scholarly journals Preparation and Two-Photon Photoluminescence Properties of Organic Inorganic Hybrid Perovskites (C6H5CH2NH3)2PbBr4 and (C6H5CH2NH3)2PbI4

2018 ◽  
Vol 8 (11) ◽  
pp. 2286 ◽  
Author(s):  
Shuai Liu ◽  
Fang Li ◽  
Xiaobo Han ◽  
Litu Xu ◽  
Fuqiang Yao ◽  
...  
Keyword(s):  
Laser Power ◽  
Radiation Detection ◽  
Photoluminescence Properties ◽  
Inorganic Hybrid ◽  
Two Photon ◽  
Structure Morphology ◽  
Potential Applications ◽  
Pl Intensity ◽  
Stacking Structure ◽  
Inorganic Components

Organic inorganic hybrid perovskites have potential applications in solar cells, electroluminescent devices and radiation detection because of their unique optoelectronic properties. In this paper, the perovskites (C6H5CH2NH3)2PbBr4 and (C6H5CH2NH3)2PbI4 were synthesized by solvent evaporation. The crystal structure, morphology, absorption spectrum, laser power dependence of the photoluminescence (PL) intensity and lifetime were studied. The results showed that the perovskites (C6H5CH2NH3)2PbBr4 and (C6H5CH2NH3)2PbI4 display a layered stacking structure of organic and inorganic components. The absorption peaks are located at 392 nm (3.16 eV) and 516 nm (2.40 eV), respectively. It was observed that the PL intensity and photoluminescence quantum yield (PLQY) increases with increasing laser power, and that the PL lifetime decreases with increasing laser power, which is mainly due to the non-geminate recombination.

scholarly journals Synthesis, Structure and Photoluminescence Properties of 2D Organic–Inorganic Hybrid Perovskites

2019 ◽  
Vol 9 (23) ◽  
pp. 5211 ◽  
Author(s):  
Liu ◽  
Li ◽  
Yao ◽  
He ◽  
Liu ◽  
...  
Keyword(s):  
Absorption Spectra ◽  
Laser Power ◽  
Radiation Detection ◽  
Photoluminescence Properties ◽  
Atom Number ◽  
Layer Spacing ◽  
Inorganic Hybrid ◽  
Potential Applications ◽  
Halide Perovskites ◽  
Organic Amines

Two-dimensional (2D) layered hybrid organic–inorganic perovskites have potential applications in solar cells, electroluminescent devices and radiation detection because of their unique optoelectronic properties. In this paper, four 2D layered hybrid organic–inorganic halide perovskites of (C6H5CH2NH3)2PbCl4, (C6H5CH2NH3)2PbBr4, (C6H5CH2NH3)2PbI4 and (C4H9NH3)2PbBr4 were synthesized by solvent evaporation. Their crystal structure and surface morphology were studied. The effects of different halogens and organic amines on perovskites’ absorption spectra were investigated, and the photoluminescence (PL) properties were studied by femtosecond ultrafast spectroscopy. The experimental results show that the four perovskites are well crystallized and oriented. With the increase of halogen atom number (Cl, Br, I) in turn, the UV-Vis absorption spectra peaks of perovskites redshift due to the increasing of the layer spacing, but organic amines have little effect on the spectra of perovskites. The PL intensity increases with increasing laser power, but the lifetime decreases with increasing laser power, which is mainly due to the non-geminate recombination. This research is of great significance for realizing the spectral regulation of organic–inorganic hybrid perovskites and promoting their application in nano-photonics and optoelectronic devices.

A Novel Multibranched Chromophore Containing Carbazole Moiety for Two-Photon Microfabrication

2012 ◽  
Vol 485 ◽  
pp. 566-569
Author(s):  
Zhi Yuan Hu ◽  
Fu Quan Guo ◽  
Hao Liang ◽  
Bin Guo
Keyword(s):  
Cross Section ◽  
Laser Power ◽  
Photon Absorption ◽  
Structural Motif ◽  
Incident Laser ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Incident Laser Power ◽  
Potential Applications ◽  
Pentaerythritol Triacrylate

A novel multibranched chromophore containing carbazole moiety，4, 4´, 4´´-tris(9-carbazyl-trans-styryl) triphenylamine (TCSTPA)，was synthesized and characterized by 1HNMR and elemental analysis. A larger two-photon absorption (TPA) cross section of the chromophore was obtained as high as 2350 GM compared to that of the traditional linear chromophore when pumped by a femtosecond laser at 800 nm. Microstructure based on TPA induced polymerization with a spatial resolution of submicron was fabricated under much lower incident laser power using TCSTPA as a TPA photoinitiator and a multifunctional resin of pentaerythritol triacrylate (PETA) as a polymerizable monomer. The result indicates potential applications of this kind of chromophores with multibranched structural motif in the fabrication of polymer and functional microdevices.

Synthesis and characterization of optical properties of soft and hard Er3+-doped (K Na)NbO3 piezophotonic ceramics

2020 ◽  
Vol 557 (1) ◽  
pp. 73-84
Author(s):  
M. C. dos Santos ◽  
J. A. Eiras ◽  
M. H. Lente
Keyword(s):  
Excited State Absorption ◽  
Photon Absorption ◽  
Visible Range ◽  
Secondary Phases ◽  
Absorption Process ◽  
Photoluminescence Properties ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Potential Applications

Real-time tuning of photoluminescence properties are highly desirable for potential applications. Thus, one proposed approach is to tune the photoluminescence emissions by applying an external electric field. However, in order to switch the ferroelectric polarization, high quality bulk ceramics is demanded. In this work, soft and hard Er3+-doped (K,Na)NbO3 piezophotonic ceramics were prepared by the conventional route and their microstructural, structural and up-conversion emission properties were investigated. Dense and free from secondary phases ceramics were successfully produced. The photoluminescence spectra, in the visible range, were characterized as a function of the pumping power. For the soft composition, a remarkable green shift was verified with increasing the laser power. It was supposed that the excited state absorption, involving a three-photon absorption process, was involved in the 4S3/2→4I15/2 transition. For the hard composition, the two-photon absorption process was dominant and the presence of complex defects reduced significantly the 4F9/2→4I15/2 transition.

Role of Sm3+ Doping on Structural, Optical and Photoluminescence Properties of ZnO Nanoparticles Synthesized by Sol-gel Auto- combustion Method

2020 ◽  
Vol 5 (3) ◽  
pp. 236-251
Author(s):  
Eshwara I. Naik ◽  
Halehatty S.B. Naik ◽  
Ranganaik Viswanath
Keyword(s):  
Zno Nanoparticles ◽  
Sol Gel ◽  
Combustion Method ◽  
Content Increase ◽  
Photoluminescence Properties ◽  
Tem Analysis ◽  
Auto Combustion ◽  
Ion Doping ◽  
Doped Zno ◽  
Pl Intensity

Background: Various interesting consequences are reported on structural, optical, and photoluminescence properties of Zn1-xSmxO (x=0, 0.01, 0.03 and 0.05) nanoparticles synthesized by sol-gel auto-combustion route. Objective: This study aimed to examine the effects of Sm3+-doping on structural and photoluminescence properties of ZnO nanoparticles. Methods: Zn1-xSmxO (x=0, 0.01, 0.03 and 0.05) nanoparticles were synthesized by sol-gel auto combustion method. Results: XRD patterns confirmed the Sm3+ ion substitution through the undisturbed wurtzite structure of ZnO. The crystallite size was decreased from 24.33 to 18.46 nm with Sm3+ doping. The hexagonal and spherical morphology of nanoparticles was confirmed by TEM analysis. UV-visible studies showed that Sm3+ ion doping improved the visible light absorption capacity of Sm3+ iondoped ZnO nanoparticles. PL spectra of Sm3+ ion-doped ZnO nanoparticles showed an orange-red emission peak corresponding to 4G5/2→6HJ (J=7/2, 9/2 and 11/2) transition of Sm3+ ion. Sm3+ ion-induced PL was proposed with a substantial increase in PL intensity with a blue shift in peak upon Sm3+ content increase. Conclusion: Absorption peaks associated with doped ZnO nanoparticles were moved to a longer wavelength side compared to ZnO, with bandgap declines when Sm3+ ions concentration was increased. PL studies concluded that ZnO emission properties could be tuned in the red region along with the existence of blue peaks upon Sm3+ ion doping, which also results in enhancing the PL intensity. These latest properties related to Sm3+ ion-doped nanoparticles prepared by a cost-efficient process appear to be interesting in the field of optoelectronic applications, which makes them a prominent candidate in the form of red light-emitting diodes.

scholarly journals Organic–Inorganic Hybrid Materials

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 86
Author(s):  
Jesús-María García-Martínez ◽  
Emilia P. Collar
Keyword(s):  
Hybrid Materials ◽  
Hybrid Material ◽  
International Union ◽  
Applied Chemistry ◽  
Inorganic Hybrid ◽  
Organic Components ◽  
Intimate Mixture ◽  
Inorganic Components

According to the IUPAC (International Union of Pure and Applied Chemistry), a hybrid material is that composed of an intimate mixture of inorganic components, organic components, or both types of components which usually interpenetrate on scales of less than 1 μm [...]

Acoustic Field-Assisted Two-Photon Polymerization Process

2021 ◽  
Vol 143 (10) ◽  
Author(s):  
Ketki M. Lichade ◽  
Yayue Pan
Keyword(s):  
Polymer Composite ◽  
Acoustic Field ◽  
Laser Power ◽  
Liquid Droplet ◽  
Three Dimensional ◽  
Polymerization Process ◽  
Photothermal Effect ◽  
Full Potential ◽  
Two Photon ◽  
Two Photon Polymerization

Abstract This study successfully integrates acoustic patterning with the Two-Photon Polymerization (TPP) process for printing nanoparticle–polymer composite microstructures with spatially varied nanoparticle compositions. Currently, the TPP process is gaining increasing attention within the engineering community for the direct manufacturing of complex three-dimensional (3D) microstructures. Yet the full potential of TPP manufactured microstructures is limited by the materials used. This study aims to create and demonstrate a novel acoustic field-assisted TPP (A-TPP) process, which can instantaneously pattern and assemble nanoparticles in a liquid droplet, and fabricate anisotropic nanoparticle–polymer composites with spatially controlled particle–polymer material compositions. It was found that the biggest challenge in integrating acoustic particle patterning with the TPP process is that nanoparticles move upon laser irradiation due to the photothermal effect, and hence, the acoustic assembly is distorted during the photopolymerization process. To cure acoustic assembly of nanoparticles in the resin through TPP with the desired nanoparticle patterns, the laser power needs to be carefully tuned so that it is adequate for curing while low enough to prevent the photothermal effect. To address this challenge, this study investigated the threshold laser power for polymerization of TPP resin (Pthr) and photothermal instability of the nanoparticle (Pthp). Patterned nanoparticle–polymer composite microstructures were fabricated using the novel A-TPP process. Experimental results validated the feasibility of the developed acoustic field-assisted TPP process on printing anisotropic composites with spatially controlled material compositions.

scholarly journals Photoluminescence properties of ZrO2:Gd3+, ZrO2:Gd3+ – Dy3+ and ZrO2:Gd3+ – Yb3+ phosphors by Pechini method

2018 ◽  
Vol 36 (1) ◽  
pp. 157-161
Author(s):  
Esra Yildiz
Keyword(s):  
Powder Diffraction ◽  
Optical Materials ◽  
Pechini Method ◽  
Photoluminescence Properties ◽  
Emission Analysis ◽  
Lifetime Measurements ◽  
X Ray ◽  
Thermal Gravimetry ◽  
Potential Applications ◽  
Scanning Electron

AbstractZr0.99Gd0.01O2, Zr0.98Gd0.01Dy0.01O2 and Zr0.98Gd0.01Yb0.1O2 phosphors were synthesized by Pechini method at 1200 °C for 12 h in air. The phosphors were characterized by using X-ray powder diffraction (XRD), differential thermal analysis/thermal gravimetry (DTA/TG), scanning electron microscopy (SEM) and photoluminescence spectrofluorometer (PL). X-ray powder diffraction studies showed that the phosphors were crystallized as monoclinic and tetragonal multiphases. The particle size of the phosphors after heat treatment at 1200 °C was found to be of 200 nm to 250 nm. Luminescence studies on these phosphors have been carried out on the emission and excitation, along with lifetime measurements. The results of emission analysis indicate that the phosphors are expected to find potential applications as new optical materials.

Sign in / Sign up

Export Citation Format

Share Document