◽  
Covalent Bonds ◽  
Maximum Value ◽  
Opposite Change ◽  
Different Temperatures ◽  
Ionic Bonds ◽  
The Stability

ZrB2/Mo multilayers were prepared by the magnetron sputtering technique on Si (100) and Al2O3 (001) substrates. The friction behavior and wear mechanism of the multilayers were tested at variable modulation ratios (tZrB2:tMo) of 1:1 to 8:1 at different temperatures. Under the influence of an effective modulation ratio and temperature, the friction coefficient and hardness of ZrB2/Mo multilayers showed an almost opposite change rule, that is, the higher the hardness, the lower the friction coefficient. The hardness and elastic modulus reached the maximum value (26.1 GPa and 241.99 GPa) at tZrB2:tMo = 5:1 and the corresponding friction coefficient was 0.86. Meanwhile, the hardness and average friction coefficient at 500 °C were, respectively, 8.9 GPa and 1.23. First-principles calculations of the interface model of ZrB2 (001)/Mo (110) showed that the ionic bonds and covalent bonds at the interface can effectively improve the viscosity of the multilayer and the stability of the interface, and thus increase the hardness. This also indicated that the variation of the friction coefficient was mainly determined by the stability of the interface in the ZrB2/Mo multilayers.

Deposition and Characterization of C-NbN/NbCN Multilayers on Si(100) Substrates

2017 ◽  
Vol 898 ◽  
pp. 1447-1452
Author(s):  
Kan Zhang ◽  
X. Li ◽  
Su Xuan Du ◽  
Ping Ren ◽  
Mao Wen ◽  
...  
Keyword(s):  
Friction Coefficient ◽  
Magnetron Sputtering ◽  
Compressive Stress ◽  
Reactive Magnetron ◽  
Modulated Structure ◽  
Mechanical And Tribological Properties ◽  
Peak Intensity ◽  
Maximum Value ◽  
Mixture Value

The cubic-NbN/NbCN multilayers with modulation periodicity (Λ) ranging from 4.2 to 39.1 nm were deposited on Si (100) substrate by reactive magnetron sputtering in a mixture of Ar and N2 gases. The Λ dependent structural, mechanical and tribological properties for resulting c-NbN/NbCN multilayers were explored. As Λ varied from 4.2 to 39.1 nm, all the films exhibited an obvious modulated structure. Increasing the Λ, the Nb (C,N)(111) peak in XRD gradually shifted to bigger angles and the peak intensity of NbN(111) became stronger. The stress for all multilayers was compressive ranging in between the stress for both NbN and NbCN single layers, and the stress value was stable with increasing Λ. The NbN layer was beneficial to relaxing the compressive stress which induced by NbCN layer. In addition, as Λ increases, the hardness (H) first increased, and then decreased after reaching a maximum value. The obvious enhancement in hardness for multilayers was observed, whose maximum value approaches 43.3 GPa when Λ = 8.4 nm, 37% larger than that obtained by the rule of mixture value. The friction coefficient values of NbN/NbCNmultilayers ranging between 0.34 and 0.4 were much lower than that of NbN monolayer but higher than that of NbCN monolayer were.

scholarly journals Structure and Friction Behavior of CrNx/a-C:H Nanocomposite Films

2014 ◽  
Vol 2014 ◽  
pp. 1-6
Author(s):  
Lunlin Shang ◽  
Guangan Zhang ◽  
Zhongrong Geng
Keyword(s):  
Friction Coefficient ◽  
Magnetron Sputtering ◽  
Chromium Carbide ◽  
Amorphous Carbon ◽  
Nanocomposite Films ◽  
Xps Analysis ◽  
Friction Behavior ◽  
Si Substrates ◽  
Diffraction Peaks ◽  
Deposited Films

CrN and CrNx/a-C:H nanocomposite films were deposited on Si substrates by the magnetron sputtering technique. The structure, chemical state, and friction behavior of the CrNx/a-C:H films prepared at various CH4 content were studied systematically. The CrN film shows strong (111) and (220) orientation, while the CrNx/a-C:H films consist of the nanocrystalline CrNx or Cr particles embedded in an amorphous hydrocarbon (a-C:H) matrix and show weak diffraction peaks, which is in accordance with the XPS analysis results. The typical Raman D and G peaks are observed, indicating that the separated amorphous carbon or CNx phase appears in the CrNx/a-C:H films. However, no chromium carbide was observed in all the as-deposited samples. From the SEM graphs, all the deposited films depicted a dense and compact microstructure with well-attached interface with the substrate. The average friction coefficient of the CrNx/a-C:H films largely decreased with increasing CH4 content.

scholarly journals A Superhydrophobic, Antibacterial, and Durable Surface of Poplar Wood

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1885
Author(s):  
Xinyu Wu ◽  
Feng Yang ◽  
Jian Gan ◽  
Zhangqian Kong ◽  
Yan Wu
Keyword(s):  
Stearic Acid ◽  
Antibacterial Properties ◽  
Alkali Resistance ◽  
Poplar Wood ◽  
X Ray Diffraction ◽  
X Ray ◽  
Different Temperatures ◽  
Acid And Alkali Resistance ◽  
The Stability

The silver particles were grown in situ on the surface of wood by the silver mirror method and modified with stearic acid to acquire a surface with superhydrophobic and antibacterial properties. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and X-ray energy spectroscopy (XPS) were used to analyze the reaction mechanism of the modification process. Scanning electron microscopy (SEM) and contact angle tests were used to characterize the wettability and surface morphology. A coating with a micro rough structure was successfully constructed by the modification of stearic acid, which imparted superhydrophobicity and antibacterial activity to poplar wood. The stability tests were performed to discuss the stability of its hydrophobic performance. The results showed that it has good mechanical properties, acid and alkali resistance, and UV stability. The durability tests demonstrated that the coating has the function of water resistance and fouling resistance and can maintain the stability of its hydrophobic properties under different temperatures of heat treatment.

scholarly journals An assessment of methanolysis and other factors used in the analysis of carbohydrate-containing materials

1971 ◽  
Vol 125 (4) ◽  
pp. 1009-1018 ◽  
Author(s):  
R. E. Chambers ◽  
J. R. Clamp
Keyword(s):  
Hydrochloric Acid ◽  
Analytical Procedure ◽  
Internal Standard ◽  
Inorganic Contaminants ◽  
Rotary Evaporation ◽  
Silver Salts ◽  
Methanolic Hydrochloric Acid ◽  
Different Temperatures ◽  
The Stability ◽  
Analytical System

The stability of monosaccharides in methanolic hydrochloric acid of different strengths and at different temperatures was determined. They are generally stable for 24h in methanolic 1m- and 2m-hydrochloric acid at both 85°C and 100°C, but undergo considerable destruction in methanolic 4m- and 6m-hydrochloric acid at 100°C. Analysis of glycopeptides and oligosaccharides of known composition showed that release of carbohydrate was complete within 3h in methanolic 1m-hydrochloric acid at 85°C. Removal of methanolic hydrochloric acid by rotary evaporation resulted in considerable losses of monosaccharides, which could be prevented by prior neutralization. Methanolysis caused extensive de-N-acetylation of acetamidohexoses, so that a re-N-acetylation step is necessary in the analytical procedure. The addition of acetic anhydride for this purpose also prevented loss of internal standard by adsorption on the insoluble silver salts used in neutralization. Several trimethylsilylating agents were studied and suitable conditions are recommended. The effects on the analytical system of water and some common organic and inorganic contaminants are assessed.

scholarly journals Influence of study model, baseline catalytic concentrations and analytical system on the stability of serum alanine aminotransferase

2020 ◽  
Vol 1 (2) ◽  
Author(s):  
Josep Miquel Bauça ◽  
Andrea Caballero ◽  
Carolina Gómez ◽  
Débora Martínez-Espartosa ◽  
Isabel García del Pino ◽  
...  
Keyword(s):  
Alanine Aminotransferase ◽  
Experimental Models ◽  
Individual Variability ◽  
Serum Samples ◽  
Multicentric Study ◽  
Different Temperatures ◽  
The Stability ◽  
Analytical System ◽  
Definition Of ◽  
Analytical Platforms

AbstractObjectivesThe stability of the analytes most commonly used in routine clinical practice has been the subject of intensive research, with varying and even conflicting results. Such is the case of alanine aminotransferase (ALT). The purpose of this study was to determine the stability of serum ALT according to different variables.MethodsA multicentric study was conducted in eight laboratories using serum samples with known initial catalytic concentrations of ALT within four different ranges, namely: <50 U/L (<0.83 μkat/L), 50–200 U/L (0.83–3.33 μkat/L), 200–400 U/L (3.33–6.67 μkat/L) and >400 U/L (>6.67 μkat/L). Samples were stored for seven days at two different temperatures using four experimental models and four laboratory analytical platforms. The respective stability equations were calculated by linear regression. A multivariate model was used to assess the influence of different variables.ResultsCatalytic concentrations of ALT decreased gradually over time. Temperature (−4%/day at room temperature vs. −1%/day under refrigeration) and the analytical platform had a significant impact, with Architect (Abbott) showing the greatest instability. Initial catalytic concentrations of ALT only had a slight impact on stability, whereas the experimental model had no impact at all.ConclusionsThe constant decrease in serum ALT is reduced when refrigerated. Scarcely studied variables were found to have a significant impact on ALT stability. This observation, added to a considerable inter-individual variability, makes larger studies necessary for the definition of stability equations.

scholarly journals Relationship between the real contact behavior and tribological characteristics of cotton fabric

Friction ◽  
2020 ◽  
Author(s):  
Rongxin Chen ◽  
Jiaxin Ye ◽  
Wei Zhang ◽  
Jiang Wei ◽  
Yan Zhang ◽  
...  
Keyword(s):  
Friction Coefficient ◽  
Contact Area ◽  
Dynamic Change ◽  
Tribological Characteristics ◽  
Real Contact Area ◽  
Cotton Fibers ◽  
Friction Behavior ◽  
Contact Behavior ◽  
The Real ◽  
Real Contact

Abstract The tribological characteristics of cotton fibers play an important role in engineering and materials science, and real contact behavior is a significant aspect in the friction behavior of cotton fibers. In this study, the tribological characteristics of cotton fibers and their relationship with the real contact behavior are investigated through reciprocating linear tribotesting and real contact analysis. Results show that the friction coefficient decreases with a general increase in load or velocity, and the load and velocity exhibit a co-influence on the friction coefficient. The dynamic change in the real contact area is recorded clearly during the experiments and corresponds to the fluctuations observed in the friction coefficient. Moreover, the friction coefficient is positively correlated with the real contact area based on a quantitative analysis of the evolution of friction behavior and the real contact area at different loads and velocities. This correlation is evident at low velocities and medium load.

Studies on the Coordination Reaction of VO2+ and Tannic Acid in the Tannin Extract Desulfurization

2012 ◽  
Vol 239-240 ◽  
pp. 1573-1576
Author(s):  
Zhu Qing Gao ◽  
Xiao Dong Cai ◽  
Kai Cheng Ling
Keyword(s):  
Stability Constants ◽  
Tannic Acid ◽  
Ph Value ◽  
Protonation Constants ◽  
Conditional Stability ◽  
Tannin Extract ◽  
Acid Effect ◽  
Different Temperatures ◽  
The Stability ◽  
Apparent Stability

At different temperatures, the protonation constants of tannic acid and the complex apparent stability constants between tannic acid and VO2+ were determined by using pH potentimetric method. The results showed that the protonation constants and the complex apparent stability constants slightly decreased with the raising temperature. In accordance with the pH value in the tannin extract technology, the conditional stability constants of the complex were calculated on the basis of the acid effect of tannic acid and the hydrolysis effect of VO2+. It was found that pH greatly affected the stability constants of the complex , so pH must be strictly controlled in the tannin extract technology.

scholarly journals Out-of-plane local mechanism analysis with finite element method

2021 ◽  
Vol 8 (1) ◽  
pp. 130-136
Author(s):  
Roberto Spagnuolo
Keyword(s):  
Finite Element ◽  
Masonry Walls ◽  
Finite Element Models ◽  
Mechanism Analysis ◽  
Fem Method ◽  
Local Mechanism ◽  
Out Of Plane ◽  
Smeared Crack ◽  
The Stability ◽  
No Tension Material

Abstract The stability check of masonry structures is a debated problem in Italy that poses serious problems for its extensive use. Indeed, the danger of out of plane collapse of masonry walls, which is one of the more challenging to evaluate, is traditionally addressed not using finite element models (FEM). The power of FEM is not properly used and some simplified method are preferred. In this paper the use of the thrust surface is suggested. This concept allows to to evaluate the eccentricity of the membrane stresses using the FEM method. For this purpose a sophisticated, layered, finite element with a no-tension material is used. To model a no-tension material we used the smeared crack method as it is not mesh-dependent and it is well known since the early ’80 in an ASCE Report [1]. The described element has been implemented by the author in the program Nòlian by Softing.

An improved nonlinear model considering relative velocity for the friction behavior between untwisted glass-fiber tow and roller

2021 ◽  
pp. 004051752110308
Author(s):  
Yang Liu ◽  
Zhong Xiang ◽  
Xiangqin Zhou ◽  
Zhenyu Wu ◽  
Xudong Hu
Keyword(s):  
Friction Coefficient ◽  
Glass Fiber ◽  
Relative Velocity ◽  
Friction Model ◽  
Woven Fabric ◽  
Test Results ◽  
Application Process ◽  
Friction Behavior ◽  
Improved Model

Friction between the tow and tool surface normally happens during the tow production, fabric weaving, and application process and has an important influence on the quality of the woven fabric. Based on this fact, this paper studied the influence of tension and relative velocity on the three kinds of untwisted-glass-fiber tow-on-roller friction with a Capstan-based test setup. Furthermore, an improved nonlinear friction model taking both tension and velocity into account was proposed. According to statistical test results, firstly, the friction coefficient was found to be positively correlated with tension and relative velocity. Secondly, tension and velocity were complementary on the tow-on-roller friction behavior, with neither being superior to the other. Thirdly, an improved model was found to present well the nonlinear characteristics between friction coefficient and tension and velocity, and predicational results of the model were found to agree well with the observations from Capstan tests.

A novel technique for modeling friction behavior in knitted fabric simulation

2017 ◽  
Vol 29 (6) ◽  
pp. 776-792
Author(s):  
Vajiha Mozafary ◽  
Pedram Payvandy
Keyword(s):  
Friction Coefficient ◽  
Uniform Distribution ◽  
Friction Force ◽  
Experimental Result ◽  
Knitted Fabric ◽  
Friction Behavior ◽  
Content Type ◽  
Novel Technique ◽  
Fabric Structure ◽  
Fabric Surface

Purpose Fabric-object friction force is a fundamental factor in cloth simulation. A large number of parameters influence the frictional properties of fabrics such as fabric structure, yarn structure, and inherent properties of component fibers. The purpose of this paper is to propose a novel technique for modeling fabric-object friction force in knitted fabric simulation based on the mass spring model. Design/methodology/approach In this technique, unlike other studies, distribution of friction coefficient over the fabric surface is not uniform and depends on the fabric structure. The main reason for considering non-uniform distribution is that in various segments of fabric, contact percent of fabric-object is different. Findings The proposed technique and common methods based on friction coefficient uniform distribution are used to simulate the frictional behavior of knitted fabrics. The results show that simulation error values for proposed technique and common methods are 2.7 and 9.4 percent as compared with the experimental result, respectively. Originality/value In the existing methods of the friction force modeling, the friction coefficient of fabric is assumed uniform. But this assumption is not correct because fabric does not have an isotropic structure. Thus in this study, the friction coefficient distribution is considered based on fabric structure to achieve more of realistic simulations.

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