scholarly journals Trichoderma Biomass as an Alternative for Removal of Congo Red and Malachite Green Industrial Dyes

2021 ◽  
Vol 11 (1) ◽  
pp. 448
Author(s):  
Rosalba Argumedo-Delira ◽  
Mario J. Gómez-Martínez ◽  
Ramiro Uribe-Kaffure
Keyword(s):  
Activated Carbon ◽  
Malachite Green ◽  
Removal Efficiency ◽  
Congo Red ◽  
Fungal Biomass ◽  
Cost Effective ◽  
Fresh Biomass ◽  
Pseudo Second Order ◽  
Cost Effective Alternative ◽  
Adsorption Rates

The present study evaluated the removal efficiency of two dyes, Congo red (CR) and malachite green (MG), using either fresh or dry fungal biomass of two species of Trichoderma (T. virens and T. viride) and activated carbon. After 24 h, the CR removal efficiency obtained with fresh biomass was higher than that obtained with activated carbon. For the MG dye, the average removal with activated carbon (99%) was higher than those obtained with dry and fresh biomass of T. viride and T. virens. Experimental results for fresh and dry fungal biomass showed a good correlation with Langmuir isotherms. The adsorption rates of CR and MG by of T. virens and T. viride can be more appropriately described using the pseudo-second-order rate. We found an adsorption capacity of 81.82 mg g−1 for T. virens with MG dye. Results show that fresh or dry biomass of T. virens can represent a simple and cost-effective alternative for removing industrial dyes such as CR and MG.

scholarly journals A Comparative Study on Dye Degradation by Leaf and Root Extracts of Parthenium hysterophorus L

2018 ◽  
Vol 6 (4) ◽  
pp. 327-331
Author(s):  
Dipesh Shahi ◽  
Rajiv Sapkota
Keyword(s):  
Malachite Green ◽  
Seedling Growth ◽  
Congo Red ◽  
Dye Degradation ◽  
Cost Effective ◽  
Germination Percentage ◽  
Parthenium Hysterophorus ◽  
Treated Wastewater ◽  
Root Extracts ◽  
Phytotoxicity Test

The use of different dyes and pigments is increasing with the increase in industrialization leading to the high production of effluent. The effluent contaminated with dyes and dye-stuff has harmful effects on public health and the environment. Thus, the treatment of effluent is essential. Biological approaches are gaining much interest due to their cost-effective and eco-friendly nature over various physicochemical methods for the treatment of dye-contaminated wastewater. This study highlights on the biodegradation of congo red and malachite green by using leaf and root extracts of Parthenium hysterophorus. The extract and the dye were mixed in the ratio of 1:2 and incubated at 40ºC for 90 minutes. Decolorization assay was performed using UV visible spectrophotometer which indicated that decolorization was due to degradation of dyes into non-colored metabolites. The leaves extract exhibited higher decolorizing activity than roots extract. The maximum decolorization for leaves extract was 55.8% (congo red) and 51.6% (malachite green). Furthermore, phytotoxicity test was carried out to determine the effect of dyes and their degradation metabolites on seed germination and seedling growth of chickpea (Cicer arietinum L). The germination percentage and seedling growth were more in degradation metabolites than untreated dyes, indicating less toxic nature of degradation metabolites. Hence, it can be inferred that P. hysterophorus extracts can be used to treat dye wastewater and treated wastewater can be used for irrigation. Int. J. Appl. Sci. Biotechnol. Vol 6(4): 327-331

scholarly journals Removal of Malachite Green from Aqueous Solution by Activated Carbon Developed from Cocoa (Theobroma Cacao) Shell - A Kinetic and Equilibrium Studies

2011 ◽  
Vol 8 (s1) ◽  
pp. S363-S371 ◽  
Author(s):  
C. Theivarasu ◽  
S. Mylsamy
Keyword(s):  
Experimental Data ◽  
Activated Carbon ◽  
Malachite Green ◽  
Kinetic Models ◽  
Theobroma Cacao ◽  
Second Order ◽  
Order Kinetic ◽  
Equilibrium Studies ◽  
Initial Ph ◽  
Pseudo Second Order

The removal of malachite green (MG) by cocoa (Theobroma cacao) shell activated carbon (CSAC) was investigated in present study. Adsorption studies were performed by batch experiments as a function of process parameters such as initial pH, contact time, initial concentration and adsorbent dose. A comparison of kinetic models applied to the adsorption of MG on CSAC was evaluated for the pseudo-first order and pseudo-second order kinetic models. Results showed that the pseudo-second order kinetic model was found to correlate the experimental data well. The experimental equilibrium adsorption data was represented with Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich and Flory-Huggins isotherms. The experimental data obtained in the present study indicated that activated carbon developed from cocoa shell can be attractive options for dye removal from waste water.

scholarly journals STUDY ON THE ADSORPTION CHARACTERISTICS OF CONGO RED BY SYCAMORE BARK ACTIVATED CARBON

2017 ◽  
Vol 1 ◽  
pp. 64 ◽  
Author(s):  
Li Cong ◽  
Lingling Feng ◽  
Xinlai Wei ◽  
Jie Jin ◽  
Ke Wu
Keyword(s):  
Activated Carbon ◽  
Congo Red ◽  
Room Temperature ◽  
Adsorption Process ◽  
Removal Rate ◽  
Adsorption Properties ◽  
Adsorption Efficiency ◽  
Adsorbent Dosage ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order

The activated carbon was prepared from sycamore bark by activation of zinc chloride. The absorbing effect of activated carbon on Congo red wastewater is studied. The characteristics of sycamore bark activated carbon were characterized by SEM and BET. The effects of adsorbent dosage, time, and shaking speed on the adsorption properties of Congo red by sycamore bark activated carbon were studied. The isotherm, kinetics, and thermodynamics of adsorption were explored. The results revealed that the activated carbon contain a large apparent mesopores. Adsorption efficiency was increased with enhancing the adsorption dosage and time. The removal rate of Conge red reached to 98.2% under room temperature with adsorbent dosage of 3.0 g/L, adsorption time of 120 min, shaking speed of 60r/min. The adsorption of Congo red on sycamore bark activated carbon was followed Langmuir isotherm model and Lagergren pseudo-second order kinetics model. The adsorption was spontaneous, endothermic, and the entropy was increasing in the adsorption process.

Ultrasound and microwave-assisted preparation of Fe-activated carbon as an effective low-cost adsorbent for dyes wastewater treatment

RSC Advances ◽  
2016 ◽  
Vol 6 (82) ◽  
pp. 78936-78946 ◽  
Author(s):  
Song Cheng ◽  
Libo Zhang ◽  
Hongying Xia ◽  
Jinhui Peng ◽  
Jianhua Shu ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Activated Carbon ◽  
Adsorption Capacity ◽  
Removal Efficiency ◽  
Langmuir Isotherm ◽  
Low Cost ◽  
Order Model ◽  
Microwave Assisted ◽  
Pseudo Second Order ◽  
Mb Adsorption

A and B are Langmuir isotherm and pseudo-second-order model. We conclude that MB adsorption capacity of Fe-activated carbon is bigger than raw activated carbon, indicating that Fe-activated carbon has better MB removal efficiency.

scholarly journals Platinum Nanoparticles Loaded on Activated Carbon as Novel Adsorbent for the Removal of Congo Red

2012 ◽  
Vol 9 (1) ◽  
pp. 63-74 ◽  
Author(s):  
M. Ghaedi ◽  
S. J. Hossaini ◽  
S. Ramezani
Keyword(s):  
Free Energy ◽  
Activated Carbon ◽  
Platinum Nanoparticles ◽  
Congo Red ◽  
Adsorption Process ◽  
Second Order ◽  
Particle Diffusion ◽  
Free Energy Of Adsorption ◽  
Pseudo Second Order ◽  
Enthalpy And Entropy

Platinum nanoparticles loaded on activated carbon as novel adsorbent was successfully applied for efficient removal of congo red. The influences of effective parameters including contact time, pH and temperature, amount of adsorbents and concentration of initial dye on the efficiency of removal of congo red from aqueous solution were investigated. Adsorption experiments indicate that the extent of adsorption is strongly dependent on pH of solution. Thermodynamic parameters like Free energy of adsorption, enthalpy and entropy changes were calculated to know the nature of adsorption. The calculated values of free energy of adsorption (negative value) indicate that the adsorption process is spontaneous. The estimated values of enthalpy and entropy both show the positive sign, which indicate that the adsorption process is endothermic and the dye molecules are organized on the adsorbent surface in more randomly fashion than in solution. Fitting experimental data to different kinetic models including first order, pseudo second order and Elovich and intra-particle diffusion models shows that the rate of dye adsorption follows pseudo second order model and involvement of intera- particle diffusion mechanism.

scholarly journals Response surface methodology as a statistical tool for optimization of removal of chromium (VI) from aqueous solution by Teff (Eragrostis teff) husk activated carbon

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Tsegaye Adane ◽  
Daniel Haile ◽  
Awrajaw Dessie ◽  
Yohannes Abebe ◽  
Henok Dagne
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Removal Efficiency ◽  
Carbon Adsorbent ◽  
Statistical Tool ◽  
Chromium Vi ◽  
Environment Exposure ◽  
Column Adsorption ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order

AbstractRecently, rapid industrialization leads to excessive release of heavy metals such as Cr(VI) in the environment. Exposure to chromium (VI) can cause kidney and liver damage, depressed immune systems, and a variety of cancers. Therefore, treatment of Cr(VI) containing wastewater is mandatory. This study aims to optimize the removal of Cr(VI) from aqueous solution using locally available Teff husk activated carbon adsorbent. The laboratory-based study was conducted on the optimization of Cr(VI) removal efficiency of Teff husk activated carbon from aqueous solution. A central composite design was used to examine the effect of the interaction of process parameters and to optimize the process using Design Expert version 7.0 software. The optimized removal efficiency of Teff husk activated carbon (95.597%) was achieved at 1.92 pH, 87.83 mg/L initial concentration, 20.22 g/L adsorbent dose, and 2.07 H contact time. The adsorption of Cr(VI) on Teff husk activated carbon was found to be best fitted with pseudo-second-order kinetics and Langmuir isotherm model of the adsorption. Teff husk activated carbon can be used as an efficient adsorbent for removal of chromium (VI) from contaminated water. Column adsorption needs to be studied in the future.

scholarly journals Adsorption performance and mechanisms of mercaptans removal from gasoline oil using core-shell AC-based adsorbents: Role of intra-particles space

2021 ◽  
Author(s):  
Pamphile Ndagijimana ◽  
Xuejiao Liu ◽  
Zhiwei Li ◽  
Zhenjiao Xing ◽  
Beibei Pan ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Removal Efficiency ◽  
Liquid Fuels ◽  
Core Shell ◽  
High Mechanical Strength ◽  
Adsorption Behaviors ◽  
Pore Texture ◽  
Pseudo Second Order ◽  
Granulated Activated Carbon

Abstract Sulfur compound detection such as mercaptans in liquid fuels is undesirable because sulfur is the main sourcing emission of sulfur oxide (SOx) into the air. The use of activated carbon (AC) has proven to efficiently remove mercaptans. In the meantime, it is limited by the generation of the second pollution in oil, and the difficulties of recovery and regeneration. To address these issues, a core-shell structured AC with high mechanical strength and big intra-particles space were synthesized and demonstrated to efficiently remove organic pollutants from an aqueous solution without generation of the second pollution in our previous work. However, the performance, characteristics, and mechanism of mercaptans adsorption from gasoline oil by core-shell structured AC was still unclear. In this study, the mercaptans adsorption behaviors using core-shell powdered activated carbon (CSAC) and core-shell granulated activated carbon (CSGAC), along with raw PAC, PAC-core, raw GAC, and GAC-core were carried out. The results showed that both the CSAC and CSGAC adsorbents effectively removed sulfur-based pollutants and were provided with good recovery and recyclability without second pollution in gasoline oil. The CSGAC exhibited a higher mercaptans removal efficiency compared to those of CSAC as a result of the bigger intra-particles space. PAC-based adsorbents, presented the shrinking of removal efficiency after regeneration. The Pseudo-second-order kinetics and Langmuir isotherms models were dominated for mercaptans adsorption by both CSAC and CSGAC. Furthermore, the interactions between mercaptans and the composites were probably ascribed to the Van der Waals force, hydrophobic compatibility, pore texture, and π-π dispersion interaction.

Exclusion of Organic Dye Using Neoteric Activated Carbon Prepared from Cornulaca monacantha Stem: Equilibrium and Thermodynamics Studies

2016 ◽  
Vol 875 ◽  
pp. 1-15 ◽  
Author(s):  
Arush Sharma ◽  
Gaurav Sharma ◽  
Amit Kumar ◽  
Zia Mahmood Siddiqi ◽  
Gaurav Sharma
Keyword(s):  
Activated Carbon ◽  
Malachite Green ◽  
Low Cost ◽  
Entropy Change ◽  
Sorption Process ◽  
Second Order ◽  
Adsorption Parameters ◽  
Malachite Green Dye ◽  
Endothermic Process ◽  
Pseudo Second Order

In this study, Cornulacamonacantha stem (CMS) has been used for the preparation of highly competent, ecofriendly and low-cost activated carbon (CMSAC) biosorbent. It was characterized by some instrumental techniques such as Fourier transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM). The biosorbent was evaluated for the eradication of hazardous malachite green (MG) dye from aqueous solution. Batch experiments were conducted to assess the effect of various adsorption parameters such initial dye concentration, sorbent dosage, pH, agitation time and temperature. The results indicated that maximum sorption of MG was occurred at the pH ranged from 10.0 to 12.0. Langmuir, Freundlich and Tempkin isotherms were applied for the interpretation of experimental data and Langmuir model was found to be strongly fitted with higher R2 (0.999). The kinetics studies were examined using pseudo-first-order, pseudo-second-order, Elovich model. The sorption process was described by pseudo-second-order kinetics. The thermodynamic parameters such as energy change (ΔG°), enthalpychange (ΔH°) and entropy change (ΔS°) were found to be-6.21kJ/mol, 46.17 kJ/mol and 172.81 J/mol/K, respectively. The adsorption performance of malachite green dye onto gleaming activated carbon developed from Cornulacamonacantha stem was found to be spontaneous, feasible and endothermic process.

scholarly journals Application of Novel Clay Composite Adsorbent for Fluoride Removal

2019 ◽  
Vol 16 (2) ◽  
pp. 164-173 ◽  
Author(s):  
Lechisa Daba Gidi ◽  
Enyew Zereffa Amare ◽  
H C Ananda Murthy ◽  
Buzuayehu Abebe
Keyword(s):  
Removal Efficiency ◽  
Volume Ratio ◽  
Cost Effective ◽  
Xrd Analysis ◽  
Fluoride Removal ◽  
Clay Material ◽  
Composite Adsorbent ◽  
Pseudo Second Order ◽  
Ft Ir ◽  
Ir Analysis

A novel cost-effective, eco-friendly clay composite adsorbent was developed towards fluoride remediation. Clay, Grog, Bone char, and Sawdust were dry mixed within volume ratios of (5:1:1:1), (4:2:2:1), and (3:3:3:1), respectively. The powders were mixed again with distilled water, pressed with disc shape; sun dried for three days and fired for one hour in the muffle furnace at 400oC, 500oC, and 600oC. The cooled discs were ground and sieved to obtain nine different composite powdered with particle size less than 1.18 mm. The developed composite adsorbent was characterized using advanced techniques: XRD, SEM, and FT-IR. The adsorption studies showed that among the developed adsorbents, composite with the volume ratio of (3:3:3:1) and optimized at firing temperature of 400°C exhibited maximum adsorption capacities of 91.6% fluoride removal efficiency. The XRD analysis revealed mixed phases in the composite, and the presence of OH¯ functional groups was indicated by FT-IR analysis. The experimental results indicated that the Langmuir model was found to fit better for the removal of fluoride ion and followed the pseudo-second-order rate equation. The composite clay material exhibited excellent removal efficiency for the real water samples analyzed.

Sign in / Sign up

Export Citation Format

Share Document