scholarly journals Different Supramolecular Coordination Polymers of [N,N'-di(pyrazin-2-yl)-pyridine-2,6-diamine]Ni(II) with Anions and Solvent Molecules as a Result of Hydrogen Bonding

Molecules ◽  
2007 ◽  
Vol 12 (4) ◽  
pp. 821-831 ◽  
Author(s):  
Gene-Hsiang Lee ◽  
Hsin-Ta Wang
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Supramolecular Coordination ◽  
Solvent Molecules

The effect of the coordination orientation of N atoms on polymeric structures: synthesis and characterization of one- and two-dimensional CuII coordination polymers based on 4-amino-3-(pyridin-2-yl)-5-[(pyridin-3-ylmethyl)sulfanyl]-1,2,4-triazole

2019 ◽  
Vol 75 (4) ◽  
pp. 443-450
Author(s):  
Guiying Zhu ◽  
Yang Lu ◽  
Guoxia Jin ◽  
Xuan Ji ◽  
Jianping Ma
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
3D Structure ◽  
Three Dimensional ◽  
Great Influence ◽  
Two Dimensional ◽  
3D Network ◽  
Solvent Molecules ◽  
Bonding Systems ◽  
Polymeric Structures

Three new one- (1D) and two-dimensional (2D) CuII coordination polymers, namely poly[[bis{μ2-4-amino-3-(pyridin-2-yl)-5-[(pyridin-3-ylmethyl)sulfanyl]-1,2,4-triazole}copper(II)] bis(methanesulfonate) tetrahydrate], {[Cu(C13H12N5S)2](CH3SO3)2·4H2O} n (1), catena-poly[[copper(II)-bis{μ2-4-amino-3-(pyridin-2-yl)-5-[(pyridin-4-ylmethyl)sulfanyl]-1,2,4-triazole}] dinitrate methanol disolvate], {[Cu(C13H12N5S)2](NO3)2·2CH3OH} n (2), and catena-poly[[copper(II)-bis{μ2-4-amino-3-(pyridin-2-yl)-5-[(pyridin-4-ylmethyl)sulfanyl]-1,2,4-triazole}] bis(perchlorate) monohydrate], {[Cu(C13H12N5S)2](ClO4)2·H2O} n (3), were obtained from 4-amino-3-(pyridin-2-yl)-5-[(pyridin-3-ylmethyl)sulfanyl]-1,2,4-triazole with pyridin-3-yl terminal groups and from 4-amino-3-(pyridin-2-yl)-5-[(pyridin-4-ylmethyl)sulfanyl]-1,2,4-triazole with pyridin-4-yl terminal groups. Compound 1 displays a 2D net-like structure. The 2D layers are further linked through hydrogen bonds between methanesulfonate anions and amino groups on the framework and guest H2O molecules in the lattice to form a three-dimensional (3D) structure. Compound 2 and 3 exhibit 1D chain structures, in which the complicated hydrogen-bonding interactions play an important role in the formation of the 3D network. These experimental results indicate that the coordination orientation of the heteroatoms on the ligands has a great influence on the polymeric structures. Moreover, the selection of different counter-anions, together with the inclusion of different guest solvent molecules, would also have a great effect on the hydrogen-bonding systems in the crystal structures.

Two novel 3D lanthanide supramolecular coordination polymers constructed from paddle wheel SBUs and hydrogen bonding: synthesis, structures and properties

RSC Advances ◽  
2014 ◽  
Vol 4 (59) ◽  
pp. 30963-30967 ◽  
Author(s):  
Qipeng Li ◽  
Shaowu Du
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Luminescent Property ◽  
Temperature Dependent ◽  
Paddle Wheel ◽  
Structures And Properties ◽  
Supramolecular Coordination

Two novel 3D lanthanide supramolecular coordination polymers with lanthanide paddle wheel SBUs were synthesized through in situ generation of formate anions. Their structure and temperature dependent luminescent property are investigated.

Multiple Processing of Metal-Ion Coordination, Anion-Binding, Hydrogen-Bonding- Self-Assembly and p-p Stacking Subprograms in Silver (I) oordination Polymers

2008 ◽  
Vol 59 (3) ◽  
pp. 260-265 ◽  
Author(s):  
Pascal Blondeau ◽  
Yves-Marie Legrand ◽  
Arie Van Der Lee ◽  
Gihane Nasr ◽  
Mihail Barboiu
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Metal Ion ◽  
Silver Triflate ◽  
Anion Coordination ◽  
Supramolecular Coordination ◽  
Geometrical Information ◽  
Molecular Components ◽  
Multiple Processing

New crystalline coordination-polymers are obtained under conditions in which distinct metal ion coordination, hydrogen-bonding and p-p stacking subprograms are involved in independent binding events of ureidopyridyl ligands 1 and 2 by silver hexafluorophosphate or silver triflate. The geometrical information contained in the structure of the ligands 1 and 2 is fully exploited by the silver ion coordination and urea-self assembly or H-bond anion coordination templating features in an independent way. The resulted linear or angular sequences may serve to use the information stored in molecular components that could be read out by synergistic and sequential non-covalent subprograms. It results in linear or tubular supramolecular coordination polymers constructed in a bottom-up strategy.

scholarly journals Three New Supramolecular Coordination Polymers Based on 1H-pyrazolo[3,4-b]pyridin-3-amine and 1,3-benzenedicarboxylate Derivatives

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 819 ◽  
Author(s):  
Yun Xu ◽  
Qing-Hua Deng ◽  
Fang Ding ◽  
Ran An ◽  
Dong Liu ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Supramolecular Network ◽  
Photoluminescence Properties ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
Sheet Structure ◽  
Supramolecular Coordination ◽  
Solvothermal Conditions

Three new supramolecular coordination polymers, namely [Zn(1,3-BDC)(HL)]n (Polymer 1), [Zn3(1,3,5-BTC)2(HL)2(H2O)2]n (Polymer 2), and [Zn9(5-SO3-1,3-BDC)2(L)8(OH)4]n (Polymer 3), were synthesized under solvothermal conditions, based on 1H-pyrazolo[3,4-b]pyridin-3-amine (HL) along with 1,3-benzenedicarboxylate (1,3-BDC) and its derivatives, such as 1,3,5-benzenetricarboxylate (1,3,5-BTC) and 5-sulfo-1,3-benzenedicarboxylate (5-SO3-1,3-BDC). Polymers 1–3 were characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction (PXRD), and single crystal X-ray diffraction analysis. Polymer 1 exhibited a two-dimensional (2D) 4-connected sql net. The neighboring 2D nets were further linked into a 3D supramolecular network by hydrogen-bonding interactions. Polymer 2 displayed a 3D (4, 4, 4)-connected network, which was further stabilized by R 2 2 (14) and S(9) hydrogen-bonding rings along with π–π interactions. The 2D sheet structure of Polymer 3 was constructed by novel quasi-linear nonanuclear Zn(II) units, which further extended into a 3D supramolecular structure by hydrogen-bonding interactions. The solid-state photoluminescence properties of Polymers 1–3 were also investigated.

Effects of Multiple Binding Sites on Studies of Hydrogen Bonding between Nitroxide Radicals and Solvent Molecules

1993 ◽  
Vol 58 (1) ◽  
pp. 47-52 ◽  
Author(s):  
Imad Al-Bala'a ◽  
Richard D. Bates
Keyword(s):  
Hydrogen Bonding ◽  
Magnetic Resonance ◽  
Binding Site ◽  
Binding Sites ◽  
Hyperfine Coupling Constant ◽  
Hydrogen Donor ◽  
Complex Formation Constants ◽  
Multiple Binding Sites ◽  
Multiple Binding ◽  
Solvent Molecules

The role of more than one binding site on a nitroxide free radical in magnetic resonance determinations of the properties of the complex formed with a hydrogen donor is examined. The expression that relates observed hyperfine couplings in EPR spectra to complex formation constants and concentrations of each species in solution becomes much more complex when multiple binding sites are present, but reduces to a simpler form when binding at the two sites occurs independently and the binding at the non-nitroxide site does not produce significant differences in the hyperfine coupling constant in the complexed radical. Effects on studies of hydrogen bonding between multiple binding site nitroxides and hydrogen donor solvent molecules by other magnetic resonance methods are potentially more extreme.

Carboxylic Acid-Doped SBA-15 Silica as a Host for Metallo-supramolecular Coordination Polymers†

2008 ◽  
Vol 112 (46) ◽  
pp. 14637-14647 ◽  
Author(s):  
D. Akcakayiran ◽  
D. Mauder ◽  
C. Hess ◽  
T. K. Sievers ◽  
D. G. Kurth ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Supramolecular Coordination

Two Coordination Polymers Constructed from Pentanuclear Zinc Clusters with Triazolate and Benzenecarboxylate Ligands: Selective Gas Adsorption

2018 ◽  
Vol 71 (3) ◽  
pp. 111 ◽  
Author(s):  
Wen-Wen Zhang ◽  
Yu-Ling Wang ◽  
Ying Liu ◽  
Qing-Yan Liu
Keyword(s):  
Porous Structure ◽  
Coordination Polymers ◽  
Gas Adsorption ◽  
3D Structure ◽  
Co2 Uptake ◽  
N2 Adsorption ◽  
Carboxylate Oxygen ◽  
Zinc Clusters ◽  
Solvent Molecules ◽  
3D Framework

Reactions of Zn(NO3)2·6H2O with 1,2,4-triazole (Htrz) and 1,3,5-benzenetricarboxylic acid (H3BTC) or 5-sulfoisophthalic acid (5-H3SIP) afforded two coordination polymers, {[Zn5(μ3-OH)2(trz)2(BTC)2(DMF)2]·x(solvent)}n (1) and {[Zn7(trz)8(5-SIP)2(H2O)4]·4(H2O)}n (2). Compound 1 has pentanuclear [Zn5(μ3-OH)2] clusters, which are linked by the triazolate ligands to give a 2D layer. The 2D layer is further bridged by BTC3− ligands to form a 3D framework. The 3D framework of 1 has 1D channels filled by solvent molecules. Desolvated 1 shows a moderate CO2 uptake and high CO2/CH4 and CO2/N2 adsorption selectivities due to its carboxylate oxygen decorated pore environment. Compound 2 contains a rare 3D zinc-triazolate framework constructed from a pentanuclear [Zn5(trz)8] cluster wherein the five zinc atoms are arranged linearly. The 3D zinc-triazolate substructure has 1D open channels filled by 5-SIP3− ligands, which interact with the zinc-triazolate framework through Zn–O bonds, leading to a non-porous 3D structure of 2. Introduction of BTC3− into the zinc-triazolate system gave the porous structure of 1. While a variation of BTC3−, 5-SIP3− was introduced into the zinc-triazolate system yielding a non-porous structure of 2, demonstrating that the secondary ligands play an important role in the formation of the final structures.

scholarly journals Hydrated metal(II) complexes of N-(6-amino-3,4-dihydro-3-methyl-5-nitroso-4-oxopyrimidin-2-yl) derivatives of glycine, glycylglycine, threonine, serine, valine and methionine: a monomeric complex and coordination polymers in one, two and three dimensions linked by hydrogen bonding. Corrigendum

2006 ◽  
Vol 62 (1) ◽  
pp. 165-165
Author(s):  
M. Luz Godino Salido ◽  
Paloma Arranz Mascarós ◽  
Rafaél López Garzón ◽  
M. Dolores Gutiérrez Valero ◽  
John N. Low ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Synchrotron Radiation ◽  
Data Collection ◽  
Coordination Polymers ◽  
Data Reduction ◽  
Three Dimensions ◽  
Compound Viii ◽  
Monomeric Complex ◽  
Cell Refinement ◽  
Derivatives Of

Some of the data collection details for compound (VIII) were incorrectly given in Table 1 of Godino Salido et al. (2004). The data for compound VIII in this paper were collected using synchrotron radiation at the Daresbury SRS station 9.8, λ = 0.6935 Å (Cernik et al., 1997; Clegg, 2000). The data were collected using a Bruker SMART 1K CCD diffractometer using ω rotation with narrow frames. The computer program used in the data collection was SMART (Bruker, 2001) and for cell refinement and data reduction SAINT (Bruker, 2001).

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