scholarly journals Mg-Based Hydrogen Absorbing Materials for Thermal Energy Storage—A Review

2018 ◽  
Vol 8 (8) ◽  
pp. 1375 ◽  
Author(s):  
Bo Li ◽  
Jianding Li ◽  
Huaiyu Shao ◽  
Liqing He
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Energy Loss ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Heat Storage ◽  
High Energy ◽  
Low Energy ◽  
Potential Candidate ◽  
Chemical Heat

Utilization of renewable energy such as solar, wind, and geothermal power, appears to be the most promising solution for the development of sustainable energy systems without using fossil fuels. Energy storage, especially to store the energy from fluctuating power is quite vital for smoothing out energy demands with peak/off-peak hour fluctuations. Thermal energy is a potential candidate to serve as an energy reserve. However, currently the development of thermal energy storage (TES) by traditional physical means is restricted by the relatively low energy density, high temperature demand, and the great thermal energy loss during long-period storage. Chemical heat storage is one of the most promising alternatives for TES due to its high energy density, low energy loss, flexible temperature range, and excellent storage duration. A comprehensive review on the development of different types of Mg-based materials for chemical heat storage is presented here and the classic and state-of-the-art technologies are summarized. Some related chemical principles, as well as heat storage properties, are discussed in the context. Finally, some dominant factors of chemical heat storage materials are concluded and the perspective is proposed for the development of next-generation chemical heat storage technologies.

Towards High Energy Density, High Conductivity Thermal Energy Storage Composites

2012 ◽  
Author(s):  
Patrick J. Shamberger ◽  
Daniel E. Forero
Keyword(s):  
Thermal Conductivity ◽  
Energy Storage ◽  
Energy Density ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Nitrate ◽  
Nitrate Trihydrate ◽  
Graphitic Foam

Thermal energy storage (TES) materials absorb transient pulses of heat, allowing for rapid storage of low-quality thermal energy for later use, and effective temperature regulation as part of a thermal management system. This paper describes recent development of salt hydrate-based TES composites at the Air Force Research Laboratory. Salt hydrates are known to be susceptible to undercooling and chemical segregation, and their bulk thermal conductivities remain too low for rapid heat transfer. Here, we discuss recent progress towards solving these challenges in the composite system lithium nitrate trihydrate/graphitic foam. This system takes advantage of both the high volumetric thermal energy storage density of lithium nitrate trihydrate and the high thermal conductivity of graphitic foams. We demonstrate a new stable nucleation agent specific to lithium nitrate trihydrate which decreases undercooling by up to ∼70% relative to previously described nucleation agents. Furthermore, we demonstrate the compatibility of lithium nitrate trihydrate and graphitic foam with the addition of a commercial nonionic silicone polyether surfactant. Finally, we show that thermal conductivity across water-graphite interfaces is optimized by tuning the surfactant concentration. These advances demonstrate a promising route to synthesizing high energy density, high thermal conductivity TES composites.

scholarly journals Review of Technologies and Recent Advances in Low-Temperature Sorption Thermal Storage Systems

Energies ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 6052
Author(s):  
Hamza Ayaz ◽  
Veerakumar Chinnasamy ◽  
Junhyeok Yong ◽  
Honghyun Cho
Keyword(s):  
Energy Storage ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Heat Storage ◽  
Storage Systems ◽  
Energy Storage Materials ◽  
Potential Candidate ◽  
Recent Advances ◽  
Sorption Heat ◽  
Absorption Cycle

Sorption thermochemical storage systems can store thermal energy for the long-term with minimum amount of losses. Their flexibility in working with sustainable energy sources further increases their importance vis-à-vis high levels of pollution from carbon-based energy forms. These storage systems can be utilized for cooling and heating purposes or shifting the peak load. This review provides a basic understanding of the technologies and critical factors involved in the performance of thermal energy storage (TES) systems. It is divided into four sections, namely materials for different sorption storage systems, recent advances in the absorption cycle, system configuration, and some prototypes and systems developed for sorption heat storage systems. Energy storage materials play a vital role in the system design, owing to their thermal and chemical properties. Materials for sorption storage systems are discussed in detail, with a new class of absorption materials, namely ionic liquids. It can be a potential candidate for thermal energy storage due to its substantial thermophysical properties which have not been utilized much. Recent developments in the absorption cycle and integration of the same within the storage systems are summarized. In addition, open and closed systems are discussed in the context of recent reactor designs and their critical issues. Finally, the last section summarizes some prototypes developed for sorption heat storage systems.

scholarly journals Development and Characterization of Concrete/PCM/Diatomite Composites for Thermal Energy Storage in CSP/CST Applications

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4410
Author(s):  
Adio Miliozzi ◽  
Franco Dominici ◽  
Mauro Candelori ◽  
Elisabetta Veca ◽  
Raffaele Liberatore ◽  
...  
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Power Plants ◽  
Heat Storage ◽  
Low Cost ◽  
Renewable Energy Sources ◽  
Storage System

Thermal energy storage (TES) systems for concentrated solar power plants are essential for the convenience of renewable energy sources in terms of energy dispatchability, economical aspects and their larger use. TES systems based on the use of concrete have been demonstrated to possess good heat exchange characteristics, wide availability of the heat storage medium and low cost. Therefore, the purpose of this work was the development and characterization of a new concrete-based heat storage material containing a concrete mix capable of operating at medium–high temperatures with improved performance. In this work, a small amount of shape-stabilized phase change material (PCM) was included, thus developing a new material capable of storing energy both as sensible and latent heat. This material was therefore characterized thermally and mechanically and showed increased thermal properties such as stored energy density (up to +7%, with a temperature difference of 100 °C at an average operating temperature of 250 °C) when 5 wt% of PCM was added. By taking advantage of these characteristics, particularly the higher energy density, thermal energy storage systems that are more compact and economically feasible can be built to operate within a temperature range of approximately 150–350 °C with a reduction, compared to a concrete-only based thermal energy storage system, of approximately 7% for the required volume and cost.

scholarly journals Constant-volume vapor-liquid equilibrium for thermal energy storage: Generalized analysis of pure fluids

2020 ◽  
Vol 197 ◽  
pp. 01001
Author(s):  
Abdullah Bamoshmoosh ◽  
Gianluca Valenti
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Storage Capacity ◽  
High Energy ◽  
Constant Volume ◽  
Temperature Range ◽  
Energy Storage Capacity ◽  
Vapor Liquid

Thermal energy storage is of great interest both for the industrial world and for the district heating and cooling sector. Available technologies present drawbacks that reduce the margin of application, such as low energy density, limited temperature range of work, and investment costs. Phase transition is one of the main phenomena that can be exploited for thermal energy storage because of its naturally high energy density. Constant-volume vapor-liquid transition shows higher flexibility and increased heat transfer properties with respect to available technologies. This work presents a description of the behavior of these types of systems. The analysis is carried out through a generalized approach using the Corresponding State Principle. Variation of internal energy as a function of temperature over a fixed range is calculated at constant volume at different values of specific volume. It is shown that, for lower specific volumes, larger temperature ranges of work can be achieved without occurring in the steep pressure increase typically given by the expansion of liquid. Maximum operating temperature range is increased by up to 20% of the critical temperature with minimal energy loss. In optimal subsets of these ranges of temperature, the energy storage capacity of vapor-liquid systems increases at lower volumes, with energy storage capacity increasing to up to 40% with a 50% increase of the reduced volume. This is especially valid for more complex fluids, which are more interesting for these applications because of their higher heat capacity.

scholarly journals Thermal Energy Storage Performance of Tetrabutylammonium Acrylate Hydrate as Phase Change Materials

2021 ◽  
Vol 11 (11) ◽  
pp. 4848
Author(s):  
Hitoshi Kiyokawa ◽  
Hiroki Tokutomi ◽  
Shinichi Ishida ◽  
Hiroaki Nishi ◽  
Ryo Ohmura
Keyword(s):  
Energy Storage ◽  
Heat Exchanger ◽  
Thermal Energy ◽  
Thermal Energy Storage ◽  
Phase Change Materials ◽  
Heat Storage ◽  
Solid Phase ◽  
Agitation Rate ◽  
Mechanical Agitation ◽  
External Forces

Kinetic characteristics of thermal energy storage (TES) using tetrabutylammonium acrylate (TBAAc) hydrate were experimentally evaluated for practical use as PCMs. Mechanical agitation or ultrasonic vibration was added to detach the hydrate adhesion on the heat exchanger, which could be a thermal resistance. The effect of the external forces also was evaluated by changing their rotation rate and frequency. When the agitation rate was 600 rpm, the system achieved TES density of 140 MJ/m3 in 2.9 hours. This value is comparable to the ideal performance of ice TES when its solid phase fraction is 45%. UA/V (U: thermal transfer coefficient, A: surface area of the heat exchange coil, V: volume of the TES medium) is known as an index of the ease of heat transfer in a heat exchanger. UA/V obtained in this study was comparable to that of other common heat exchangers, which means the equivalent performance would be available by setting the similar UA/V. In this study, we succeeded in obtaining practical data for heat storage by TBAAc hydrate. The data obtained in this study will be a great help for the practical application of hydrate heat storage in the future.

scholarly journals Efficient Operation Method of Aquifer Thermal Energy Storage System Using Demand Response

Energies ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3129
Author(s):  
Jewon Oh ◽  
Daisuke Sumiyoshi ◽  
Masatoshi Nishioka ◽  
Hyunbae Kim
Keyword(s):  
Energy Storage ◽  
Power Consumption ◽  
Thermal Energy ◽  
Demand Response ◽  
Thermal Energy Storage ◽  
Heat Storage ◽  
Storage System ◽  
Total Power ◽  
Operation Method ◽  
Total Power Consumption

The mass introduction of renewable energy is essential to reduce carbon dioxide emissions. We examined an operation method that combines the surplus energy of photovoltaic power generation using demand response (DR), which recognizes the balance between power supply and demand, with an aquifer heat storage system. In the case that predicts the occurrence of DR and performs DR storage and heat dissipation operation, the result was an operation that can suppress daytime power consumption without increasing total power consumption. Case 1-2, which performs nighttime heat storage operation for about 6 h, has become an operation that suppresses daytime power consumption by more than 60%. Furthermore, the increase in total power consumption was suppressed by combining DR heat storage operation. The long night heat storage operation did not use up the heat storage amount. Therefore, it is recommended to the heat storage operation at night as much as possible before DR occurs. In the target area of this study, the underground temperature was 19.1 °C, the room temperature during cooling was about 25 °C and groundwater could be used as the heat source. The aquifer thermal energy storage (ATES) system in this study uses three wells, and consists of a well that pumps groundwater, a heat storage well that stores heat and a well that used heat and then returns it. Care must be taken using such an operation method depending on the layer configuration.

scholarly journals Artificial Neural Network Simulation of Energetic Performance for Sorption Thermal Energy Storage Reactors

Energies ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3294
Author(s):  
Carla Delmarre ◽  
Marie-Anne Resmond ◽  
Frédéric Kuznik ◽  
Christian Obrecht ◽  
Bao Chen ◽  
...  
Keyword(s):  
Neural Network ◽  
Artificial Neural Network ◽  
Energy Storage ◽  
Thermal Energy ◽  
Temperature Difference ◽  
Thermal Energy Storage ◽  
Heat Storage ◽  
Experimental Results ◽  
Physical Models ◽  
Artificial Neural

Sorption thermal heat storage is a promising solution to improve the development of renewable energies and to promote a rational use of energy both for industry and households. These systems store thermal energy through physico-chemical sorption/desorption reactions that are also termed hydration/dehydration. Their introduction to the market requires to assess their energy performances, usually analysed by numerical simulation of the overall system. To address this, physical models are commonly developed and used. However, simulation based on such models are time-consuming which does not allow their use for yearly simulations. Artificial neural network (ANN)-based models, which are known for their computational efficiency, may overcome this issue. Therefore, the main objective of this study is to investigate the use of an ANN model to simulate a sorption heat storage system, instead of using a physical model. The neural network is trained using experimental results in order to evaluate this approach on actual systems. By using a recurrent neural network (RNN) and the Deep Learning Toolbox in MATLAB, a good accuracy is reached, and the predicted results are close to the experimental results. The root mean squared error for the prediction of the temperature difference during the thermal energy storage process is less than 3K for both hydration and dehydration, the maximal temperature difference being, respectively, about 90K and 40K.

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