scholarly journals The Dependence of Spontaneous Charge Generation in Water on its Flow Rate in a Flow-Based Analytical System

2020 ◽  
Vol 10 (7) ◽  
pp. 2444 ◽  
Author(s):  
Yuri D. Ivanov ◽  
Andrey F. Kozlov ◽  
Rafael A. Galiullin ◽  
Anastasia A. Valueva ◽  
Tatyana O. Pleshakova
Keyword(s):  
Time Dependence ◽  
Charge State ◽  
Water Flow ◽  
Flow Rate ◽  
Charge Accumulation ◽  
Measuring Cell ◽  
Highly Sensitive ◽  
Wide Range ◽  
Analyte Solution ◽  
Detection Of Biomolecules

Highly sensitive biosensor systems are particularly sensitive to the charge state of an analyte. This charge state can have either a positive (for instance, in case of increasing the efficiency of fishing of low-abundant proteins) or negative effect (for instance, in case of the appearance of charge jumps upon the injection of analyte solution into a measuring cell, what can cause undesirable parasitic signals). Previously, it was demonstrated that upon the pumping of analyte solution through polymeric communications of biosensors with a peristaltic pump at a low (~1 mL/min) flow rate, an accumulation of charge, transferred by the liquid drops from the feeding system into the measuring cell, is observed. At this point, the time dependence of charge accumulation has a linear-stepwise form. In the present study, the influence of the flow rate of water on the parameters of the time dependence of the accumulation of charge in such a system—including the influence on the stepwise charge accumulation—has been investigated. The measurements have been performed with a highly sensitive electrometer sensor at 38 °C, which corresponds to a pathological state of a human body. It has been found that a linear-stepwise time dependence of charge accumulation is observed in a wide range of water flow rates (V= 0.9 to 7.2 mL/min). At that point, upon increasing the flow rate with the transition from the drop-by-drop mode of water supply (0.9 mL/min) to the jet flow (7.2 mL/min), an increase in the absolute value of accumulated charge is observed, but the magnitude of the charge jumps does not change significantly. Thus, the amount of charge accumulated in the cell ambiguously depends on the water flow rate—i.e., this dependence can be non-linear. Accounting for the discovered phenomenon is important in the development of new, more accurate models describing physicochemical properties of aqueous solutions and hemodynamics. This effect should also be taken into account in the development of highly sensitive diagnostic systems intended for the detection of single biomarkers of pathologies in humans and crops, as well as in other living systems. In low-concentration systems, the occurrence of a charge can become a significant factor affecting the efficiency of detection of biomolecules and the reliability of the data obtained. The detection of biomolecules present in the solution at low concentrations is in high demand in medical diagnostics for the revelation of biomarkers at the early asymptomatic stage of various diseases, including aggressive forms of cancer.

Analysis of Triangular Microchannel Under Forced Convection Heat Transfer Condition for Laminar Flow Condition

2013 ◽  
Author(s):  
D. A. Kamble ◽  
B. S. Gawali
Keyword(s):  
Heat Transfer ◽  
Laminar Flow ◽  
Water Flow ◽  
Flow Rate ◽  
Heat Input ◽  
Water Flow Rate ◽  
Temperature Drop ◽  
Experimental Result ◽  
Rate Condition ◽  
Wide Range

Micro-convection is a strategic area in transport phenomena, since it is the basis for a wide range of miniaturized high-performance heat transfer applications. Surface area is one of the important parameter for high flux heat transfer in microchannel performance. This experimental study deals with heat transfer using triangular microchannel having hydraulic diameters of 321μm and 289μm. Experimentation is carried out for triangular microchannel set for different heat input and flow rate condition. Triangular microchannel are manufactured with EDM technology. Testing of microchannel under laminar flow is considered with different tip angle, spacing, and length of microchannels. The different microchannels made up of copper material with 29 microchannel each having three different sets of length of 50 mm, 70 mm and 90 mm respectively. Tip angles for triangular microchannel is varied 50 ° and 60 ° with width of 30 mm each respectively are analyzed numerically. Spacing between triangular microchannels is also varied and 300μm and 400μm are considered for the analysis. Water flow rate is considered laminar flow. The flow rate of water is varied from 0.0167 kg/sec to 0.167 kg/sce to carry away heat. It is observed that as hydraulic diameters increase the heat transfer coefficient decreases. As the heat input to microchannel increases from 10 Watt to 100 Watt the temperature drop across varies from 2° C to 22°C as water flow rate increases. The numerical analysis is done using computer C programming. Experimental result differ from theoretical for temperature drop with variation of 2°C to 5°C. It is also observed that in all triangular microchannels its geometry i.e. tip angle and hydraulic diameter are dominant parameters which influences on rate of heat transfer. With increasing channel depth, increases flow passage area therefore enhances heat transfer sufficiently. From experimentation a Nu number correlation is proposed with considering tip angle, length, spacing of microchannel and other related parameters.

Direct electrosynthesis of pure aqueous H2O2 solutions up to 20% by weight using a solid electrolyte

Science ◽  
2019 ◽  
Vol 366 (6462) ◽  
pp. 226-231 ◽  
Author(s):  
Chuan Xia ◽  
Yang Xia ◽  
Peng Zhu ◽  
Lei Fan ◽  
Haotian Wang
Keyword(s):  
Hydrogen Peroxide ◽  
Carbon Black ◽  
Solid Electrolyte ◽  
Oxygen Reduction ◽  
Water Flow ◽  
Flow Rate ◽  
Water Flow Rate ◽  
Porous Solid ◽  
Wide Range ◽  
Current Densities

Hydrogen peroxide (H2O2) synthesis generally requires substantial postreaction purification. Here, we report a direct electrosynthesis strategy that delivers separate hydrogen (H2) and oxygen (O2) streams to an anode and cathode separated by a porous solid electrolyte, wherein the electrochemically generated H+ and HO2– recombine to form pure aqueous H2O2 solutions. By optimizing a functionalized carbon black catalyst for two-electron oxygen reduction, we achieved >90% selectivity for pure H2O2 at current densities up to 200 milliamperes per square centimeter, which represents an H2O2 productivity of 3.4 millimoles per square centimeter per hour (3660 moles per kilogram of catalyst per hour). A wide range of concentrations of pure H2O2 solutions up to 20 weight % could be obtained by tuning the water flow rate through the solid electrolyte, and the catalyst retained activity and selectivity for 100 hours.

scholarly journals WGC Based Robust and Gain Scheduling PI Controller Design for Condensing Boilers

2014 ◽  
Vol 6 ◽  
pp. 659051 ◽  
Author(s):  
Cem Onat
Keyword(s):  
Water Flow ◽  
Flow Rate ◽  
Closed Loop ◽  
Controller Design ◽  
Water Flow Rate ◽  
Pi Controller ◽  
Main Challenge ◽  
Wide Range ◽  
The Stability ◽  
Gain Scheduled

This paper addresses the water temperature PI control in condensing domestic boilers. The main challenge of this process under the controller design perspective is the fact that the dynamics of condensing boilers are strongly affected by the demanded water flow rate. First, a robust PI controller based on weighted geometrical center method is designed that stabilizes and achieves good performance for closed-loop system for a wide range of the water flow rate. Then, it is shown that if the water flow rate information is used to update the controller gains, through a technique known as gain scheduled control, the performance can be significantly improved. Important characteristics of these PI design approaches are that the resulting parameters are calculated numerically without using any graphical method or iterative optimization process and that it guarantees the stability of the closed-loop. Significantly, simulation results have demonstrated that the proposed tuning techniques can perform better for set point changes and load disturbance than other available methods in the literature.

Radon removal by aeration: observations on testing, installation and maintenance of domestic treatment units

2009 ◽  
Vol 9 (4) ◽  
pp. 469-475
Author(s):  
T. Turtiainen
Keyword(s):  
Water Quality ◽  
Water Flow ◽  
Removal Efficiency ◽  
Flow Rate ◽  
Test Protocol ◽  
Household Water ◽  
Medium Flow ◽  
Removal Efficiencies ◽  
Frequent Sampling

Radon is one of the contaminants that sometimes impair the water quality of wells, especially those drilled in bedrock. Domestic radon removal units based on aeration have been commercially available for more than ten years. In order to determine how effectively these units remove radon a new test protocol applying frequent sampling while letting 100 litres of water flow, was developed. This way, removal efficiencies can be more accurately calculated and possible malfunctions detected. Seven models of domestic aerators designed for removing radon from household water were tested. The aerators were based on diffused bubble aeration, spray aeration or jet aeration. The average removal efficiencies for 100 litres with a medium flow rate were 86–100% except for a unit that circulated the aerated water back to the well that had removal efficiency of 80% at the maximum. By conducting a questionnaire study usual problems related to the aeration units were localized and recommendations on maintenance and installation are given accordingly.

scholarly journals Effect of Water Flow on Underwater Wet Welded A36 Steel

Metals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 682
Author(s):  
Eko Surojo ◽  
Aziz Harya Gumilang ◽  
Triyono Triyono ◽  
Aditya Rio Prabowo ◽  
Eko Prasetya Budiana ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Water Flow ◽  
Flow Rate ◽  
Water Flow Rate ◽  
Physical And Mechanical Properties ◽  
Shielded Metal Arc Welding ◽  
Effect Of Water ◽  
Bending Effect ◽  
Metal Arc Welding ◽  
A36 Steel

Underwater wet welding (UWW) combined with the shielded metal arc welding (SMAW) method has proven to be an effective way of permanently joining metals that can be performed in water. This research was conducted to determine the effect of water flow rate on the physical and mechanical properties (tensile, hardness, toughness, and bending effect) of underwater welded bead on A36 steel plate. The control variables used were a welding speed of 4 mm/s, a current of 120 A, electrode E7018 with a diameter of 4 mm, and freshwater. The results show that variations in water flow affected defects, microstructure, and mechanical properties of underwater welds. These defects include spatter, porosity, and undercut, which occur in all underwater welding results. The presence of flow and an increased flow rate causes differences in the microstructure, increased porosity on the weld metal, and undercut on the UWW specimen. An increase in water flow rate causes the acicular ferrite microstructure to appear greater, and the heat-affected zone (HAZ) will form finer grains. The best mechanical properties are achieved by welding with the highest flow rate, with a tensile strength of 534.1 MPa, 3.6% elongation, a Vickers microhardness in the HAZ area of 424 HV, and an impact strength of 1.47 J/mm2.

scholarly journals Geometrical Optimization of a Venturi-Type Microbubble Generator Using CFD Simulation and Experimental Measurements

Designs ◽  
2021 ◽  
Vol 5 (1) ◽  
pp. 4
Author(s):  
Dillon Alexander Wilson ◽  
Kul Pun ◽  
Poo Balan Ganesan ◽  
Faik Hamad
Keyword(s):  
Water Flow ◽  
Flow Rate ◽  
Cfd Simulation ◽  
Air Flow ◽  
Bubble Diameter ◽  
Diameter Ratio ◽  
Experimental Measurements ◽  
Cfd Model ◽  
Flow Rates ◽  
Throat Diameter

Microbubble generators are of considerable importance to a range of scientific fields from use in aquaculture and engineering to medical applications. This is due to the fact the amount of sea life in the water is proportional to the amount of oxygen in it. In this paper, experimental measurements and computational Fluid Dynamics (CFD) simulation are performed for three water flow rates and three with three different air flow rates. The experimental data presented in the paper are used to validate the CFD model. Then, the CFD model is used to study the effect of diverging angle and throat length/throat diameter ratio on the size of the microbubble produced by the Venturi-type microbubble generator. The experimental results showed that increasing water flow rate and reducing the air flow rate produces smaller microbubbles. The prediction from the CFD results indicated that throat length/throat diameter ratio and diffuser divergent angle have a small effect on bubble diameter distribution and average bubble diameter for the range of the throat water velocities used in this study.

Preparation of Functionalized Diorganomagnesium Reagents in Toluene via Bromine or Iodine/Magnesium-Exchange Reactions

Synthesis ◽  
2021 ◽  
Author(s):  
Alexandre Desaintjean ◽  
Fanny Danton ◽  
Paul Knochel
Keyword(s):  
Exchange Reaction ◽  
Nitro Group ◽  
General Formula ◽  
Functional Groups ◽  
Exchange Reactions ◽  
Acyl Chlorides ◽  
Aryl Iodides ◽  
Highly Sensitive ◽  
Wide Range ◽  
Magnesium Exchange

A wide range of polyfunctionalized di(hetero)aryl- and dialkenyl-magnesium reagents were prepared in toluene within 10 to 120 min between −78 °C and 25 °C via an I/Mg- or Br/Mg-exchange reaction using reagents of the general formula R2Mg (R = sBu, Mes). Highly sensitive functional groups, such as a triazene or a nitro group, were tolerated in these exchange reactions, enabling the synthesis of various functionalized (hetero)arenes and alkenes derivatives after quenching with several electrophiles including allyl bromides, acyl chlorides, aldehydes, ketones, and aryl iodides.

scholarly journals 6-Axis Stress Tensor Sensor Using Multifaceted Silicon Piezoresistors

Micromachines ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 279
Author(s):  
Kentaro Noda ◽  
Jian Sun ◽  
Isao Shimoyama
Keyword(s):  
Stress Tensor ◽  
Elastic Body ◽  
Building Materials ◽  
Sensor Response ◽  
Stress Change ◽  
Sensor Chip ◽  
Naked Eye ◽  
Highly Sensitive ◽  
Wide Range

A tensor sensor can be used to measure deformations in an object that are not visible to the naked eye by detecting the stress change inside the object. Such sensors have a wide range of application. For example, a tensor sensor can be used to predict fatigue in building materials by detecting the stress change inside the materials, thereby preventing accidents. In this case, a sensor of small size that can measure all nine components of the tensor is required. In this study, a tensor sensor consisting of highly sensitive piezoresistive beams and a cantilever to measure all of the tensor components was developed using MEMS processes. The designed sensor had dimensions of 2.0 mm by 2.0 mm by 0.3 mm (length by width by thickness). The sensor chip was embedded in a 15 mm3 cubic polydimethylsiloxane (PDMS) (polydimethylsiloxane) elastic body and then calibrated to verify the sensor response to the stress tensor. We demonstrated that 6-axis normal and shear Cauchy stresses with 5 kPa in magnitudes can be measured by using the fabricated sensor.

Experimental Characterization of a Modified Airlift Pump

2014 ◽  
Author(s):  
Afshin Goharzadeh ◽  
Keegan Fernandes
Keyword(s):  
Water Flow ◽  
Flow Rate ◽  
High Speed ◽  
Water Flow Rate ◽  
High Speed Photography ◽  
Two Phase ◽  
Inner Diameter ◽  
Airlift Pump ◽  
Flow Map ◽  
Churn Flow

This paper presents an experimental investigation on a modified airlift pump. Experiments were undertaken as a function of air-water flow rate for two submergence ratios (ε=0.58 and 0.74), and two different riser geometries (i) straight pipe with a constant inner diameter of 19 mm and (ii) enlarged pipe with a sudden expanded diameter of 19 to 32 mm. These transparent vertical pipes, of 1 m length, were submerged in a transparent rectangular tank (0.45×0.45×1.1 m3). The compressed air was injected into the vertical pipe to lift the water from the reservoir. The flow map regime is established for both configurations and compared with previous studies. The two phase air-water flow structure at the expansion region is experimentally characterized. Pipeline geometry is found to have a significant influence on the output water flow rate. Using high speed photography and electrical conductivity probes, new flow regimes, such as “slug to churn” and “annular to churn” flow, are observed and their influence on the output water flow rate and efficiency are discussed. These experimental results provide fundamental insights into the physics of modified airlift pump.

Sign in / Sign up

Export Citation Format

Share Document