scholarly journals Evaluation of the Corrosion Resistance of Phosphate Coatings Deposited on the Surface of the Carbon Steel Used for Carabiners Manufacturing

2020 ◽  
Vol 10 (8) ◽  
pp. 2753 ◽  
Author(s):  
Diana-Petronela Burduhos-Nergis ◽  
Petrica Vizureanu ◽  
Andrei Victor Sandu ◽  
Costica Bejinariu
Keyword(s):  
Corrosion Resistance ◽  
Carbon Steel ◽  
Zinc Phosphate ◽  
Sea Water ◽  
Electrochemical Impedance ◽  
Phosphate Solution ◽  
Fire Extinguishing ◽  
Different Types ◽  
Iron Based ◽  
Corrosive Environments

This study aims to evaluate the corrosion resistance of carbon steel, used for carabiners manufacturing, coated with three different types of phosphate layer. The phosphate layers have been obtained by phosphate conversion coating with three different types of phosphate solutions: zinc-based solution, zinc-iron-based phosphate solution, and manganese-based phosphate solution. Additionally, the test was performed on zinc phosphate samples impregnated with molybdenum bisulfate-based oil and zinc phosphate samples further coated with a layer of elastomer-based paint. Considering the areas where the carabiners are used (civil engineering, navigation, oil industry, rescue operations, etc.), the corrosive environments studied are rainwater, Black Sea water, and fire extinguishing solution. The structure of the deposited layers was studied by scanning electron microscopy, while the interface structure between the alloy and corrosive environment was analyzed by electrochemical impedance spectroscopy. According to this study, the corrosion resistance of zinc-based phosphate coated samples and zinc/iron-based phosphate coated samples is higher than that of the studied carbon steel samples, despite the corrosion environment. Also, the most aggressive corrosion environment was the fire extinguishing solution.

scholarly journals Galvanic Corrosion Behaviour of Different Types of Coatings Used in Safety Systems Manufacturing

Coatings ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1542
Author(s):  
Diana-Petronela Burduhos-Nergis ◽  
Dumitru-Doru Burduhos-Nergis ◽  
Costica Bejinariu
Keyword(s):  
Corrosion Resistance ◽  
Carbon Steel ◽  
Corrosion Behaviour ◽  
Galvanic Corrosion ◽  
Worker Safety ◽  
Corrosion Properties ◽  
Corrosive Media ◽  
Fire Extinguishing ◽  
Different Types ◽  
Corrosive Environments

Worker safety is one of the main aspects to be taken into account in any activity carried out at work. When we talk about the safety of the worker at activities carried out at height, the condition and characteristics of the personal protective equipment against falling from a height are one of the main causes of work accidents resulting in serious injuries or death. Carabiners are the main components of the safety system; their role is to connect the other components of the system or to make the connection between the system and the anchor point. Therefore, to be used safely, the carabiners’ material must have high corrosion resistance in different environments. This paper is part of a complex study that aims to improve the corrosion properties of carbon steel used in the manufacture of carabiners. Previous studies have shown that the corrosion resistance of carbon steel in various corrosive environments has been improved by the deposition of different types of phosphate layers, as well as other subsequently deposited layers. The aim of this paper is to study the galvanic corrosion evaluation between different galvanic couples (duralumin-coated samples, aluminium bronze-coated samples, and carbon steel-coated samples) tested in three different corrosive media. Moreover, the study approaches for the first time the galvanic corrosion of systems that can be formed between the materials used in the manufacture of carabiners. Accordingly, it was observed that, overall, the samples coated with a Zn phosphate layer exhibited the best performance in all the corrosive environments (saltwater and fire extinguishing solution).

scholarly journals Phosphate Surface Treatment for Improving the Corrosion Resistance of the C45 Carbon Steel Used in Carabiners Manufacturing

Materials ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3410
Author(s):  
Diana-Petronela Burduhos-Nergis ◽  
Petrica Vizureanu ◽  
Andrei Victor Sandu ◽  
Costica Bejinariu
Keyword(s):  
Corrosion Resistance ◽  
Carbon Steel ◽  
Corrosion Behaviour ◽  
Phosphate Solution ◽  
Fire Extinguishing ◽  
Mechanical Shocks ◽  
Carbon Steel Surface ◽  
Insoluble Phosphate ◽  
The Coefficient Of Friction ◽  
Corrosive Environments

This study approaches the issues which appear during carabiner use and analyses the possibility to eliminate them. Therefore, to improve the corrosion resistance of carbon steel, used in carabiners manufacturing, three different insoluble phosphate layers were deposited on the samples’ surface. The layers were obtained by immersion in zinc-based phosphate solution, zinc/iron-based phosphate solution and manganese-based phosphate solution, Afterwards, to protect against mechanical shocks, a layer of elastomer-based paint was deposited. Furthermore, to reduce rope wear by decreasing the value of the coefficient of friction, the samples were impregnated in molybdenum disulfide-based lubricant. This study aims to analyse the corrosion behaviour of the layers deposited on the carbon steel surface in three of the most common corrosive environments (rainwater, seawater and fire extinguishing solution) by linear and cyclic polarisation. The overall results show that all types of deposited layers increase the corrosion resistance of C45 steel. The experimental results revealed that the samples coated with a phosphate layer obtained by immersion in the zinc-based phosphate solution possess the highest corrosion resistance among the phosphate samples.

scholarly journals Nano-TiO2 Phosphate Conversion Coatings – A Chemical Approach

2018 ◽  
Vol 4 (1) ◽  
pp. 47-54 ◽  
Author(s):  
Nilesh S. Bagal ◽  
Vaibhav S. Kathavate ◽  
Pravin P. Deshpande
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance Spectroscopy ◽  
Carbon Steel ◽  
Impedance Spectroscopy ◽  
Zinc Phosphate ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Low Carbon ◽  
Phosphate Coatings ◽  
Coating Weight

AbstractThe present study aims at deposition of zinc phosphate coatings on low carbon steel with incorporated nano- TiO2 particles by chemical phosphating method. The coated low carbon steel samples were assessed in corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarization techniques (Tafel) in 3.5% NaCl solution. Morphology and chemical composition of the coatings were analyzed by scanning electron microscopy and energy dispersive X-ray spectroscopy in order to observe growth of coating. Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano- TiO2 in the phosphating bath. Corrosion rate of nano-TiO2 chemical phosphate coated samples was found to be 3.5 milli inches per year which was 3 times less than the normal phosphate-coated sample (8 mpy). Electrochemical impedance spectroscopy studies reveal reduction of porosity of nano-TiO2 phosphate coated samples. It was found that nano-TiO2 particles in the phosphating solution yielded uniform phosphate coatings of higher coating weight, fewer defects and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).

scholarly journals Nano Metal Dioxide Incorporated Conversion Phosphate Coatings—A Chemical Approach

2016 ◽  
Author(s):  
Nilesh S. Bagal ◽  
Vaibhav S. Kathavate ◽  
Pravin P. Deshpande
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance Spectroscopy ◽  
Carbon Steel ◽  
Zinc Phosphate ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Low Carbon ◽  
Nano Tio2 ◽  
Phosphate Coatings ◽  
Coating Weight

The present study aims at deposition of zinc phosphate coatings with the incorporation of nano Titanium dioxide particles by chemical phosphating method. Zinc phosphate coatings were developed on low carbon steel by using nano TiO2 in the standard phosphating bath. The Coated low carbon steel samples were assessed for corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarisation techniques in 3.5% NaCl solution. Chemical composition of the coatings was analysed by energy dispersive X-ray spectroscopy (EDX). Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano TiO2 in the phosphating bath. Corrosion rate of nano TiO2 incorporated chemical phosphate coated samples was found to be 3.5 mpy which was 4 times less than the bare uncoated low carbon steel (~14 mpy). Electrochemical impedance spectroscopy studies revels in the reduction of porosity in nano TiO2 phosphate coated samples. It was found that nano TiO2 particles in the phosphating solution yielded phosphate coatings of higher coating weight, greater surface coverage and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).

scholarly journals Nano Metal Dioxide Incorporated Conversion Phosphate Coatings—A Chemical Approach

2016 ◽  
Author(s):  
Nilesh S. Bagal ◽  
Vaibhav S. Kathavate ◽  
Pravin P. Deshpande
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance Spectroscopy ◽  
Carbon Steel ◽  
Zinc Phosphate ◽  
Electrochemical Impedance ◽  
Low Carbon Steel ◽  
Low Carbon ◽  
Nano Tio2 ◽  
Phosphate Coatings ◽  
Coating Weight

The present study aims at deposition of zinc phosphate coatings with the incorporation of nano Titanium dioxide particles by chemical phosphating method. Zinc phosphate coatings were developed on low carbon steel by using nano TiO2 in the standard phosphating bath. The Coated low carbon steel samples were assessed for corrosion studies using electrochemical impedance spectroscopy and potentiodynamic polarisation techniques in 3.5% NaCl solution. Chemical composition of the coatings was analysed by energy dispersive X-ray spectroscopy (EDX). Significant variations in the coating weight, porosity and corrosion resistance were observed with the addition of nano TiO2 in the phosphating bath. Corrosion rate of nano TiO2 incorporated chemical phosphate coated samples was found to be 3.5 mpy which was 4 times less than the bare uncoated low carbon steel (~14 mpy). Electrochemical impedance spectroscopy studies revels in the reduction of porosity in nano TiO2 phosphate coated samples. It was found that nano TiO2 particles in the phosphating solution yielded phosphate coatings of higher coating weight, greater surface coverage and enhanced corrosion resistance than the normal zinc phosphate coatings (developed using normal phosphating bath).

scholarly journals The Galvanic Corrosion Behavior of Phosphated Carbon Steel Used at Carabiners Manufacturing

2019 ◽  
Vol 70 (1) ◽  
pp. 215-219 ◽  
Author(s):  
Diana Petronela Burduhos Nergis ◽  
Carmen Nejneru ◽  
Dumitru Doru Burduhos Nergis ◽  
Cristian Savin ◽  
Andrei Victor Sandu ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Carbon Steel ◽  
Corrosion Behavior ◽  
Sea Water ◽  
Galvanic Corrosion ◽  
Microscopic Analysis ◽  
Steel Corrosion ◽  
Material Surface ◽  
Fire Extinguishing ◽  
Fall Arrest

The carabiners are metallic links used to quickly connect the components of personal fall arrest equipment. Because these systems are used in corrosive environments, the carabiners must possess good corrosion resistance properties. In order to improve these properties, a phosphate layer was chemically deposited by converting on the carabiner material surface. This paper presents the microscopic analysis of the phosphated layer and the galvanic corrosion behavior of phosphated carbon steel, coupled to duralumin and initial carbon steel. Corrosion resistance has been studied for Black Sea water and fire extinguishing solution.

scholarly journals Phosphate Coatings: EIS and SEM Applied to Evaluate the Corrosion Behavior of Steel in Fire Extinguishing Solution

2021 ◽  
Vol 11 (17) ◽  
pp. 7802
Author(s):  
Diana-Petronela Burduhos-Nergis ◽  
Gabriel Dragos Vasilescu ◽  
Dumitru-Doru Burduhos-Nergis ◽  
Ramona Cimpoesu ◽  
Costica Bejinariu
Keyword(s):  
Corrosion Resistance ◽  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Health And Safety ◽  
Industrial Applications ◽  
Metal Corrosion ◽  
Protective Equipment ◽  
Fire Extinguishing ◽  
Phosphate Coatings ◽  
In Fire

Phosphate coatings are one of the most important methods in preventing metal corrosion, especially iron alloys. The high interest in this method for industrial applications is mainly due to the low costs associated with the phosphating solution component and technological process. Considering this aspect and the advantages offered to the materials (corrosion resistance, good adhesion, wear resistance), this study evaluates the potential of using the phosphate coating method in health and safety applications. Therefore, the deposition of a layer of zinc phosphate on the steel surface used in the manufacture of components for personal protective equipment was approached. Firefighters, during rescue/evacuation operations, use protective equipment for fall arrest, whose accessories (hooks, carabiners) are made of steel. Due to the low corrosion resistance property of carbon steel, these accessories must be replaced frequently. This paper aims to analyze the possibility of improving the corrosion resistance of carbon steel in a fire extinguishing solution. Accordingly, the electrochemical behavior of two different types of coatings was studied by electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM). In the literature, different corrosion evaluating methods or systems have been considered, and up until now, there has been no previous study to have approached the corrosive behavior of C45, phosphate C45, and painted phosphate C45 immersed in fire extinguishing solution.

Corrosion Resistance of Nd-Fe-B Magnets Coated with Polypyrrole Films

2006 ◽  
Vol 530-531 ◽  
pp. 111-116
Author(s):  
M.C.E. Bandeira ◽  
F.D. Prochnow ◽  
Isolda Costa ◽  
César V. Franco
Keyword(s):  
Corrosion Resistance ◽  
Electrochemical Impedance ◽  
Nacl Solution ◽  
Corrosion Performance ◽  
Low Frequencies ◽  
Polypyrrole Films ◽  
Phosphate Ions ◽  
Polypyrrole Film ◽  
Corrosive Environments ◽  
Magnet Surface

Nd-Fe-B magnets present outstanding magnetic properties. However, due to their low corrosion resistance, their applications are limited to non-corrosive environments. Nowadays, significant efforts are underway to increase the corrosion resistance of these materials, through the use of coatings. Herein are presented the results of a study on the corrosion resistance of Nd-Fe-B magnets coated with polypyrrole (PPY). The electrochemical behavior of coated and uncoated magnets has been studied by Electrochemical Impedance spectroscopy (EIS) in synthetic saliva. The results were compared to previous investigations, which were carried out under similar conditions, in Na2SO4 and NaCl solutions. In sulphate solution, the corrosion resistance of the PPY-coated magnet was 3 times larger (1600 .cm2) than that of uncoated magnet (500 .cm2). In NaCl solution, however, the corrosion resistance of coated and uncoated magnets were very similar (250 .cm2). In synthetic saliva, both the uncoated and coated magnets presented good corrosion performance (1940 .cm2). Such behavior can be attributed to the phosphate ions in saliva, which play a role as corrosion inhibitor, producing phosphating, at least partially, of the magnet surface. The PPY-coated magnets presented a strong diffusional control from moderate to low frequencies, caused by the polypyrrole film. The thicker PPY film increased the corrosion resistance of the magnet in synthetic saliva.

Effect of Nanoparticle Addition in Hybrid Sol-Gel Silane Coating on Corrosion Resistance of Low Carbon Steel

2013 ◽  
Vol 686 ◽  
pp. 244-249 ◽  
Author(s):  
Poovarasi Balan ◽  
Aaron Ng ◽  
Chee Beng Siang ◽  
R.K. Singh Raman ◽  
Eng Seng Chan
Keyword(s):  
Corrosion Resistance ◽  
Carbon Steel ◽  
Electrochemical Impedance ◽  
Sol Gel ◽  
Low Carbon Steel ◽  
Electrochemical Corrosion ◽  
Alumina Nanoparticles ◽  
Low Carbon ◽  
Silane Coating ◽  
Sol Gel Films

Chromium pre-treatments of metal have been replaced by silane pre-treatments as more environmental friendly option. Nanoparticles can be added in the silane sol-gel network have been reported to improve corrosion resistance. In this work, the electrochemical corrosion resistance of low carbon steel coated with hybrid organic-inorganic sol-gel film filled with nanoparticles was evaluated. The sol-gel films have been synthesized from 3-glycidoxy-propyl-trimethoxy-silane (3-GPTMS) and tetra-ethyl-ortho-silicate (TEOS) precursors. These films have been impregnated with 300 ppm of silica or alumina nanoparticles. The electrochemical behavior of the coated steel was evaluated by means of electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). Equivalent circuit modeling, used for quantifying the EIS measurements showed that sol-gel films containing silica nanoparticles improved the barrier properties of the silane coating. The silica nanoparticle-containing films showed highest initial pore resistance over the five days of immersion in 0.05M NaCl.

Corrosion resistance of composite coating used for fastener protection

2019 ◽  
Vol 66 (5) ◽  
pp. 595-602
Author(s):  
Zhifeng Lin ◽  
Likun Xu ◽  
Xiangbo Li ◽  
Li Wang ◽  
Weimin Guo ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Carbon Steel ◽  
Composite Coating ◽  
Marine Environment ◽  
Electrochemical Impedance ◽  
Salt Spray ◽  
Diffusion Method ◽  
Economic Losses ◽  
Neutral Salt ◽  
Content Type

Purpose The purpose of this paper is to examine the performance of a fastener composite coating system, sherardized (SD) coating/zinc-aluminum (ZA) coating whether it has good performance in marine environment. Design/methodology/approach In this paper, SD coating was fabricated on fastener surface by solid-diffusion method. ZA coating was fabricated by thermal sintering method. Corrosion behaviours of the composite coating were investigated with potentiodynamic polarization curves, open circuit potential and electrochemical impedance spectroscopy methods. Findings Neutral salt spray (NSS) and deep sea exposure tests revealed that the composite coating had excellent corrosion resistance. Polarization curve tests showed that corrosion current density of the sample with composite coating was significantly decreased, indicating an effective corrosion protection of the composite coating. OCP measurement of the sample in NaCl solution demonstrated that the composite coating had the best cathodic protection effect. The good corrosion resistance of the composite coating was obtained by the synergy of SD and ZA coating. Practical implications SD/ZA coating can be used in marine environment to prolong the life of carbon steel fastener. Social implications SD/ZA composite coating can reduce the risk and accident caused by failed fastener, avoid huge economic losses. Originality/value A new kind of composite coating was explored to protect the carbon steel fastener in marine environment. And the composite coating has the long-term anti-corrosion performance both in simulated and marine environment test.

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