scholarly journals Assessment of Crystallinity Development during Fused Filament Fabrication through Fast Scanning Chip Calorimetry

2019 ◽  
Vol 9 (13) ◽  
pp. 2676 ◽  
Author(s):  
Dries Vaes ◽  
Margot Coppens ◽  
Bart Goderis ◽  
Wim Zoetelief ◽  
Peter Van Puyvelde
Keyword(s):  
Rapid Heating ◽  
Single Layer ◽  
Weld Strength ◽  
Fused Filament Fabrication ◽  
Crystalline Polymers ◽  
Molecular Weights ◽  
Heating And Cooling ◽  
Chip Calorimetry ◽  
The Impact ◽  
Fast Scanning Chip Calorimetry

Although semi-crystalline polymers are associated with considerably better mechanical properties and thermal stability compared to their amorphous counterparts, using them as feedstock for Fused Filament Fabrication still poses some major challenges. Hence, the development of printed part crystallinity during printing should be fully understood in order to control the developed weld strength, as well as part shrinkage and warpage. Infrared thermography was utilized to record the thermal history of deposited layers while printing a single-layer wall geometry, employing two PA 6/66 copolymers with distinct molecular weights as feedstock. Print settings were varied to establish which settings are essential to effectively monitor final part crystallinity. The resulting temperature profiles were simulated in a Fast Scanning Chip Calorimetry device that allows for the rapid heating and cooling rates experienced by the printed polymer. Both liquefier temperature and print speed were found to have very little influence on the total attained crystallinity. It became apparent that the build plate, set at a temperature above the polymer’s glass transition temperature, imposes a considerable annealing effect on the printed part. A reduced molecular weight was observed to enhance crystallinity even more strongly. The presented methodology proves that Fast Scanning Chip Calorimetry is an effective tool to assess the impact of both print parameters and feedstock characteristics on the crystallization behavior of semi-crystalline polymers over the course of printing.

scholarly journals Dependence of Crystallization Behavior of Interacting Telechelic Poly(butylene succinate) Oligomer on Molecular Weight

Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1530
Author(s):  
Cong Chen ◽  
Xue-Wen Zhang ◽  
Hai-Mu Ye
Keyword(s):  
Growth Rate ◽  
Crystallization Rate ◽  
Crystal Nucleation ◽  
Nucleation Density ◽  
Butylene Succinate ◽  
Nucleation Behavior ◽  
Crystalline Polymers ◽  
Molecular Weights ◽  
Primary Nucleation ◽  
The Impact

A large spherulite structure deteriorates the mechanical properties of crystalline polymers, and therefore various methods have been explored to increase primary nucleation density. Recently, chain-end modification has been proposed as an effective approach for regulating polymer crystal nucleation. However, the relevant nucleation mechanism still requires investigation. Therefore, in this work, 2-ureido-4[1H]-pyrimidinone (UPy) units, which can form stacks via quadruple hydrogen bonds with each other, are introduced as end groups for the preparation of interacting telechelic poly(butylene succinate) (PBS-UPy) oligomers with different molecular weights (Mns). The crystallization, especially the nucleation behavior of PBS-UPy, is studied in detail by comparing with the corresponding pre-polymer, the hydroxyl-terminal PBS (PBS-OH). The thermal properties of PBS-UPy exhibit similar Mn-dependent tendency to those of PBS-OH, but with weaker total crystallization rate. The spherulite growth rate is significantly reduced, whereas the primary nucleation density is highly promoted, after introducing UPy groups. Further investigation reveals that the mechanism of UPy stacks’ influence on nucleation ability changes from inhibition to promotion with respect to Mn. Even under an inhibition of nucleation ability, the final nucleation density is obviously increased because of a significant decline of the growth rate. In addition, the change in the impact of UPy stacks on nucleation ability is speculated to originate from the memory expression feasibility of ordered conformation in the melt during crystallization.

scholarly journals Crystallization of Random Metallocene-Catalyzed Propylene-Based Copolymers with Ethylene and 1-Hexene on Rapid Cooling

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2091
Author(s):  
Daniela Mileva ◽  
Jingbo Wang ◽  
René Androsch ◽  
Katalee Jariyavidyanont ◽  
Markus Gahleitner ◽  
...  
Keyword(s):  
Mechanical Performance ◽  
Metallocene Catalyst ◽  
Nucleating Agent ◽  
Random Copolymers ◽  
Rapid Cooling ◽  
Significant Difference ◽  
Chip Calorimetry ◽  
High Cooling Rates ◽  
Fast Scanning Chip Calorimetry

Propylene-based random copolymers with either ethylene or 1-hexene as comonomer, produced using a metallocene catalyst, were studied regarding their crystallization behaviors, with a focus on rapid cooling. To get an impression of processing effects, fast scanning chip calorimetry (FSC) was used in addition to the characterization of the mechanical performance. When comparing the comonomer type and the relation to commercial grades based on Ziegler–Natta-type catalysts, both an interaction with the catalyst-related regio-defects and a significant difference between ethylene and 1-hexene was observed. A soluble-type nucleating agent was found to modify the behavior, but to an increasingly lesser degree at high cooling rates.

scholarly journals Damage Evolution of Granodiorite after Heating and Cooling Treatments

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 779
Author(s):  
Mohamed Gomah ◽  
Guichen Li ◽  
Salah Bader ◽  
Mohamed Elkarmoty ◽  
Mohamed Ismael
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Failure Mode ◽  
Physical And Mechanical Properties ◽  
P Wave ◽  
Physical Parameters ◽  
Slow Cooling ◽  
Heating And Cooling ◽  
Natural Rock ◽  
The Impact

The awareness of the impact of high temperatures on rock properties is essential to the design of deep geotechnical applications. The purpose of this research is to assess the influence of heating and cooling treatments on the physical and mechanical properties of Egyptian granodiorite as a degrading factor. The samples were heated to various temperatures (200, 400, 600, and 800 °C) and then cooled at different rates, either slowly cooled in the oven and air or quickly cooled in water. The porosity, water absorption, P-wave velocity, tensile strength, failure mode, and associated microstructural alterations due to thermal effect have been studied. The study revealed that the granodiorite has a slight drop in tensile strength, up to 400 °C, for slow cooling routes and that most of the physical attributes are comparable to natural rock. Despite this, granodiorite thermal deterioration is substantially higher for quick cooling than for slow cooling. Between 400:600 °C is ‘the transitional stage’, where the physical and mechanical characteristics degraded exponentially for all cooling pathways. Independent of the cooling method, the granodiorite showed a ductile failure mode associated with reduced peak tensile strengths. Additionally, the microstructure altered from predominantly intergranular cracking to more trans-granular cracking at 600 °C. The integrity of the granodiorite structure was compromised at 800 °C, the physical parameters deteriorated, and the rock tensile strength was negligible. In this research, the temperatures of 400, 600, and 800 °C were remarked to be typical of three divergent phases of granodiorite mechanical and physical properties evolution. Furthermore, 400 °C could be considered as the threshold limit for Egyptian granodiorite physical and mechanical properties for typical thermal underground applications.

scholarly journals QPOs in compact binaries from small scale eruptions in an inner magnetized disk

2020 ◽  
Author(s):  
Nicolas Scepi ◽  
Mitchell C Begelman ◽  
Jason Dexter
Keyword(s):  
Rapid Heating ◽  
Small Scale ◽  
Type B ◽  
Periodic Oscillations ◽  
X Ray ◽  
Compact Binaries ◽  
Heating And Cooling ◽  
Low Mass ◽  
X Ray Binaries ◽  
Standard Disk

Abstract Dwarf novæ (DNe) and low mass X-ray binaries (LMXBs) are compact binaries showing variability on time scales from years to less than seconds. Here, we focus on explaining part of the rapid fluctuations in DNe, following the framework of recent studies on the monthly eruptions of DNe that use a hybrid disk composed of an outer standard disk and an inner magnetized disk. We show that the ionization instability, that is responsible for the monthly eruptions of DNe, is also able to operate in the inner magnetized disk. Given the low density and the fast accretion time scale of the inner magnetized disk, the ionization instability generates small, rapid heating and cooling fronts propagating back and forth in the inner disk. This leads to quasi-periodic oscillations (QPOs) with a period of the order of 1000 s. A strong prediction of our model is that these QPOs can only develop in quiescence or at the beginning/end of an outburst. We propose that these rapid fluctuations might explain a subclass of already observed QPOs in DNe as well as a, still to observe, subclass of QPOs in LMXBs. We also extrapolate to the possibility that the radiation pressure instability might be related to Type B QPOs in LMXBs.

Design of a Robust Memristive Spiking Neuromorphic System with Unsupervised Learning in Hardware

2021 ◽  
Vol 17 (4) ◽  
pp. 1-26
Author(s):  
Md Musabbir Adnan ◽  
Sagarvarma Sayyaparaju ◽  
Samuel D. Brown ◽  
Mst Shamim Ara Shawkat ◽  
Catherine D. Schuman ◽  
...  
Keyword(s):  
Unsupervised Learning ◽  
Recognition Task ◽  
Single Layer ◽  
Process Variations ◽  
Spike Timing ◽  
System Level ◽  
Design Parameters ◽  
Digital Pulse ◽  
Neuromorphic System ◽  
The Impact

Spiking neural networks (SNN) offer a power efficient, biologically plausible learning paradigm by encoding information into spikes. The discovery of the memristor has accelerated the progress of spiking neuromorphic systems, as the intrinsic plasticity of the device makes it an ideal candidate to mimic a biological synapse. Despite providing a nanoscale form factor, non-volatility, and low-power operation, memristors suffer from device-level non-idealities, which impact system-level performance. To address these issues, this article presents a memristive crossbar-based neuromorphic system using unsupervised learning with twin-memristor synapses, fully digital pulse width modulated spike-timing-dependent plasticity, and homeostasis neurons. The implemented single-layer SNN was applied to a pattern-recognition task of classifying handwritten-digits. The performance of the system was analyzed by varying design parameters such as number of training epochs, neurons, and capacitors. Furthermore, the impact of memristor device non-idealities, such as device-switching mismatch, aging, failure, and process variations, were investigated and the resilience of the proposed system was demonstrated.

scholarly journals Experimental studies on the possibility of using a pulsed laser for spot welding of thin metallic foils

2020 ◽  
Vol 10 (1) ◽  
pp. 674-680
Author(s):  
Piotr Sęk
Keyword(s):  
Experimental Studies ◽  
Pulsed Laser ◽  
Welding Process ◽  
Pulse Mode ◽  
Weld Strength ◽  
Spot Welds ◽  
Butt Welding ◽  
Strength Tests ◽  
Metallic Foils ◽  
The Impact

AbstractThe purpose of the experiment was to study the influence of the laser beam in pulse mode on metallic foils in order to obtain a spot weld. The welding process was carried out using the overlap weld method, using spot welds in various quantities. The Nd - YAG BLS 720 pulsed laser was used to conduct the experiment. The impact of the number of spot welds on the value of force needed to break the sample was examined. A number of measurements were carried out to determine the best process parameters. Butt welding and overlap welding were also performed using a continuous weld consisting of spot welds. Weld strength tests were performed to select the most appropriate parameters for the process under consideration.

scholarly journals Analysis of the Impact on the Mechanical Properties of Modification of Oligohydroxyethers in Organic Solvent Solution with Rubbers

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 519
Author(s):  
Vitalii Bezgin ◽  
Agata Dudek ◽  
Adam Gnatowski
Keyword(s):  
Mechanical Properties ◽  
Scientific Paper ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Molecular Weights ◽  
Wide Range ◽  
Strength Tests ◽  
Materials Used ◽  
Styrene Butadiene ◽  
The Impact

This paper proposes and presents the chemical modification of linear hydroxyethers (LHE) with different molecular weights (380, 640, and 1830 g/mol) with the addition of three types of rubbers (polysulfide rubber (PSR), polychloroprene rubber (PCR), and styrene-butadiene rubber (SBR)). The main purpose of choosing this type of modification and the materials used was the possibility to use it in industrial settings. The modification process was conducted for a very wide range of modifier additions (rubber) per 100 g LHE. The materials obtained in the study were subjected to strength tests in order to determine the effect of the modification on functional properties. Mechanical properties of the modified materials were improved after the application of the modifier (rubber) to polyhydroxyether (up to certain modifier content). The most favorable changes in the tested materials were registered in the modification of LHE-1830 with PSR. In the case of LHE-380 and LHE-640 modified in cyclohexanol (CH) and chloroform (CF) solutions, an increase in the values of the tested properties was also obtained, but to a lesser extent than for LHE-1830. The largest changes were registered for LHE-1830 with PSR in CH solution: from 12.1 to 15.3 MPa for compressive strength tests, from 0.8 to 1.5 MPa for tensile testing, from 0.8 to 14.7 MPa for shear strength, and from 1% to 6.5% for the maximum elongation. The analysis of the available literature showed that the modification proposed by the authors has not yet been presented in any previous scientific paper.

Rapid heating and cooling of aluminum alloys in a fluidized bed

1970 ◽  
Vol 12 (2) ◽  
pp. 156-159 ◽  
Author(s):  
V. P. Kurbatov ◽  
V. I. Murav'ev
Keyword(s):  
Aluminum Alloys ◽  
Fluidized Bed ◽  
Rapid Heating ◽  
Heating And Cooling

scholarly journals Analysis of actinic flux profiles measured from an ozonesonde balloon

2015 ◽  
Vol 15 (8) ◽  
pp. 4131-4144 ◽  
Author(s):  
P. Wang ◽  
M. Allaart ◽  
W. H. Knap ◽  
P. Stammes
Keyword(s):  
Atmospheric Chemistry ◽  
Low Cost ◽  
Green Light ◽  
Single Layer ◽  
Radiative Transfer Model ◽  
Cloud Base ◽  
Transfer Model ◽  
Actinic Flux ◽  
Clear Sky ◽  
The Impact

Abstract. A green light sensor has been developed at KNMI to measure actinic flux profiles using an ozonesonde balloon. In total, 63 launches with ascending and descending profiles were performed between 2006 and 2010. The measured uncalibrated actinic flux profiles are analysed using the Doubling–Adding KNMI (DAK) radiative transfer model. Values of the cloud optical thickness (COT) along the flight track were taken from the Spinning Enhanced Visible and Infrared Imager (SEVIRI) Cloud Physical Properties (CPP) product. The impact of clouds on the actinic flux profile is evaluated on the basis of the cloud modification factor (CMF) at the cloud top and cloud base, which is the ratio between the actinic fluxes for cloudy and clear-sky scenes. The impact of clouds on the actinic flux is clearly detected: the largest enhancement occurs at the cloud top due to multiple scattering. The actinic flux decreases almost linearly from cloud top to cloud base. Above the cloud top the actinic flux also increases compared to clear-sky scenes. We find that clouds can increase the actinic flux to 2.3 times the clear-sky value at cloud top and decrease it to about 0.05 at cloud base. The relationship between CMF and COT agrees well with DAK simulations, except for a few outliers. Good agreement is found between the DAK-simulated actinic flux profiles and the observations for single-layer clouds in fully overcast scenes. The instrument is suitable for operational balloon measurements because of its simplicity and low cost. It is worth further developing the instrument and launching it together with atmospheric chemistry composition sensors.

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