scholarly journals Why is Soft (Green) Processing (= Low-Energy Production) of Advanced Nano-Materials Difficult but Necessary for Sustainable Society?

2020 ◽  
Vol 2 (2) ◽  
pp. 9-10
Keyword(s):  
Energy Production ◽  
High Energy ◽  
Inorganic Materials ◽  
Low Energy ◽  
Nano Particles ◽  
Nano Materials ◽  
Functionalized Graphene ◽  
Green Processing ◽  
Ink Jet ◽  
Soft Processing

Modern our society has been developed with various advanced nano-materials. Most of the advanced materials, Metallurgical materials, Semiconductors, Ceramic materials, and Plastics have been used in a wide area of applications like structural, mechanical, chemical, electrical, electronic, optical, photonic, biological, medical, etc. Most of them, except for bio-polymers & bio-minerals, have never been produced via biological systems. Thus they have generally been fabricated artificially and/or industrially by so-called high-technology, where harsh conditions & high energy species like high temperature, high pressure, vacuum, molecule, atom, ion, plasma, etc. have been used for their fabrications, thus consumed a huge amount of resources and energies then exhausted huge amounts of wastes: materials, heats, and entropy. To save this tragedy, we must consider “Cascade use of Heats” and “Low energy Production of advanced nano-materials via water-based processings.” Bio-inspired process, which means that “Learn from Bio-systems then Exceed them”. We have challenged to fabricate those advanced inorganic materials with the desired shape/size/location, etc. directly in low energetic routes using aqueous solutions since 1989 when we found a method to fabricate BaTiO3 film on Ti substrate in a Ba(OH)2 solution by Hydrothermal Electrochemical[HEC] method at low temperatures of 60-200 C. We proposed in 1995 an innovative concept and technology, “Soft Processing” or “Soft Solution Processing,” which aims low energetic (=environmentally friendly) fabrication of shaped, sized, located, and oriented inorganic materials in/from solutions1,2). It can be regarded as green processing or eco-processing. When we have activated/stimulated interfacial reactions locally and/or moved the reaction point dynamically, we can get patterned ceramic films directly in solution without any firing, masking, nor etching—direct Patterning of CdS, PbS, and CaWO4 on papers by Ink-Jet Reaction method. Furthermore, we have succeeded in fabricating BaTiO3 patterns on Ti by a laser beam scanning3) and carbon patterns on Si by plasma using a needle electrode scanning directly in solutions. Successes in TiO2 and CeO2 patterns by Ink-Jet Deposition, where nano-particles are nucleated and grown successively on the surface of the substrate, thus become dense even below 300 oC will be presented. Nano-structured films will also be talked. .A recent novel subject, Soft Processing for various nano-carbons including graphene and functionalized graphene will be introduced. Where we have succeeded to prepare functionalized Graphene Ink via successive processes under ambient temperature and pressure conditions.

scholarly journals Interactions of Single Particle with Organic Matters: A Facile Bottom-Up Approach to Low Dimensional Nanostructures

2020 ◽  
Vol 4 (1) ◽  
pp. 7 ◽  
Author(s):  
Shugo Sakaguchi ◽  
Koshi Kamiya ◽  
Tsuneaki Sakurai ◽  
Shu Seki
Keyword(s):  
Chemical Reactions ◽  
Single Particle ◽  
High Energy ◽  
Inorganic Materials ◽  
High Energy Density ◽  
Particle Accelerators ◽  
Nano Materials ◽  
Physico Chemical ◽  
Nanofabrication Technique ◽  
Low Dimensional

A particle induces a pack of chemical reactions in nanospace: chemical reactions confined into extremely small space provide an ultimate technique for the nanofabrication of organic matter with a variety of functions. Since the discovery of particle accelerators, an extremely high energy density can be deposited, even by a single isolated particle with MeV-ordered kinetic energy. However, this was considered to cause severe damages to organic molecules due to its relatively small bond energies, and lack of ability to control the reactions precisely to form the structures while retaining physico-chemical molecular functionalities. Practically, the severely damaged area along a particle trajectory: a core of a particle track has been simply visualized for the detection/dosimetry of an incident particle to the matters, or been removed to lead nanopores and functionalized by refilling/grafting of fresh organic/inorganic materials. The use of intra-track reactions in the so-called “penumbra” or “halo” area of functional organic materials has been realized and provided us with novel and facile protocols to provide low dimensional nano-materials with perfect size controllability in the 21st century. These protocols are now referred to as single particle nanofabrication technique (SPNT) and/or single particle triggered linear polymerization technique (STLiP), paving the way towards a new approach for nanomaterials with desired functionalities from original molecules. Herein, we report on the extremely wide applicability of SPNT/STLiP protocols for the future development of materials for opto-electronic, catalytic, and biological applications among others.

Low energy vs. high energy depositional settings and related sedimentary bodies in early Senenian rudist bearing carbonate shelves (central-southern Italy)

2001 ◽  
Vol 28 (1) ◽  
pp. 37-40 ◽  
Author(s):  
Gabriele Carannante ◽  
A. Laviano ◽  
D. Ruberti ◽  
Lucia Simone ◽  
G. Sirna ◽  
...  
Keyword(s):  
Southern Italy ◽  
High Energy ◽  
Low Energy ◽  
Depositional Settings

Assessing desalination as a sustainable alternative using a multiple criteria decision support model

2008 ◽  
Vol 3 (3) ◽  
Author(s):  
M. B. Fernandes ◽  
M. C. Almeida ◽  
A. G. Henriques
Keyword(s):  
Decision Support ◽  
Energy Production ◽  
Fossil Fuels ◽  
Cost Benefit Analysis ◽  
Cost Benefit ◽  
High Energy ◽  
Economic Benefits ◽  
Multiple Criteria ◽  
Water Production ◽  
Decision Support Model

Desalination technologies provide an alternative for potable water production, having significant potential for application where fresh water scarcity exists. Potential benefits have to be balanced with other factors, such as high costs, high energy consumption, and significant environmental impacts, for the understanding of real risks and gains of desalination within the context of integrated water resources management. Multiple factors can be considered when analysing the viability of a desalination project but often a limited approach is used. The complexity in the analysis lies in finding the alternatives that obey to multiple objectives (e.g. reduced environmental impact, social acceptance, less cost associated). In this paper, development of a methodology based on multiple criteria decision support system for the evaluation and ranking the potential of desalination technologies is described and applied to a Portuguese case study. Relevant factors to the selection of desalination technologies were identified using SWOT analysis and the MACBETH (Measuring Attractiveness by a Categorical Based Evaluation Technique) approach was applied. Technical alternatives considered include reverse osmosis and multi-effect desalination (MED), together with energy production by fossil fuels or solar energy. Production of water by conventional approaches was also considered. Results, for non-economic benefits, show higher score for MED solar but, in the cost-benefit analysis, conventional methods of water production have higher ranking since costs of renewable energies are not yet competitive. However, even if not preferred in economic terms, desalination is ranked significantly above the conventional approaches for non-economic criteria.

Recent Progress in the Analysis of Captopril Using Electrochemical Methods: A Review

2019 ◽  
Vol 15 (3) ◽  
pp. 198-206 ◽  
Author(s):  
Sarfaraz Ahmed Mahesar ◽  
Saeed Ahmed Lakho ◽  
Syed Tufail Hussain Sherazi ◽  
Hamid Ali Kazi ◽  
Kamran Ahmed Abro ◽  
...  
Keyword(s):  
Enzyme Inhibitor ◽  
Modified Electrodes ◽  
High Sensitivity ◽  
Pharmaceutical Formulations ◽  
Inorganic Materials ◽  
Electrochemical Methods ◽  
Nano Particles ◽  
Moderate Heart Failure ◽  
Analytical Instrumentation

Background: Captopril is the synthetic dipeptide used as an angiotensin converting enzyme inhibitor. Captopril is used to treat hypertension as well as for the treatment of moderate heart failure. Analytical instrumentation and methodology plays an important role in pharmaceutical analysis. Methods: This review presents some important applications of electrochemical modes used for the analysis of captopril. So far captopril has been analyzed by using different bare and modified working electrodes with a variety of modifiers from organic and inorganic materials to various types of nano particles/materials. Results: This paper presents some of the methods which have been published in the last few years i.e. from 2003 to 2016. This review highlights the role of the analytical instrumentation, particularly electrochemical methods in assessing captopril using various working electrodes. Conclusion: A large number of studies on voltammetry noted by means of various bare and modified electrodes. Among all of the published voltammetric methods, DPV, SWV, CV and miscellaneous modes were trendy techniques used to analyze captopril in pharmaceutical formulations as well as biological samples. Electrodes modified with nanomaterials are promising sensing tools as this showed high sensitivity, good accuracy with precision as well as selectivity. In comparison to chromatographic methods, the main advantages of electrochemical methods are its cheaper instrumentation, lower detection limit and minimal or no sample preparation.

Transportation: Fuel Energies

2017 ◽  
Author(s):  
Peter Rez
Keyword(s):  
Energy Density ◽  
Fossil Fuels ◽  
High Energy ◽  
Ease Of Use ◽  
Low Energy ◽  
High Energy Density ◽  
Nuclear Fuels ◽  
Liquid Hydrocarbons ◽  
Transportation Fuel ◽  
Journey Time

Transportation efficiency can be measured in terms of the energy needed to move a person or a tonne of freight over a given distance. For passengers, journey time is important, so an equally useful measure is the product of the energy used and the time taken for the journey. Transportation requires storage of energy. Rechargeable systems such as batteries have very low energy densities as compared to fossil fuels. The highest energy densities come from nuclear fuels, although, because of shielding requirements, these are not practical for most forms of transportation. Liquid hydrocarbons represent a nice compromise between high energy density and ease of use.

scholarly journals Low-Energy Electron Damage to Condensed-Phase DNA and Its Constituents

2021 ◽  
Vol 22 (15) ◽  
pp. 7879
Author(s):  
Yingxia Gao ◽  
Yi Zheng ◽  
Léon Sanche
Keyword(s):  
Condensed Phase ◽  
Genetic Material ◽  
High Energy ◽  
Dna Lesions ◽  
Low Energy ◽  
Experimental Investigations ◽  
Experimental Conditions ◽  
Strand Breaks ◽  
Sequence Of Events ◽  
Wide Range

The complex physical and chemical reactions between the large number of low-energy (0–30 eV) electrons (LEEs) released by high energy radiation interacting with genetic material can lead to the formation of various DNA lesions such as crosslinks, single strand breaks, base modifications, and cleavage, as well as double strand breaks and other cluster damages. When crosslinks and cluster damages cannot be repaired by the cell, they can cause genetic loss of information, mutations, apoptosis, and promote genomic instability. Through the efforts of many research groups in the past two decades, the study of the interaction between LEEs and DNA under different experimental conditions has unveiled some of the main mechanisms responsible for these damages. In the present review, we focus on experimental investigations in the condensed phase that range from fundamental DNA constituents to oligonucleotides, synthetic duplex DNA, and bacterial (i.e., plasmid) DNA. These targets were irradiated either with LEEs from a monoenergetic-electron or photoelectron source, as sub-monolayer, monolayer, or multilayer films and within clusters or water solutions. Each type of experiment is briefly described, and the observed DNA damages are reported, along with the proposed mechanisms. Defining the role of LEEs within the sequence of events leading to radiobiological lesions contributes to our understanding of the action of radiation on living organisms, over a wide range of initial radiation energies. Applications of the interaction of LEEs with DNA to radiotherapy are briefly summarized.

Fabrication of the narrow size nano curcuminoids emulsion by combining phase inversion temperature and ultrasonication: preparation and bioactivity

2021 ◽  
Author(s):  
Quang Hieu Tran ◽  
Thuy Thanh Ho ◽  
Tu Thanh Nguyen
Keyword(s):  
Energy Method ◽  
Phase Inversion ◽  
Curcuma Longa ◽  
High Energy ◽  
Low Energy ◽  
Inversion Temperature ◽  
Comprehensive Study ◽  
Phase Inversion Temperature

A comprehensive study from Curcuma longa to powder nano curcuminoids has been carried out. Combining of both low energy method (Phase Inversion Temperature) and high-energy method (Ultrasonication), a series of...

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