scholarly journals Pore Structure Degradation of Different Cement Mortars Exposed to Sulphuric Acid

2019 ◽  
Vol 9 (24) ◽  
pp. 5297 ◽  
Author(s):  
José Ortega ◽  
Victoria García-Vera ◽  
Afonso Solak ◽  
Antonio Tenza-Abril
Keyword(s):  
Compressive Strength ◽  
Sulphuric Acid ◽  
Construction Material ◽  
Zinc Stearate ◽  
Acid Attack ◽  
Structure Degradation ◽  
Refined Microstructure ◽  
Cement Mortars ◽  
Different Types ◽  
Pronounced Reduction

Acid attack causes the deterioration of construction material surfaces. The objective of this study was to investigate the degradation of different types of cement mortar in terms of variations in pore size distribution obtained by mercury intrusion porosimetry (MIP), mass loss, and compressive strength. The mortars were manufactured with nanosilica, zinc stearate, and an ethyl silicate coating. After curing (28 days), the samples were subjected to acid exposure for 90 days, immersed ina solution (3% w/w) of sulphuric acid (H2SO4). The results indicate that the mortars showed a more refined microstructure, with a higher proportion of smaller pores (<100 nm) compared to the control mortar. The 28-day and 90-day compressive strength variations of mortars were also determined by observing pronounced reduction due to the appearance of expansive compounds responsible for microcracking.

scholarly journals Exposing Sustainable Mortars with Nanosilica, Zinc Stearate, and Ethyl Silicate Coating to Sulfuric Acid Attack

2018 ◽  
Vol 10 (10) ◽  
pp. 3769 ◽  
Author(s):  
Victoria García-Vera ◽  
Antonio Tenza-Abril ◽  
Marcos Lanzón ◽  
José Saval
Keyword(s):  
Compressive Strength ◽  
Sulfuric Acid ◽  
Mass Loss ◽  
Water Absorption ◽  
Zinc Stearate ◽  
Acid Exposure ◽  
Ethyl Silicate ◽  
Acid Attack ◽  
Water Absorption Coefficient ◽  
Silicate Coating

Obtaining durable materials that lengthen the service life of constructions and thereby contribute to sustainability requires research into products that improve the durability of cementitious materials under aggressive conditions. This paper studies the effects of sulfuric acid exposure on four mortar types (control mortar, mortar with nanosilica, mortar with zinc stearate, and mortar with an ethyl silicate coating), and evaluates which of them have better performance against the acid attack. After 28 days of curing, the samples were exposed to a sulfuric acid attack by immersing them in a 3% w/w of H2SO4 solution. Physical changes (mass loss, ultrasonic pulse velocity, open porosity, and water absorption), and mechanical changes (compressive strength) were determined after the sulfuric acid exposure. A scanning electron microscope (SEM) was used to characterize the morphology of the surface mortars after the exposure. The control mortar had the highest compressive strength after the acid attack, although of the four types, the zinc stearate mortar showed the lowest percentage of strength loss. The zinc stearate mortar had the lowest mass loss after the acid exposure; moreover, it had the lowest capillary water absorption coefficient (demonstrating its hydrophobic effect) both in a non-aggressive environment and acid attack.

scholarly journals Durability of Fly Ash Based Geopolymer Concrete against Chloride and Sulphuric Acid Attack

2020 ◽  
Vol 5 (6) ◽  
pp. 1507-1510
Author(s):  
Kartika Ilma Pratiw ◽  
Saloma .
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Sulphuric Acid ◽  
Test Object ◽  
Sulfate Solution ◽  
Geopolymer Concrete ◽  
Acid Attack

The aim of this study was to replace Portland cement with fly ash-based geopolymer as precursors, to serve as a binder after reacting with NaOH and Na2SiO3 activators. The test object existed in the form of a cube of size 50 x 50 x 50 mm. The mortar was treated for 28 days and then immersed in a sulfate solution at similar interval using the wet-dry cycle and non-cycle methods. The compressive strength of the geopolymer mortar was estimated as 45.90 MPa before immersion. Therefore, 35.79 MPa, 41.09 MPa, as well as 37.85 MPa were reported after submersion in the respective solutions of 5% H2SO4, Na2SO4, and NaCl, using wet-dry cycle. Based on the non-cycle approach, the resulting strength was 37.36 MPa, 43.05 MPa and 39.52 MPa correspondingly.

EFFECT OF SULPHURIC ACID ON CONCRETE WITH IRON ORE TAILINGSc

2016 ◽  
Vol 78 (6-12) ◽  
Author(s):  
Ali Umara Shettima ◽  
Mohd Warid Hussin ◽  
Yusof Ahmad ◽  
Mohammed Yau
Keyword(s):  
Compressive Strength ◽  
Mass Loss ◽  
Sulphuric Acid ◽  
Iron Ore ◽  
Strength Loss ◽  
Test Results ◽  
X Ray Diffraction ◽  
Acid Attack ◽  
Failure Patterns ◽  
Iron Ore Tailings

Researches into the uses of waste materials are increasingly being explored to meet up society’s needs and global protection for sustainable, safe and economic development. This paper assessed concrete with iron ore tailings (IOT) exposed to dilute sulphuric acid. Iron ore tailings are the materials left-over after separating the valuable fraction from the uneconomic fraction of an ore. To study the effect of sulphuric acid, concrete of 100 mm cube with a different mix ratios containing IOT were prepared and cured for 28 days in water. The cubes were later immersed into dilute sulphuric acid at a concentration of 5%. The compressive strength of concrete at 7, 28 and 90 days of water curing were determined. Mass loss and strength reduction due to sulphuric effect were evaluated at 7, 28 and 90 days respectively. XRD microstructure of concrete specimens was analysed. Test results indicated that the IOT could be used in concrete as sand replacement since the concrete with IOT has similar trend in compressive strength loss and mass loss to sulphuric acid attack compared to control specimen. The mineralogical crystal failure patterns due to the sulphuric acid in terms X-ray diffraction analysis are the same for control and IOT concrete. 

scholarly journals Influence of a Retarding Admixture on the Behavior of Mortars Made from Different Types of Cement

2018 ◽  
Vol 7 (4.20) ◽  
pp. 334
Author(s):  
Tumadhir Merawi Borhan ◽  
Munaf A. Al-Ramahee ◽  
Noor Al-Hassnawi ◽  
Zaid Ali AlZaidi
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Cement Mortar ◽  
Setting Time ◽  
Length Change ◽  
Setting Times ◽  
White Cement ◽  
Cement Mortars ◽  
Different Types ◽  
Positive Effect

The effect of retarding admixture on the fresh and hardened behaviour of different types of cement mortars and pastes when using a retarding admixture was investigated in this study. The types of cement used are; White cement (WhC), Ordinary Portland cement (OPC) and Sulphate Resistant Portland cement (SRC). Different cement mortar and paste mixes were cast, for this purpose, with and without the admixture. Initial and final setting times, compressive strength, length change, absorption and density for these mixes were examined at the curing ages of 3,7,28,45 days. The results showed that the addition of retarding admixture delayed the setting time significantly of WhC paste. The retarding admixture has a positive effect on the compressive strength of the mortar specimens for all types of cement used. regarding the length change test, the admixture was found to reduce the initial expansion for all types of cement at all ages. The results also showed an increase in the density and decrease in water absorption, especially at the later ages for all types of cement.  Among all cement types used, WhC was noticeably the most affected type by using the retarding admixture compared to other types of cement used.  

Durability of Fly Ash Geopolymer Mortars in Corrosive Environments, Compared to that of Cement Mortars

2014 ◽  
Vol 92 ◽  
pp. 84-89 ◽  
Author(s):  
A. Asprogerakas ◽  
Aristea Koutelia ◽  
Glykeria Kakali ◽  
Sotirios Tsivilis
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Building Materials ◽  
Acid Resistance ◽  
Chloride Diffusion ◽  
Strength Development ◽  
Acid Attack ◽  
Calcareous Sand ◽  
Cement Mortars ◽  
Improved Performance

In the present paper the durability of fly ash geopolymer mortars compared to that of cement mortars is investigated. Geopolymers can improve the ecological image of building materials, especially when their production is based on industrial by-products such as fly ash. Three series of fly ash based geopolymer mortars were prepared using calcareous sand to fly ash ratio (S/FA) varying from 0.5 to 2. In addition, cement mortar specimens were prepared using cement CEM I 42.5 N and CEM II 32.5 N. Durability of geopolymer and cement mortars was evaluated by means of compressive strength development, acid resistance, chloride diffusion and sulfate resistance. It was found that fly ash can be effectively used to produce geopolymer mortars with calcareous sand. Geopolymers exhibit competitive compressive strength compared to that of cement mortars. Geopolymer mortars develop their maximum compressive strength a few days after their casting. Geopolymer and cement mortars exhibit satisfactory resistance to sulphate attack. Cement mortars, generally, show better behaviour (compared to geopolymers) in chloride diffusion. Finally, geopolymers indicate improved performance against acid attack, compared to that of cement mortars.

Incorporation of Iraqi Rocks in the Production of Eco-Friendly Cement Mortar

2020 ◽  
Vol 38 (10A) ◽  
pp. 1522-1530
Author(s):  
Rawnaq S. Mahdi ◽  
Aseel B. AL-Zubidi ◽  
Hassan N. Hashim
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Compressive Strength ◽  
Water Absorption ◽  
Structural Properties ◽  
Mechanical Milling ◽  
Cement Mortar ◽  
Cement Mortars

This work reports on the incorporation of Flint and Kaolin rocks powders in the cement mortar in an attempt to improve its mechanical properties and produce an eco-friendly mortar. Flint and Kaolin powders are prepared by dry mechanical milling. The two powders are added separately to the mortars substituting cement partially. The two powders are found to improve the mechanical properties of the mortars. Hardness and compressive strength are found to increase with the increase of powders constituents in the cement mortars. In addition, the two powders affect water absorption and thermal conductivity of the mortar specimens which are desirable for construction applications. Kaolin is found to have a greater effect on the mechanical properties, water absorption, and thermal conductivity of the mortars than Flint. This behavior is discussed and analyzed based on the compositional and structural properties of the rocks powders.

scholarly journals Properties of Calcium Sulfoaluminate Cement Mortar Modified by Hydroxyethyl Methyl Celluloses with Different Degrees of Substitution

Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2136
Author(s):  
Shaokang Zhang ◽  
Ru Wang ◽  
Linglin Xu ◽  
Andreas Hecker ◽  
Horst-Michael Ludwig ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Flexural Strength ◽  
Bond Strength ◽  
Cement Mortar ◽  
Retention Rate ◽  
Methyl Cellulose ◽  
Tensile Bond Strength ◽  
Calcium Sulfoaluminate Cement ◽  
Calcium Sulfoaluminate ◽  
Cement Mortars

This paper studies the influence of hydroxyethyl methyl cellulose (HEMC) on the properties of calcium sulfoaluminate (CSA) cement mortar. In order to explore the applicability of different HEMCs in CSA cement mortars, HEMCs with higher and lower molar substitution (MS)/degree of substitution (DS) and polyacrylamide (PAAm) modification were used. At the same time, two kinds of CSA cements with different contents of ye’elimite were selected. Properties of cement mortar in fresh and hardened states were investigated, including the fluidity, consistency and water-retention rate of fresh mortar and the compressive strength, flexural strength, tensile bond strength and dry shrinkage rate of hardened mortar. The porosity and pore size distribution were also analyzed by mercury intrusion porosimetry (MIP). Results show that HEMCs improve the fresh state properties and tensile bond strength of both types of CSA cement mortars. However, the compressive strength of CSA cement mortars is greatly decreased by the addition of HEMCs, and the flexural strength is decreased slightly. The MIP measurement shows that HEMCs increase the amount of micron-level pores and the porosity. The HEMCs with different MS/DS have different effects on the improvement of tensile bond strength in different CSA cement mortars. PAAm modification can improve the tensile bond strength of HEMC-modified CSA cement mortar.

scholarly journals The Effect of Different Types of Internal Curing Liquid on the Properties of Alkali-Activated Slag (AAS) Mortar

2021 ◽  
Vol 13 (4) ◽  
pp. 2407
Author(s):  
Guang-Zhu Zhang ◽  
Xiao-Yong Wang ◽  
Tae-Wan Kim ◽  
Jong-Yeon Lim ◽  
Yi Han
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Deionized Water ◽  
Internal Curing ◽  
Control Group ◽  
Alkali Activated Slag ◽  
Different Types ◽  
Naoh Solution ◽  
Activated Slag ◽  
Alkali Activated

This study shows the effect of different types of internal curing liquid on the properties of alkali-activated slag (AAS) mortar. NaOH solution and deionized water were used as the liquid internal curing agents and zeolite sand was the internal curing agent that replaced the standard sand at 15% and 30%, respectively. Experiments on the mechanical properties, hydration kinetics, autogenous shrinkage (AS), internal temperature, internal relative humidity, surface electrical resistivity, ultrasonic pulse velocity (UPV), and setting time were performed. The conclusions are as follows: (1) the setting times of AAS mortars with internal curing by water were longer than those of internal curing by NaOH solution. (2) NaOH solution more effectively reduces the AS of AAS mortars than water when used as an internal curing liquid. (3) The cumulative heat of the AAS mortar when using water for internal curing is substantially reduced compared to the control group. (4) For the AAS mortars with NaOH solution as an internal curing liquid, compared with the control specimen, the compressive strength results are increased. However, a decrease in compressive strength values occurs when water is used as an internal curing liquid in the AAS mortar. (5) The UPV decreases as the content of zeolite sand that replaces the standard sand increases. (6) When internal curing is carried out with water as the internal curing liquid, the surface resistivity values of the AAS mortar are higher than when the alkali solution is used as the internal curing liquid. To sum up, both NaOH and deionized water are effective as internal curing liquids, but the NaOH solution shows a better performance in terms of reducing shrinkage and improving mechanical properties than deionized water.

scholarly journals Effect of Recycled Coarse Aggregate and Bagasse Ash on Two-Stage Concrete

Crystals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 556
Author(s):  
Muhammad Faisal Javed ◽  
Afaq Ahmad Durrani ◽  
Sardar Kashif Ur Rehman ◽  
Fahid Aslam ◽  
Hisham Alabduljabbar ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Compressive Strength ◽  
Coarse Aggregate ◽  
Construction Material ◽  
Strength Reduction ◽  
Recycled Aggregate ◽  
Two Stage ◽  
Conventional Concrete ◽  
Recycled Coarse Aggregate ◽  
Coarse Aggregates

Numerous research studies have been conducted to improve the weak properties of recycled aggregate as a construction material over the last few decades. In two-stage concrete (TSC), coarse aggregates are placed in formwork, and then grout is injected with high pressure to fill up the voids between the coarse aggregates. In this experimental research, TSC was made with 100% recycled coarse aggregate (RCA). Ten percent and twenty percent bagasse ash was used as a fractional substitution of cement along with the RCA. Conventional concrete with 100% natural coarse aggregate (NCA) and 100% RCA was made to determine compressive strength only. Compressive strength reduction in the TSC was 14.36% when 100% RCA was used. Tensile strength in the TSC decreased when 100% RCA was used. The increase in compressive strength was 8.47% when 20% bagasse ash was used compared to the TSC mix that had 100% RCA. The compressive strength of the TSC at 250 °C was also determined to find the reduction in strength at high temperature. Moreover, the compressive and tensile strength of the TSC that had RCA was improved by the addition of bagasse ash.

Effect of Paper Sludge Ash on the Compressive Strength of Plaster of Paris/Paper Sludge Ash Composites

2012 ◽  
Vol 501 ◽  
pp. 34-38 ◽  
Author(s):  
Kar Keng Lim ◽  
Roslinda Shamsudin ◽  
Muhammad Azmi Abdul Hamid
Keyword(s):  
Compressive Strength ◽  
Construction Material ◽  
Paper Industry ◽  
Pulp And Paper Industry ◽  
Paper Sludge ◽  
Mixed Powder ◽  
Plaster Of Paris ◽  
Paper Sludge Ash ◽  
Sludge Ash ◽  
Cylindrical Samples

In this study, paper sludge ash, a waste from pulp and paper industry was used as a filler in fabricating Plaster of Paris/paper sludge ash composites. Various percentage of paper sludge ash was used, namely 1wt.%, 3wt.%, 5wt.% and 7wt.%. The effect of paper sludge ash on the compressive strength of the Plaster of Paris was studied. The mixed powder of paper sludge ash and Plaster of Paris were form into a 6 mm diameter and 12 mm height cylindrical samples. The composites were characterized theirs density where it shows that the density decreased as the amount of paper sludge ash increased. The compressive strength of the composites also decreased from 11.67 MPa without paper sludge ash addition to 0.50 MPa at 7wt.% paper sludge ash. However, the requirement of strength for Plaster of Paris in industry is between 8.96 MPa to 20.68 MPa. From the SEM observation, sample contain higher percentage of paper sludge ash exhibited more porosity. Therefore with the addition of 1wt.% of paper sludge ash into Plaster of Paris can be a promising construction material.

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