scholarly journals Electrochemical Behavior of Al–Al9Co2 Alloys in Sulfuric Acid

2020 ◽  
Vol 1 (2) ◽  
pp. 249-272 ◽  
Author(s):  
Athanasios K. Sfikas ◽  
Angeliki G. Lekatou
Keyword(s):  
Corrosion Resistance ◽  
Anodic Polarization ◽  
Al Alloys ◽  
Vacuum Arc ◽  
Uniform Corrosion ◽  
Arc Melting ◽  
Vacuum Arc Melting ◽  
Underlying Mechanisms ◽  
Co Alloys ◽  
Al Matrix

Al–Co alloys of various Co contents (2–20 wt.% Co) were fabricated by vacuum arc melting (VAM) with the scope to investigate the influence of cobalt on the microstructure and corrosion resistance of Al in 1 M H2SO4. The obtained microstructures were directional, consisting of Al9Co2 platelets (grown to coarse acicular plates as the Co content increased) uniformly dispersed in an Al-matrix. Alloying Al with Co did not decrease the rate of uniform corrosion of Al but it considerably increased its passivation ability. Moreover, all Al–Co alloys displayed lower uniform corrosion rate and notably higher passivation ability than market leading Al-alloys. The underlying mechanisms during anodic polarization in 1 M H2SO4 were identified and correlated with the microstructure. High Co content alloys (7–20 wt.% Co) presented superior passivation ability in 1 M H2SO4 as compared to the low Co content alloys.

scholarly journals Al-Co Alloys Prepared by Vacuum Arc Melting: Correlating Microstructure Evolution and Aqueous Corrosion Behavior with Co Content

Metals ◽  
2016 ◽  
Vol 6 (3) ◽  
pp. 46 ◽  
Author(s):  
Angeliki Lekatou ◽  
Athanasios Sfikas ◽  
Christina Petsa ◽  
Alexandros Karantzalis
Keyword(s):  
Corrosion Behavior ◽  
Microstructure Evolution ◽  
Vacuum Arc ◽  
Aqueous Corrosion ◽  
Arc Melting ◽  
Vacuum Arc Melting ◽  
Co Alloys

scholarly journals Irradiation Behaviors in BCC Multi-Component Alloys with Different Lattice Distortions

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 706
Author(s):  
Yue Su ◽  
Songqin Xia ◽  
Jia Huang ◽  
Qingyuan Liu ◽  
Haocheng Liu ◽  
...  
Keyword(s):  
Single Phase ◽  
Vacuum Arc ◽  
Face Centered Cubic ◽  
Body Centered Cubic ◽  
Chemical Complexity ◽  
Arc Melting ◽  
Vacuum Arc Melting ◽  
Lattice Distortions ◽  
Face Centered ◽  
Displacement Per Atom

Recently, the irradiation behaviors of multi-component alloys have stimulated an increasing interest due to their ability to suppress the growth of irradiation defects, though the mostly studied alloys are limited to face centered cubic (fcc) structured multi-component alloys. In this work, two single-phase body centered cubic (bcc) structured multi-component alloys (CrFeV, AlCrFeV) with different lattice distortions were prepared by vacuum arc melting, and the reference of α-Fe was also prepared. After 6 MeV Au ions irradiation to over 100 dpa (displacement per atom) at 500 °C, the bcc structured CrFeV and AlCrFeV exhibited significantly improved irradiation swelling resistance compared to α-Fe, especially AlCrFeV. The AlCrFeV alloy possesses superior swelling resistance, showing no voids compared to α-Fe and CrFeV alloy, and scarce irradiation softening appears in AlCrFeV. Owing to their chemical complexity, it is believed that the multi-component alloys under irradiation have more defect recombination and less damage accumulation. Accordingly, we discuss the origin of irradiation resistance and the Al effect in the studied bcc structured multi-component alloys.

scholarly journals Study on Microstructure and In Situ Tensile Deformation Behavior of Fe-25Mn-xAl-8Ni-C Alloy Prepared by Vacuum Arc Melting

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 814
Author(s):  
Yaping Bai ◽  
Meng Li ◽  
Chao Cheng ◽  
Jianping Li ◽  
Yongchun Guo ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Deformation Behavior ◽  
Tensile Deformation ◽  
Austenite Phase ◽  
Vacuum Arc ◽  
Al Content ◽  
Arc Melting ◽  
Vacuum Arc Melting ◽  
Tensile Deformation Behavior

In this study, Fe-25Mn-xAl-8Ni-C alloys (x = 10 wt.%, 11 wt.%, 12 wt.%, 13 wt.%) were prepared by a vacuum arc melting method, and the microstructure of this series of alloys and the in situ tensile deformation behavior were studied. The results showed that Fe-25Mn-xAl-8Ni-C alloys mainly contained austenite phase with a small amount of NiAl compound. With the content of Al increasing, the amount of austenite decreased while the amount of NiAl compound increased. When the Al content increased to 12 wt.%, the interface between austenite and NiAl compound and austenitic internal started to precipitate k-carbide phase. In situ tensile results also showed that as the content of Al increased, the alloy elongation decreased gradually, and the tensile strength first increased and then decreased. When the Al content was up to 11 wt.%, the elongation and tensile strength were 2.6% and 702.5 MPa, respectively; the results of in situ tensile dynamic observations show that during the process of stretching, austenite deformed first, and crack initiation mainly occurred at the interface between austenite and NiAl compound, and propagated along the interface, resulting in fracture of the alloy.

Microstructure and Mechanical Properties of VTaTiMoAlx Refractory High Entropy Alloys

2017 ◽  
Vol 898 ◽  
pp. 638-642 ◽  
Author(s):  
Dong Xu Qiao ◽  
Hui Jiang ◽  
Xiao Xue Chang ◽  
Yi Ping Lu ◽  
Ting Ju Li
Keyword(s):  
Mechanical Properties ◽  
Vacuum Arc ◽  
High Entropy Alloys ◽  
X Ray Diffraction ◽  
Dendrite Structure ◽  
X Ray ◽  
High Entropy ◽  
Arc Melting ◽  
Vacuum Arc Melting ◽  
Microstructure And Mechanical Properties

A series of refractory high-entropy alloys VTaTiMoAlx with x=0,0.2,0.6,1.0 were designed and produced by vacuum arc melting. The effect of added Al elements on the microstructure and mechanical properties of refractory high-entropy alloys were investigated. The X-ray diffraction results showed that all the high-entropy alloys consist of simple BCC solid solution. SEM indicated that the microstructure of VTaTiMoAlx changes from equiaxial dendritic-like structure to typical dendrite structure with the addition of Al element. The composition of different regions in the alloys are obtained by energy dispersive spectroscopy and shows that Ta, Mo elements are enriched in the dendrite areas, and Al, Ti, V are enriched in inter-dendrite areas. The yield strength and compress strain reach maximum (σ0.2=1221MPa, ε=9.91%) at x=0, and decrease with the addition of Al element at room temperature. Vickers hardness of the alloys improves as the Al addition.

The effect of 0.3 wt% oxygen on mechanical properties of a TiZrAl alloy prepared by vacuum arc melting

Vacuum ◽  
2020 ◽  
Vol 175 ◽  
pp. 109248 ◽  
Author(s):  
X.J. Jiang ◽  
Y.Y. Zhang ◽  
N. Yang ◽  
S.Q. Wang ◽  
Q.X. Ran
Keyword(s):  
Mechanical Properties ◽  
Vacuum Arc ◽  
Arc Melting ◽  
Vacuum Arc Melting

Properties and CA4GE-Engine Test of TiAl-Based Alloy Valves by Permanent Mold Casting

2010 ◽  
Vol 139-141 ◽  
pp. 557-560
Author(s):  
Wen Bin Sheng ◽  
Chun Xue Ma ◽  
Wan Li Gu
Keyword(s):  
Tial Alloy ◽  
Centrifugal Casting ◽  
Casting Process ◽  
Vacuum Arc ◽  
Permanent Mold ◽  
Casting Method ◽  
Arc Melting ◽  
Vacuum Arc Melting ◽  
Mold Casting ◽  
Induction Skull Melting

TiAl-based alloy valves were manufactured by combining charges compressed /vacuum arc melting (VA)/ induction skull melting (ISM) procedure with permanent mold centrifugal casting method. Microstructures, compositions and mechanical properties of as-cast and hot isostatical pressed (HIPed) valves are detected. Results show that the permanent mold centrifugal casting process obviously refines the size of grain in TiAl alloy and the tensile strength of as-cast and HIPed valves are 550MPa and 580MPa at 20°C, 370MPa and 470MPa at 815°C, respectively. As-cast specimens show ~0% elongation at 20°C and 1~2% at 815°C, while HIPed ones show an elongation of 1~2% at room temperature and about 10% at 815°C. Furthermore, a 200-hour test was carried out with CA4GE-engine, which demonstrated the possibility of as-cast TiAl alloy valves for the substitution of present steel ones.

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