scholarly journals TiO2-Seeded Hydrothermal Growth of Spherical BaTiO3 Nanocrystals for Capacitor Energy-Storage Application

Crystals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 202 ◽  
Author(s):  
Ming Li ◽  
Lulu Gu ◽  
Tao Li ◽  
Shiji Hao ◽  
Furui Tan ◽  
...  

Simple but robust growth of spherical BaTiO3 nanoparticles with uniform nanoscale sizes is of great significance for the miniaturization of BaTiO3-based electron devices. This paper reports a TiO2-seeded hydrothermal process to synthesize spherical BaTiO3 nanoparticles with a size range of 90–100 nm using TiO2 (Degussa) and Ba(NO3)2 as the starting materials under an alkaline (NaOH) condition. Under the optimum conditions ([NaOH] = 2.0 mol L−1, RBa/Ti = 2.0, T = 210 °C and t = 8 h), the spherical BaTiO3 nanoparticles obtained exhibit a narrow size range of 91 ± 14 nm, and the corresponding BaTiO3/polymer/Al film is of a high dielectric constant of 59, a high break strength of 102 kV mm−1, and a low dielectric loss of 0.008. The TiO2-seeded hydrothermal growth has been proved to be an efficient process to synthesize spherical BaTiO3 nanoparticles for potential capacitor energy-storage applications.

RSC Advances ◽  
2015 ◽  
Vol 5 (64) ◽  
pp. 51542-51548 ◽  
Author(s):  
Xuefeng Li ◽  
Wenhan Xu ◽  
Yunhe Zhang ◽  
Dan Xu ◽  
Guibin Wang ◽  
...  

Phthalocyanines chemical grafting acidified multi-walled carbon nanotubes and PVDF composites exhibited high dielectric performances for energy storage applications.


RSC Advances ◽  
2015 ◽  
Vol 5 (70) ◽  
pp. 57211-57211 ◽  
Author(s):  
Xuefeng Li ◽  
Wenhan Xu ◽  
Yunhe Zhang ◽  
Dan Xu ◽  
Guibin Wang ◽  
...  

Correction for ‘Chemical grafting of multi-walled carbon nanotubes on metal phthalocyanines for the preparation of nanocomposites with high dielectric constant and low dielectric loss for energy storage application’ by Xuefeng Li et al., RSC Adv., 2015, 5, 51542–51548.


2018 ◽  
Vol 6 (9) ◽  
pp. 2370-2378 ◽  
Author(s):  
Yang Liu ◽  
Cheng Zhang ◽  
Benyuan Huang ◽  
Xu Wang ◽  
Yulong Li ◽  
...  

A novel skin–core structured fluorinated MWCNT nanofiller was prepared to fabricate epoxy composite with broadband high dielectric constant and low dielectric loss.


RSC Advances ◽  
2017 ◽  
Vol 7 (38) ◽  
pp. 23309-23312 ◽  
Author(s):  
Ting Yang ◽  
Wenhui Xu ◽  
Xinwen Peng ◽  
Haoqing Hou

Crown ether-containing polyimides possess high dielectric constant and low dielectric loss, without sacrificing other properties.


2013 ◽  
Vol 1561 ◽  
Author(s):  
M.A Jithin ◽  
Lakshmi Ganapathi Kolla ◽  
Navakanta Bhat ◽  
S. Mohan ◽  
Yuichiro Morozumi ◽  
...  

ABSTRACTIn this study, synthesis and characterization of rutile-Titanium dioxide (TiO2) thin films using pulsed DC Magnetron Sputtering at room temperature, along with the fabrication and characterization of MIM capacitors have been discussed. XPS and RBS data show that the films are stoichiometric and have compositional uniformity. The influence of electrode materials on electrical characteristics of the fabricated MIM capacitors has been studied. The Al/TiO2/Al based capacitors show low capacitance density (9 fF/μm2) with low dielectric constant (K=25) and high EOT (3.67 nm) due to low dielectric constant TiO2 phase formation on Al/Si substrate. On the other hand, Ru/TiO2/Ru based capacitors show high capacitance density (49 fF/μm2) with high dielectric constant (K=130) and low EOT (0.7nm) values at high frequency (100 KHz) due to high dielectric constant phase (rutile) formation of TiO2, on Ru/Si substrate. Raman spectra confirm that the films deposited on Ru/Si substrate show the rutile phase.


1993 ◽  
Vol 37 ◽  
pp. 79-85 ◽  
Author(s):  
Hitoshi Ohsato ◽  
Toshiyuki Ohhashi ◽  
Kazuhiko Sumiya ◽  
Shinya Suzuki ◽  
Takashi Okuda

Microwave dielectric ceramics with high quality have received attention due to the rapid progress in microwave telecommunication and satellite broadcasting. The desirable properties in microwave dielectric resonators are a high dielectric constant (εr), low dielectric loss (tanδ) (i.e. high Q (Q =1/tanδ)), and low temperature coefficient of the resonant frequency(τf). Properties of dielectric ceramics in the TiO2-rich region of the BaO-Nd2O3-TiO2 ternary system (Fig. 1) were reported to have excellent dielectric constants, low dielectric losses and low temperature coefficients of capacitance by Kolar et al. (1978).


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