scholarly journals AOT + Polyethylene Glycol Eutectics for Enhanced Oil Recovery

2021 ◽  
Vol 11 (17) ◽  
pp. 8164
Author(s):  
Cristina Gallego ◽  
Alba Somoza ◽  
Héctor Rodríguez ◽  
Ana Soto

Eutectic solvents are currently being proposed as useful chemicals for enhanced oil recovery (EOR). In this work, for the first time, the preparation of eutectics based on surfactants and polymers was proposed for this application. These chemicals can be tailored to offer the most desired properties for oil recovery: water/oil interfacial tension reduction and increase of the aqueous phase viscosity, while concomitantly facilitating their handling due to their liquid character at ambient conditions. Sodium bis(2-ethylhexyl)sulfosuccinate (AOT) and polyethylene glycol (PEG) of three different molecular weights (namely 600, 1000, and 2000 g/mol) were paired in a search for eutectic behaviors. Melting temperatures for all the systems were determined by differential scanning calorimetry. The most promising combination was AOT + PEG-600, which exhibited a melting point of 275 K and thermal stability up to 473 K at a 40:60 molar ratio. A promising value of 5.1 × 10−2 mN/m was obtained for the interfacial tension between the optimized formulation and crude oil. The formulation was tested in core-holder experiments to extract oil from a sandstone rock at room temperature, achieving an encouraging 34% of additional oil recovery after the secondary extraction.

2018 ◽  
Vol 55 (3) ◽  
pp. 252-257 ◽  
Author(s):  
Derong Xu ◽  
Wanli Kang ◽  
Liming Zhang ◽  
Jiatong Jiang ◽  
Zhe Li ◽  
...  

2021 ◽  
Vol 1053 (1) ◽  
pp. 012068
Author(s):  
Teodora Dasilva ◽  
Ronny Windu Sudrajat ◽  
Mega Kasmiyatun ◽  
Slamet Priyanto ◽  
Suherman ◽  
...  

Author(s):  
Rana Obaidat ◽  
Bashar Al-taani ◽  
Hanan Al-quraan

Objective: Meloxicam is classified as class II corresponding to its high permeability and low solubility (12μg/ml). This study aims to compare the effect of selected polymers on stabilization of amorphous form, and dissolution of meloxicam by preparation of different solid dispersions using selected polymers (chitosan oligomers, polyvinylpyrrolidone K30, and polyethylene glycols).Methods: These solid dispersions were prepared using two different methods; solvent evaporation method for the two molecular weights chitosan carriers (16 and 11KDa) and polyvinylpyrrolidone-K30 and melting method for the two different molecular weights polyethylene glycol (4000 and 6000). The physicochemical properties of solid dispersions were analyzed using differential scanning calorimetry, Fourier transform infra-red analysis, Powder X-ray diffraction, and scanning electron microscopy. Selected dispersions were then compared to two selected marketed drugs (Mobic® and Moven®).Results: Best dissolution rates were obtained for both polyvinylpyrrolidone-K30 and polyethylene glycol 6000, followed by chitosan 16 kDa, chitosan 11 kDa, and polyethylene glycol 4000. Increasing polymeric ratio increased dissolution rate except for chitosan. Precipitation of the drug as amorphous form occurred in chitosan and polyvinylpyrrolidone-K30 dispersions, while no change in crystallinity obtained for polyethylene glycol dispersions. Failure of polyvinylpyrrolidone-K30 in the maintenance of stability during storage time was observed while re-crystallization occurred in chitosan-based dispersions, which ends with preferences to polyethylene glycol dispersions. After comparing the release of selected dispersions with the two selected polymers; all dispersions got a higher release than that of the two marketed drugs release.Conclusion: The dissolution profile of meloxicam has been increased successfully in a reproducible manner.


Author(s):  
Ahmed Ragab ◽  
Eman M. Mansour

The enhanced oil recovery phase of oil reservoirs production usually comes after the water/gas injection (secondary recovery) phase. The main objective of EOR application is to mobilize the remaining oil through enhancing the oil displacement and volumetric sweep efficiency. The oil displacement efficiency enhances by reducing the oil viscosity and/or by reducing the interfacial tension, while the volumetric sweep efficiency improves by developing a favorable mobility ratio between the displacing fluid and the remaining oil. It is important to identify remaining oil and the production mechanisms that are necessary to improve oil recovery prior to implementing an EOR phase. Chemical enhanced oil recovery is one of the major EOR methods that reduces the residual oil saturation by lowering water-oil interfacial tension (surfactant/alkaline) and increases the volumetric sweep efficiency by reducing the water-oil mobility ratio (polymer). In this chapter, the basic mechanisms of different chemical methods have been discussed including the interactions of different chemicals with the reservoir rocks and fluids. In addition, an up-to-date status of chemical flooding at the laboratory scale, pilot projects and field applications have been reported.


2021 ◽  
Author(s):  
Rini Setiati ◽  
Muhammad Taufiq Fathaddin ◽  
Aqlyna Fatahanissa

Microemulsion is the main parameter that determines the performance of a surfactant injection system. According to Myers, there are four main mechanisms in the enhanced oil recovery (EOR) surfactant injection process, namely interface tension between oil and surfactant, emulsification, decreased interfacial tension and wettability. In the EOR process, the three-phase regions can be classified as type I, upper-phase emulsion, type II, lower-phase emulsion and type III, middle-phase microemulsion. In the middle-phase emulsion, some of the surfactant grains blend with part of the oil phase so that the interfacial tension in the area is reduced. The decrease in interface tension results in the oil being more mobile to produce. Thus, microemulsion is an important parameter in the enhanced oil recovery process.


2018 ◽  
Vol 124 (2) ◽  
Author(s):  
Hassan Soleimani ◽  
Mirza Khurram Baig ◽  
Noorhana Yahya ◽  
Leila Khodapanah ◽  
Maziyar Sabet ◽  
...  

2020 ◽  
Author(s):  
Nur Asyraf Md Akhir ◽  
Afif Izwan Abd Hamid ◽  
Ismail Mohd Saaid ◽  
Ahmad Kamal Idris ◽  
Nik Nor Azrizam Nik Norizam ◽  
...  

Processes ◽  
2020 ◽  
Vol 8 (9) ◽  
pp. 1073 ◽  
Author(s):  
Goshtasp Cheraghian ◽  
Sara Rostami ◽  
Masoud Afrand

Nanoparticles (NPs) are known as important nanomaterials for a broad range of commercial and research applications owing to their physical characteristics and properties. Currently, the demand for NPs for use in enhanced oil recovery (EOR) is very high. The use of NPs can drastically benefit EOR by changing the wettability of the rock, improving the mobility of the oil drop and decreasing the interfacial tension (IFT) between oil/water. This paper focuses on a review of the application of NPs in the flooding process, the effect of NPs on wettability and the IFT. The study also presents a review of several investigations about the most common NPs, their physical and mechanical properties and benefits in EOR.


2015 ◽  
Vol 9 (9) ◽  
pp. 722-726 ◽  
Author(s):  
S.N. Hosseini ◽  
M.T. Shuker ◽  
Z. Hosseini ◽  
T. Joao Tomocene ◽  
A. Shabib-asl ◽  
...  

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