scholarly journals Assessing CeO2 and TiO2 Nanoparticle Concentrations in the Seine River and Its Tributaries Near Paris

2021 ◽  
Vol 8 ◽  
Author(s):  
Karine Phalyvong ◽  
Yann Sivry ◽  
Hélène Pauwels ◽  
Alexandre Gélabert ◽  
Mickaël Tharaud ◽  
...  

Motivation for detecting engineered nanoparticles (ENPs) in the environment comes from a need to understand fate and behavior of these materials in natural matrices. The difficulty lies in the low expected ENP particle number concentration (PNC) and the presence of a large and variable background concentration of natural NPs. We report the PNCs and characteristics of cerium-bearing nanoparticles (Ce-NPs) and titanium-bearing nanoparticles (Ti-NPs) in an aquatic matrix (the Seine River and three of its tributaries) with the use of single particle ICP-MS (spICPMS) and electron microscopy (FEG-SEM). Ce-bearing and Ti-bearing particles were observed in suspended particulate matter collected onto 0.2 μm and 1 kDa filters, using FEG-SEM imaging. At Marnay-sur-Seine, the upstream point, PNCs for Ce-NPs and Ti-NPs were 0.47 ± 0.07 × 106 and 1.35 ± 0.17 × 106 particles as measured by spICPMS. The maximum PNC for both Ce-NPs and Ti-NPs, 1.59 ± 0.10 × 106 particles mL−1 and 5.89 ± 0.10 × 106 particles mL−1, respectively, were found in the Marne River, a major tributary to the Seine. It was shown that downstream of each confluence, an increase in the PNC of the Seine is observed, suggesting a significant contribution of the different tributaries. Mass balance of particles flows and elemental ratios of Ce/La showed that in the Marne and the Oise River, a contribution of natural CeO2 NPs exists. The anthropogenic contribution in TiO2 ENPs for the Marne River was further assessed with Ti/Al, Ti/V, and Ti/Y elemental ratios. Near constant element ratios in the Seine below the Orge River and Paris city suggest neither contribute significantly to Ce or Ti NP concentrations. The study provides further investigation of the strengths and limitations of the application of spICPMS to natural samples and contributes data to the currently highly-limited dataset on natural NP backgrounds in rivers, information that is key to assessing the potential for quantifying the input of ENPs to surface waters. Of the total mass of Ce and Ti, 83 and 90%, respectively, could be detected as particles by spICPMS.

1998 ◽  
Vol 38 (6) ◽  
pp. 327-335
Author(s):  
Yasunori Kozuki ◽  
Yoshihiko Hosoi ◽  
Hitoshi Murakami ◽  
Katuhiro Kawamoto

In order to clarify the origin and behavior of suspended particulate matter (SPM) in a tidal river, variation of SPM in a tidal river was investigated with regard to its size and constituents. SPM was separated into three groups according to size. Change of contents of titanium and organic substances of each group of SPM was examined. SPM which was discharged by run-off was transported with decomposition and sedimentation in a tidal river. Concentration of SPM with a particle size greater than 0.45 μm increased due to resuspension in a tidal river. Origin of SPM with a size of less than 0.45 μm at upstream areas was from natural soil and most of such SPM which had been transported settled near a river mouth. It was determined from examination of the CN ratio and the ratio of the number of attached bacteria to free bacteria that SPM with a size greater than 1.0 μm at upstream areas was decomposing intensively. At the downstream areas, SPM with a size of less than 0.45 μm came from the sea. SPM with particle size greater than 1.0 μm consisted of plankton and substances which were decomposed sufficiently while flowing.


Geosciences ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 8
Author(s):  
Matthias Baeye ◽  
Kaveh Purkiani ◽  
Henko de de Stigter ◽  
Benjamin Gillard ◽  
Michael Fettweis ◽  
...  

The purpose of the study was to measure in situ the background suspended particulate matter concentration (SPMC) in the DISCOL area (SE Pacific) and its increase due to mechanical mobilization of the seabed. The disturbance experiment imitated future manganese nodule exploitations and was designed to measure the sediment plume generated by such activities. In the direct vicinity of the disturbance, landers equipped with acoustic and optical sensors measured the current velocities and the SPMC. The SPMC at the disturbance was easily up to 10 mg/L and thus about 200 times higher than the background concentration. The downstream sediment plume, measured by the lander, had a SPMC of about 1 mg/L. After tide reversal, the sediment plume was recorded a second time. A sediment transport model reproduced the plume dispersion. After rapid settling of the coarser fraction, a plume of hardly settling fine particles remained in suspension (and no deposition–resuspension cycles). The transport was controlled by the tides and by the vertical velocity component that resulted from bathymetrical differences. The plume may continue to disperse up to 100+ days (up to hundreds of km) depending on the particle size and until background concentration is reached.


Stem Cells ◽  
2015 ◽  
Vol 33 (9) ◽  
pp. 2748-2761 ◽  
Author(s):  
Sylwia Bobis-Wozowicz ◽  
Katarzyna Kmiotek ◽  
Malgorzata Sekula ◽  
Sylwia Kedracka-Krok ◽  
Elzbieta Kamycka ◽  
...  

Author(s):  
Françoise Vincent-Hubert ◽  
Karine Heas-Moisan ◽  
Catherine Munschy ◽  
Jacek Tronczynski

2020 ◽  
Vol 88 ◽  
pp. 248-259
Author(s):  
Penghui Li ◽  
Min Su ◽  
Xiaodan Wang ◽  
Xiaoyan Zou ◽  
Xia Sun ◽  
...  

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