scholarly journals Recent Progress in Hybrid Solar Cells Based on Solution-Processed Organic and Semiconductor Nanocrystal: Perspectives on Device Design

2020 ◽  
Vol 10 (12) ◽  
pp. 4285 ◽  
Author(s):  
Sihang Xie ◽  
Xueqi Li ◽  
Yasi Jiang ◽  
Rourou Yang ◽  
Muyi Fu ◽  
...  

Solution-processed hybrid solar cells have been well developed in the last twenty years due to the advantages of low cost, low material-consuming and simple fabricating technology. However, the performance, stability and film quality of hybrid solar cells need to be further improved for future commercial application (with a lifetime up to 20 years and power conversion efficiency higher than 15%). By combining the merits of organic polymers and nanocrystals (NC), the reasonable design of interface engineering and device architecture, the performance coupled with stability of hybrid solar cells can be significantly improved. This review gives a brief conclusive introduction to the progress on solution-processed organic/inorganic semiconductor hybrid solar cells, including a summary of the development of hybrid solar cells in recent years, the strategy of hybrid solar cells with different structures and the incorporation of new organic hole transport materials with new insight into device processing for high efficiency. This paper also puts forward some suggestions and guidance for the future development of high-performance NC-based photovoltaics.

2019 ◽  
Vol 9 (9) ◽  
pp. 1885 ◽  
Author(s):  
Kaiying Luo ◽  
Wanhua Wu ◽  
Sihang Xie ◽  
Yasi Jiang ◽  
Shengzu Liao ◽  
...  

The use of solution-processed photovoltaics is a low cost, low material-consuming way to harvest abundant solar energy. Organic semiconductors based on perovskite or colloidal quantum dot photovoltaics have been well developed in recent years; however, stability is still an important issue for these photovoltaic devices. By combining solution processing, chemical treatment, and sintering technology, compact and efficient CdTe nanocrystal (NC) solar cells can be fabricated with high stability by optimizing the architecture of devices. Here, we review the progress on solution-processed CdTe NC-based photovoltaics. We focus particularly on NC materials and the design of devices that provide a good p–n junction quality, a graded bandgap for extending the spectrum response, and interface engineering to decrease carrier recombination. We summarize the progress in this field and give some insight into device processing, including element doping, new hole transport material application, and the design of new devices.


2015 ◽  
Vol 3 (38) ◽  
pp. 19353-19359 ◽  
Author(s):  
Wei-Yi Chen ◽  
Lin-Long Deng ◽  
Si-Min Dai ◽  
Xin Wang ◽  
Cheng-Bo Tian ◽  
...  

Low-cost solution-processed copper iodide replaces PEDOT:PSS in inverted planar heterojunction perovskite solar cells with high efficiency and enhanced stability.


2021 ◽  
Vol 12 (11) ◽  
pp. 1692-1699
Author(s):  
Ji Hye Lee ◽  
Jinhyo Hwang ◽  
Chai Won Kim ◽  
Amit Kumar Harit ◽  
Han Young Woo ◽  
...  

New polystyrene-based polymers with high π-extended hole transport pendants were synthesized to obtain a low turn-on voltage and high efficiency in solution-processed green TADF-OLEDs.


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Juanyong Wan ◽  
Yonggao Xia ◽  
Junfeng Fang ◽  
Zhiguo Zhang ◽  
Bingang Xu ◽  
...  

AbstractNonfullerene organic solar cells (OSCs) have achieved breakthrough with pushing the efficiency exceeding 17%. While this shed light on OSC commercialization, high-performance flexible OSCs should be pursued through solution manufacturing. Herein, we report a solution-processed flexible OSC based on a transparent conducting PEDOT:PSS anode doped with trifluoromethanesulfonic acid (CF3SO3H). Through a low-concentration and low-temperature CF3SO3H doping, the conducting polymer anodes exhibited a main sheet resistance of 35 Ω sq−1 (minimum value: 32 Ω sq−1), a raised work function (≈ 5.0 eV), a superior wettability, and a high electrical stability. The high work function minimized the energy level mismatch among the anodes, hole-transporting layers and electron-donors of the active layers, thereby leading to an enhanced carrier extraction. The solution-processed flexible OSCs yielded a record-high efficiency of 16.41% (maximum value: 16.61%). Besides, the flexible OSCs afforded the 1000 cyclic bending tests at the radius of 1.5 mm and the long-time thermal treatments at 85 °C, demonstrating a high flexibility and a good thermal stability.


2018 ◽  
Vol 217 ◽  
pp. 92-95 ◽  
Author(s):  
Qingduan Li ◽  
Jianwei Yang ◽  
Chun Huang ◽  
Shaozhong Zeng ◽  
Jizhao Zou ◽  
...  

ChemSusChem ◽  
2019 ◽  
Vol 12 (16) ◽  
pp. 3808-3816 ◽  
Author(s):  
Ahmed Mourtada Elseman ◽  
Mohamed S. Selim ◽  
Lie Luo ◽  
Cun Yun Xu ◽  
Gang Wang ◽  
...  

2019 ◽  
Vol 7 (36) ◽  
pp. 20494-20518 ◽  
Author(s):  
Bo Li ◽  
Lin Fu ◽  
Shuang Li ◽  
Hui Li ◽  
Lu Pan ◽  
...  

High-efficiency and low-cost perovskite solar cells (PSCs) are desirable candidates for addressing the scalability challenge of renewable solar energy.


2018 ◽  
Vol 8 (7) ◽  
pp. 1195 ◽  
Author(s):  
Yanru Chen ◽  
Xianglin Mei ◽  
Xiaolin Liu ◽  
Bin Wu ◽  
Junfeng Yang ◽  
...  

The CdTe nanocrystal (NC) is an outstanding, low-cost photovoltaic material for highly efficient solution-processed thin-film solar cells. Currently, most CdTe NC thin-film solar cells are based on CdSe, ZnO, or CdS buffer layers. In this study, a wide bandgap and Cd-free ZnSe NC is introduced for the first time as the buffer layer for all solution-processed CdTe/ZnSe NC hetero-junction thin-film solar cells with a configuration of ITO/ZnO/ZnSe/CdTe/MoOx/Au. The dependence of the thickness of the ZnSe NC film, the annealing temperature and the chemical treatment on the performance of NC solar cells are investigated and discussed in detail. We further develop a ligand-exchanging strategy that involves 1,2-ethanedithiol (EDT) during the fabrication of ZnSe NC film. An improved power conversion efficiency (PCE) of 3.58% is obtained, which is increased by 16.6% when compared to a device without the EDT treatment. We believe that using ZnSe NC as the buffer layer holds the potential for developing high-efficiency, low cost, and stable CdTe NC-based solar cells.


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