Two novel 3D lanthanide supramolecular coordination polymers constructed from paddle wheel SBUs and hydrogen bonding: synthesis, structures and properties

RSC Advances ◽  
2014 ◽  
Vol 4 (59) ◽  
pp. 30963-30967 ◽  
Author(s):  
Qipeng Li ◽  
Shaowu Du
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Luminescent Property ◽  
Temperature Dependent ◽  
Paddle Wheel ◽  
Structures And Properties ◽  
Supramolecular Coordination

Two novel 3D lanthanide supramolecular coordination polymers with lanthanide paddle wheel SBUs were synthesized through in situ generation of formate anions. Their structure and temperature dependent luminescent property are investigated.

Multiple Processing of Metal-Ion Coordination, Anion-Binding, Hydrogen-Bonding- Self-Assembly and p-p Stacking Subprograms in Silver (I) oordination Polymers

2008 ◽  
Vol 59 (3) ◽  
pp. 260-265 ◽  
Author(s):  
Pascal Blondeau ◽  
Yves-Marie Legrand ◽  
Arie Van Der Lee ◽  
Gihane Nasr ◽  
Mihail Barboiu
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Metal Ion ◽  
Silver Triflate ◽  
Anion Coordination ◽  
Supramolecular Coordination ◽  
Geometrical Information ◽  
Molecular Components ◽  
Multiple Processing

New crystalline coordination-polymers are obtained under conditions in which distinct metal ion coordination, hydrogen-bonding and p-p stacking subprograms are involved in independent binding events of ureidopyridyl ligands 1 and 2 by silver hexafluorophosphate or silver triflate. The geometrical information contained in the structure of the ligands 1 and 2 is fully exploited by the silver ion coordination and urea-self assembly or H-bond anion coordination templating features in an independent way. The resulted linear or angular sequences may serve to use the information stored in molecular components that could be read out by synergistic and sequential non-covalent subprograms. It results in linear or tubular supramolecular coordination polymers constructed in a bottom-up strategy.

Zinc maleate and fumarate coordination polymers containing hydrogen-bonding capable organodiimines featuring ligand dependent in situ cis–trans isomerization

2010 ◽  
Vol 363 (1) ◽  
pp. 250-256 ◽  
Author(s):  
Gregory A. Farnum ◽  
David P. Martin ◽  
Laura K. Sposato ◽  
Ronald M. Supkowski ◽  
Robert L. LaDuca
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Trans Isomerization

Self-assembly of [Cu3I2]- or [CuI]n-based (n = 2, 4, and ∞) coordination polymers from unsymmetrical bis(pyridyl) and in situ ligands: syntheses, structures, and properties

CrystEngComm ◽  
2014 ◽  
Vol 16 (3) ◽  
pp. 359-368 ◽  
Author(s):  
Zhu-Yan Zhang ◽  
Zhao-Peng Deng ◽  
Xian-Fa Zhang ◽  
Li-Hua Huo ◽  
Hui Zhao ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
Structures And Properties

scholarly journals Three New Supramolecular Coordination Polymers Based on 1H-pyrazolo[3,4-b]pyridin-3-amine and 1,3-benzenedicarboxylate Derivatives

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 819 ◽  
Author(s):  
Yun Xu ◽  
Qing-Hua Deng ◽  
Fang Ding ◽  
Ran An ◽  
Dong Liu ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Supramolecular Network ◽  
Photoluminescence Properties ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
Sheet Structure ◽  
Supramolecular Coordination ◽  
Solvothermal Conditions

Three new supramolecular coordination polymers, namely [Zn(1,3-BDC)(HL)]n (Polymer 1), [Zn3(1,3,5-BTC)2(HL)2(H2O)2]n (Polymer 2), and [Zn9(5-SO3-1,3-BDC)2(L)8(OH)4]n (Polymer 3), were synthesized under solvothermal conditions, based on 1H-pyrazolo[3,4-b]pyridin-3-amine (HL) along with 1,3-benzenedicarboxylate (1,3-BDC) and its derivatives, such as 1,3,5-benzenetricarboxylate (1,3,5-BTC) and 5-sulfo-1,3-benzenedicarboxylate (5-SO3-1,3-BDC). Polymers 1–3 were characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction (PXRD), and single crystal X-ray diffraction analysis. Polymer 1 exhibited a two-dimensional (2D) 4-connected sql net. The neighboring 2D nets were further linked into a 3D supramolecular network by hydrogen-bonding interactions. Polymer 2 displayed a 3D (4, 4, 4)-connected network, which was further stabilized by R 2 2 (14) and S(9) hydrogen-bonding rings along with π–π interactions. The 2D sheet structure of Polymer 3 was constructed by novel quasi-linear nonanuclear Zn(II) units, which further extended into a 3D supramolecular structure by hydrogen-bonding interactions. The solid-state photoluminescence properties of Polymers 1–3 were also investigated.

Reaction-temperature-dependent supramolecular isomerism of copper(I) coordination polymers with incorporated thiocyanate and in situ generated 5-methyltetrazolate ligands

Polyhedron ◽  
2012 ◽  
Vol 42 (1) ◽  
pp. 265-270 ◽  
Author(s):  
Ali Mahmoudi ◽  
Saeed Dehghanpour ◽  
Camelia Gholamrezazadeh ◽  
Maryam Jahanbakhshyan ◽  
Amir H. Mahmoudkhani ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Reaction Temperature ◽  
Temperature Dependent ◽  
Supramolecular Isomerism

Zinc and cadmium metal-directed coordination polymers: in situ flexible tetrazole ligand synthesis, structures, and properties

CrystEngComm ◽  
2015 ◽  
Vol 17 (30) ◽  
pp. 5814-5831 ◽  
Author(s):  
Ruo Ting Dong ◽  
Zhao Ying Ma ◽  
Li Xin Chen ◽  
Lan Fen Huang ◽  
Qian Hong Li ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Hydrothermal Conditions ◽  
Structures And Properties ◽  
Cadmium Metal ◽  
Ligand Synthesis ◽  
Coordination Frameworks

Seven zinc and cadmium coordination frameworks were obtained through in situ tetrazole synthesis. By varying the hydrothermal conditions the unprecedented generation of tetrazole ligands were achieved.

Syntheses, Structures, and Properties of Honeycomb and Square Grid Coordination Polymers with In Situ Formed 5-(2′-Pyrimidyl)tetrazolate

2010 ◽  
Vol 10 (7) ◽  
pp. 2908-2915 ◽  
Author(s):  
Jian-Yong Zhang ◽  
Ai-Ling Cheng ◽  
Qian Sun ◽  
Qi Yue ◽  
En-Qing Gao
Keyword(s):  
Coordination Polymers ◽  
Square Grid ◽  
Structures And Properties

Three ZnII Coordination Polymers Based on 1,2-Naphthalenedicarboxylate and Different 4,4′-Bipyridyl-like Bridging Co-ligands: Structural Regulation and Properties

2015 ◽  
Vol 68 (1) ◽  
pp. 113
Author(s):  
Min Chen ◽  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Chun-Sen Liu
Keyword(s):  
Hydrogen Bonding ◽  
Thermal Properties ◽  
Coordination Polymers ◽  
Stacking Interactions ◽  
In Situ Reaction ◽  
Aromatic Stacking ◽  
Hydrogen Bonding Interactions ◽  
Structural Regulation

Three new ZnII coordination polymers, namely [Zn(ndc)]n (1), {[Zn(ndc)(bpe)]·1.25H2O}n (2), and {[Zn(ndc)(bpee)]·1.25H2O}n (3), were prepared based on in situ reaction of 1,2-naphthalenedicarboxylic anhydride (ndca) with two different 4,4′-bipyridyl-like bridging co-ligands, bpe and bpee (ndc = 1,2-naphthalenedicarboxylate, bpe = 1,2-bis(4-pyridyl)ethane, and bpee = trans-1,2-bis(4-pyridyl)ethylene). In 1, the ZnII and ndc ligands are directly involved in the polymeric frameworks, forming a 2D (43.63) layered network. Complexes 2 and 3 similarly consist of Zn2(ndc)2 binuclear units that are linked by bpe and bpee ligands, respectively, into a 2D (44.62) sheet. However, further analysis indicates that 2 and 3 feature the similar 2-fold interpenetrating structure linked via hydrogen bonding interactions for 2 and aromatic stacking interactions for 3. In addition, the resultant 2D→3D supramolecular frameworks of 2 and 3 are both constructed via aromatic stacking interactions. Also, the fluorescent and thermal properties of the complexes were investigated.

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