scholarly journals Innovative and Conventional Valorizations of Grape Seeds from Winery By-Products as Sustainable Source of Lipophilic Antioxidants

Antioxidants ◽  
2020 ◽  
Vol 9 (7) ◽  
pp. 568
Author(s):  
Ivana Dimić ◽  
Nemanja Teslić ◽  
Predrag Putnik ◽  
Danijela Bursać Kovačević ◽  
Zoran Zeković ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Oil Recovery ◽  
Soxhlet Extraction ◽  
Extraction Methods ◽  
Tocopherol Content ◽  
Industrial Applications ◽  
Operating Conditions ◽  
Vitis Vinifera L ◽  
Grape Seeds ◽  
Extraction Technology

The aim of this study was to valorize the oil recovery from red and white grape seeds (Vitis vinifera L.) that remains as by-product after the winemaking process. Oils were extracted by modern techniques, ultrasound assisted (UAE), microwave assisted (MAE) and supercritical fluid extraction (SFE), and compared to the Soxhlet extraction (SE). Firstly, SFE was optimized at different operating conditions: pressure (250–350 bar), temperature (40–60 °C), CO2 flow rate (0.2, 0.3 and 0.4 kg h−1), and particle size (315–800 µm and >800 µm). The highest extraction yields were achieved by SFE at the optimal conditions: 350 bar, 60 °C, 0.4 kg h−1. Afterwards, SFE was compared to SE, UAE and MAE with respect to oil extraction yields, and analyzed for fatty acid composition and antioxidant capacity. Considering the general classification of fatty acids, it was found that samples had high content of polyunsaturated fatty acids, regardless of extraction technology. Tocopherol content was significantly influenced by all extraction methods, whereas UAE and MAE resulted in extracts richer with lipophilic antioxidants. In conclusion, modern extractions that are suited for industrial applications had better performance as compared to SE, as judging by the oil yield and quality.

scholarly journals Extraction of omega 3 fatty acids from sardine byproducts using supercritical carbon dioxide (SC-CO2)

2020 ◽  
Vol 15 (1) ◽  
Author(s):  
Sahena F. ◽  
Zaidul I.S.M. ◽  
Kamaruzzaman B.Y ◽  
Abir H.M. ◽  
Rukshana A.H.
Keyword(s):  
Carbon Dioxide ◽  
Fatty Acids ◽  
Fatty Acid ◽  
Supercritical Carbon Dioxide ◽  
Fish Oil ◽  
Fatty Acid Content ◽  
Soxhlet Extraction ◽  
Extraction Methods ◽  
Omega 3 ◽  
Supercritical Carbon

Introduction: Sardine generally processed as canned fish, and in consequence of a lot of solid waste are generated as byproducts which could be good sources of fish oil. Omega-3 fatty acid compositions of total lipids extracted by supercritical carbon dioxide (SC-CO2) from sardine fish by-product (head, skin and viscera) were determined and the results were compared with Soxhlet extraction. Methods: SC-CO2 extraction was performed at the optimized condition at a temperature of 60 0 C, the pressure of 35 Mpa and flow rate of 3 ml min-1 . Results: Highest yield was obtained from the skin (42.5%) followed by the head (22.4%) and the viscera (9.6%) which is closer to that of the yield of Soxhlet extraction method where 44%, 23% and 11% (on dry basis) oil were yielded from skin, head and viscera, respectively. Saturated fatty acid was dominant incorporate with monounsaturated and polyunsaturated fatty acid in all organs and the difference of extracted fatty acids between SC-CO2 and Soxhlet methods were insignificant. Docosahexaenoic acid (DHA) was characteristically major PUFA accounting 19.8% in head, 15.4% in skin and 13.6% in viscera of the total fatty acids. Conclusions: Total oil extracted by SC-CO2 had lower free fatty acid content than the oil extracted by Soxhlet method. Thus, SC-CO2 could be the effective method for extracting omega-3 PUFA rich fish oil from sardine by-products.

scholarly journals Characterization of Neocarya Macrophylla Seed Oil using Gas Chromatography-Mass Spectrometry (GC-MS) and Fourier Transform Infra-Red (FT-IR) Techniques

2019 ◽  
pp. 1-7
Author(s):  
Aliyu Ahmad Warra ◽  
Lawal Gusau Hassan ◽  
Leye Jonathan Babatola ◽  
Adedara Adejoju Omodolapo ◽  
Richard Undigweundeye Ukpanukpong ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Gas Chromatography ◽  
Fourier Transform ◽  
Seed Oil ◽  
Saturated Fatty Acids ◽  
Soxhlet Extraction ◽  
Industrial Applications ◽  
Pharmaceutical Products ◽  
Gas Chromatography Mass Spectrometry ◽  
Ft Ir

Aim: Modern researches described incorporating gingerbread plum (Neocarya macrophylla) kernel oils into food, cosmetics and pharmaceutical products by exploiting its physicochemical properties. Study Design: Experimental and instrumental study was done to determine the general and the saturated fatty acids present in the seed oil and its suitability for industrial applications. This study examined the fatty acids by qualitative determination from hexane extracts of Neocarya macrophylla seed using GC-MS. Materials and Methods: Indigenous Neocarya macrophylla   seeds obtained from Gingerbread plum tree were collected in the Month of August from Birnin Kebbi, Kebbi State, Nigeria. soxhlet extraction method was used for the oil extraction. The GC-MS analysis was by coupling system of Shimadzu QP2010 series gas chromatography with Shimadzu QP2010 plus mass spectroscopy detector (GCMS).  For the FT-IR analysis, software of OMNIC operating system (Version 7.0 Thermo Nicolet) was connected to Fourier Transform Infrared Spectrometer Nicolet 8400S equipped with a detector of deuterated triglycine sulphate (DTGS). Conclusion: These results showed the potential of this oil in cosmetic industry.

N-Hexane, Methyl Ethyl Ketone and Chloroform Solvents for Oil Recovery from Refinery Waste

2014 ◽  
Vol 699 ◽  
pp. 666-671
Author(s):  
Reem Ahmed ◽  
Chandra Mohan Sinnathambi ◽  
Usama Eldmerdash
Keyword(s):  
Oil Recovery ◽  
Extraction Method ◽  
Soxhlet Extraction ◽  
Extraction Methods ◽  
Refinery Waste ◽  
Solvent Extraction Method ◽  
Soxhlet Apparatus ◽  
Mixing Method ◽  
Oily Waste ◽  
Land Filling

Considerable amount of oily waste is generated from petroleum refinery in Malaysia. A typical refinery produces about 40 tons of sludge per month. Disposing via land filling (common method) is becoming less accepted and more expensive. As a result, refineries and other facilities have accumulated large volumes of this waste in makeshift landfills or other storage areas. For this reason solvent extraction method has been selected for oil recovery and to minimize the solid waste. Three solvents (chloroform, MEK, and n-hexane) and two extraction methods (sludge–solvent mixing method , and Soxhlet apparatus) were applied to recover the oil from the refinery sludge. Soxhlet extraction method has shown higher efficiency in extraction than sludge-solvent mixing method. Soxhlet extraction method using MEK solvent can recover about 48.3 % of oil, as compared to mixing method which accounts to only about 32.5 % of recovered oil. It has an added recovery of about 7.1 %, 15.8 % and 5.7 % for n-hexane, MEK and chloroform solvents respectively. FTIR results confirmed that MEK has the highest capability to extract hydrocarbon from refinery waste.

Extraction and Quantification of Eugenol from Clove Buds Using HPLC

2020 ◽  
Vol 7 (1) ◽  
pp. 17-23
Author(s):  
Khadiza Fitri Shafira ◽  
Abul Kalam Azad ◽  
Zubair Khalid Labu ◽  
Abul Bashar Mohammed Helal Uddin
Keyword(s):  
Processing Time ◽  
Soxhlet Extraction ◽  
Extraction Methods ◽  
Past Study ◽  
Solvent Ratio ◽  
Clove Oil ◽  
Microwave Assisted ◽  
Assisted Extraction ◽  
Significant Difference ◽  
Clove Essential Oil

Background: Eugenol is the main constituent of clove essential oil. Past studies have found that clove oil has diverse uses in the pharmaceutical field due to its antioxidant, antibacterial and anesthetic properties. Objective: This work compares the performance of different extraction methods and factors and identifies the effect of the treatments on oil yields and eugenol content. Materials and Methods: Maceration, Hydro distillation, microwave-assisted extraction (MAE), and Soxhlet were performed. The best technique was identified according to yield and content. Further studies were conducted to examine the effects of different factors, such as solvent types (ethanol and methanol) and sample-to-solvent ratio (1:10 and 1:15). HPLC UV-Vis was utilized in the analysis of eugenol concentration. Results and Discussion: Soxhlet extraction provided the highest yield (39.98%) and eugenol content (15.83%), compared to other methods. The results observed from several Soxhlet extraction factors showed that there is no significant difference between the different factors. In the meantime, methanol 1:15 provided the greatest amount of yields (57.83%) and eugenol content (22.21%). In this regard, the higher ratio resulted in higher eugenol content. Conclusion: The results obtained are less comparable because the processing time, the working solvent, and the separation technique were carried out differently for each method. In the meantime, as there is no past study that compared the selected methods and factors, this study’s findings will contribute substantially to fill the gap in this field.

Comparison of extraction efficiency of various methods to extract L-DOPA from Mucuna pruriens (L.) DC.

2017 ◽  
Vol 6 (04) ◽  
pp. 5343
Author(s):  
Ragni Vora ◽  
Ambika N. Joshi* ◽  
Nitesh C. Joshi
Keyword(s):  
Extraction Efficiency ◽  
Soxhlet Extraction ◽  
Extraction Methods ◽  
Mucuna Pruriens ◽  
Water Mixture ◽  
Uv Detector ◽  
Pharmacological Activities ◽  
Hplc Mobile Phase ◽  
Plant Sources ◽  
Seed Extracts

Mucuna pruriens seeds are noted to be a natural source of L-DOPA and are also used as a substitute for the synthetic L-DOPA. In the present study; attempts are made to develop suitable method(s) for extraction of L-DOPA from the powdered seeds of Mucuna pruriens using different solvents and conditions. The Seed powder was subjected to 7 different extraction methods and Method 1 was subjected to various solvent concentrations. Some methods used de-fatting procedure, either the method was cold maceration or in high temperature. Soxhlet extraction was also used in one of the extraction methods. All the extracts were analyzed using RP-HPLC. Mobile Phase used was Water: Methanol: AcetoNitrile (100:60:40) (v/v) containing 0.2% Triethylamine, pH = 3.3 and monitored at 280 nm with variable wavelength UV detector. The extraction was best with Methanol Water mixture in a cold maceration technique and overall gives good extraction efficiency of 13.36 % L-DOPA and id the best method giving highest extraction efficiency. The De-fatting method was the 2nd best methods giving approximately 8.8% L-DOPA and Method 5 viz, heat reflux method gives 8.7% L-DOPA making it the 3rd best method. There are not many studies done for optimization of extraction technique for L-DOPA despite an extensive work is reported for isolation, identification and pharmacological activities of L-DOPA from various plant sources. Keeping this in view, present investigation was done to study the extraction efficiency of various extraction methods of L-DOPA content in seed extracts of Mucuna pruriens and compare it.

scholarly journals A Study of Overripe Seed Byproducts from Sun-Dried Grapes by Dispersive Raman Spectroscopy

Foods ◽  
2021 ◽  
Vol 10 (3) ◽  
pp. 483
Author(s):  
Francisco J. Rivero ◽  
Leonardo Ciaccheri ◽  
M. Lourdes González-Miret ◽  
Francisco J. Rodríguez-Pulido ◽  
Andrea A. Mencaglia ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Spectroscopic Data ◽  
Principal Component ◽  
Industrial Applications ◽  
Phenolic Composition ◽  
Grape Seeds ◽  
Detection Scheme ◽  
Sun Drying ◽  
Dried Grapes ◽  
Excitation Laser

Overripe seeds from sun-dried grapes submitted to postharvest dehydration constitute a scarcely investigated class of vinification byproduct with limited reports on their phenolic composition and industrial applications. In this study, Raman spectroscopy was applied to characterize a selection of overripe seed byproducts from different white grapes (cv. Moscatel, cv. Pedro Ximénez and cv. Zalema) submitted to postharvest sun drying. The Raman measurements were taken using a 1064 nm excitation laser in order to mitigate the fluorescent effect and the dispersive detection scheme allowed a compactness of the optical system. Spectroscopic data were processed by a principal component analysis to reduce the dimensionality and partner recognition. The evolution of the Raman spectrum during the overripening process was compared with the phenolic composition of grape seeds, which was determined by rapid resolution liquid chromatography/mass spectrometry (RRLC/MS). A multivariate processing of the spectroscopic data allowed the classification of overripe seeds according to the grape variety and the monitoring of stages of the postharvest sun drying process.

scholarly journals Interaction and Adsorption of Hydrophobically Modified Polyacrylamide on Silica and Asphaltene Surfaces

2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Wenjie Zou ◽  
Zichuan Fang ◽  
Zhijun Zhang ◽  
Zhenzhen Lu
Keyword(s):  
Oil Recovery ◽  
Adhesion Force ◽  
Interaction Mechanism ◽  
Surface Force ◽  
Industrial Applications ◽  
Oil Sand ◽  
Continuous Adsorption ◽  
Hydrophobically Modified Polyacrylamide ◽  
Hydrophobically Modified ◽  
Modified Polyacrylamide

The adsorption of polymers affects the cost and oil recovery in oil reservoir exploitation and the flocculation effect in the treatment of oil sand tailings. The adhesion and adsorption of a hydrophobically modified polyacrylamide (HMPAM), i.e., P(AM-NaAA-C16DMAAC), on silica and asphaltene were investigated using surface force measurements, thermodynamic analysis and quartz crystal microbalance with dissipation (QCM-D) measurement. Our study indicates that HMPAM polymer has strong interaction with both silica and asphaltene. The adhesion force of HMPAM on silica was stronger than that on asphaltene surface. Consistently, the adsorption of HMPAM was also greater on silica surface, with a more rigid layer formed on the surface. For HMPAM/silica system, the attractive interaction and the strong adhesion are mainly driven by the hydrogen bonding and electrostatic interaction. For HMPAM/asphaltene system, it is mainly due to hydrophobic interaction between the long hydrocarbon chains of HMPAM and asphaltene. Furthermore, continuous adsorption of HMPAM was detected and multiple layers formed on both silica and asphaltene surfaces, which can be attributed to the hydrophobic chains of HMPAM polymers. This work has illustrated the interaction mechanism of HMPAM polymer on hydrophilic silica and hydrophobic asphaltene surfaces, which provide insight into the industrial applications of hydrophobically modified polymer.

scholarly journals Effect of Dietary Hazelnut Peels on the Contents of Fatty Acids, Cholesterol, Tocopherols, and on the Shelf-Life of Ripened Ewe Cheese

Antioxidants ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 538
Author(s):  
Vita Maria Marino ◽  
Teresa Rapisarda ◽  
Margherita Caccamo ◽  
Bernardo Valenti ◽  
Alessandro Priolo ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Dry Matter ◽  
Tocopherol Content ◽  
The Other ◽  
Cholesterol Oxidation ◽  
Cholesterol Levels ◽  
Bulk Milk ◽  
Chocolate Industry ◽  
Experimental Group ◽  
Effect Of Feeding

Hazelnut peel (HNP), a by-product from the chocolate industry, is considered to be a suitable ingredient to be included in the diet of ruminants. This study aimed to evaluate the effect of feeding dairy ewes with a diet containing HNP on ripened cheese quality, including fatty acid (FA) profile, cholesterol, and tocopherol content, as well as stability during storage under commercial conditions. In total, 10 experimental cheeses were produced with bulk milk obtained from ewes fed a commercial concentrate (C group; n = 5) or a concentrate containing 36% HNP in dry matter (HNP group; n = 5). After 40 days of aging, each cheese was sub-sampled into three slices: one was analyzed immediately (C0 and HNP0), and the other two were refrigerated and analyzed after seven days (C7 and HNP7) and 14 days (C14 and HNP14), respectively. Compared to C, HNP cheese had more than twice as many tocopherols and mono-unsaturated FA and respectively 38% and 24% less of cholesterol and saturated FA. Tocopherols and cholesterol levels remained rather stable up to 14 days of storage regardless of the experimental group, suggesting no cholesterol oxidation. Therefore, the inclusion of HNP in ewe diets could be a valid resource to produce cheese with a healthier lipid profile and higher tocopherols content.

Identification of Bearing Coefficients of Flexible Rotor-Bearing Systems

2000 ◽  
Author(s):  
Tachung Yang ◽  
Wei-Ching Chaung
Keyword(s):  
Industrial Applications ◽  
Operating Conditions ◽  
Least Square ◽  
Flexible Rotor ◽  
Fem Modeling ◽  
Identification Method ◽  
Reaction Forces ◽  
Manufacturing Assembly ◽  
Stiffness And Damping

The accuracy of stiffness and damping coefficients of bearings is critical for the rotordynamic analysis of rotating machinery. However, the influence of bearings depends on the design, manufacturing, assembly, and operating conditions of the bearings. Uncertainties occur quite often in manufacturing and assembly, which causes the inaccuracy of bearing predictions. An accurate and reliable in-situ identification method for the bearing coefficients is valuable to both analyses and industrial applications. The identification method developed in this research used the receptance matrices of flexible shafts from FEM modeling and the unbalance forces of trial masses to derive the displacements and reaction forces at bearing locations. Eight bearing coefficients are identified through a Total Least Square (TLS) procedure, which can handle noise effectively. A special feature of this method is that it can identify bearing coefficients at a specific operating speed, which make it suitable for the measurement of speed-dependent bearings, like hydrodynamic bearings. Numerical validation of this method is presented. The configurations of unbalance mass arrangements are discussed.

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