Distribution of metallic trace elements (ETM) in surface soils around the Mediouna discharge (southern of Casablanca)

2019 ◽  
Author(s):  
Chem Int

The objective of present research was to characterize the surface soils located at 300, 600 and 1000 m of an uncontrolled landfill. The work also aims to evaluate the levels and spatial distribution of metallic trace elements (Cd, Pb, Cu, Ni, Zn, Cr, Co and As) in these soils. Soil samples were collected in 36 points around the landfill. Results showed that Cd, Pb, Zn are concentrated in the soils rich in clay and carbonates, and in organic matter, located at 300 m from the landfill. The basic pH of all soils enhances the retention of these metals. On the other hand, As present in soils at 300, 600 and 1000 m at concentrations slightly higher than those of referenced soils were apparently mobilized by water from the solid/water interfaces. The other metals Cu, Ni, Co, Cr are present at very low concentrations.

2020 ◽  
Author(s):  
Jelena Popović-Djordjević ◽  
Zoran Broćić ◽  
Mirjana Kresović ◽  
Jelena Mutić

<p>Potato is currently the third most significant crop culture in the world, with the production of over 388 million tons in 2016. This crop is present on the tables of Serbian consumers throughout the year because of the tradition and its affordable price. Serbia has relatively good climatic conditions for potato production, which are defined by the temperature regime and the amount and frequency of precipitation. The nutritive value of the potato is mainly attributed to the chemical composition of the tuber. The element composition of tubers depends on many factors, such as: genotype, developmental phase of the plant, agroecological conditions, chemical properties of soil, fertilization and irrigation. On the other hand, geochemical origin of trace elements in the soil, the intensive agriculture production, use of contaminated soil and irrigation water may increase their toxic levels in tubers.</p><p> Potato tubers of five varieties were produced on commercial farms at two locations in Western Serbia (Guča and Sjenica), with favorable agroecological conditions for potato production. Tuber samples of studied varieties from each location were collected at the end of growing seasons at the stage of physiological maturity. Soil samples were collected from several sites at each production location at the depth of 0–30 cm. Basic agrochemical properties of the soil samples were determined. Content of toxic (As, Cd, Pb) and potentially toxic (Al, Ba, Ni, V) elements in fresh tubers (peel and core) and soil samples was established by inductively coupled plasma–optical emission spectrometry (ICP–OES). Bioaccumulation factor (BAF) of each studied element, as the ratio between its content in the peel and in the core of the tuber and the soil, was calculated.</p><p> According to pH values, 4.77 and 6.80, soils were clasified as very acidic (Guča location) and slightly acidic (Sjenica location), respectively. Content of studied trace elements in soils, with the exception of Ni, was within the allowable limits. Tuber peel of all studied varieties grown on both soil types was characterized with the higher content of Cd, Al, Ba and Ni, compared to the relevant core. Consenquently, the higher values of BAF were observed in the peel of tubers. Average values of BAF for the studied elements in the peel for both soil pH values 4.77 and 6.80 (Guča and Sjenica, respectively) were in the following order: Cd>Ba>Pb>As>Ni>Al=V. On the other hand, average BAF values for the core of the tuber samples were in a slightly different order, depending on the soil pH; Cd>Pb>As>Ba>Ni>Al=V (pH 4.77) and Cd>Pb>As>Ba=Ni>V (pH 6.80). The highest/lowest BAFs were calculated for Cd (0.339) in the peel and Al (0.0002) in the core, respectively. Content of As and Cd did not exeed the maximum allowed concentrations set by the national and European Union regulations, but it should be pointed out that Cd content was close to the upper limit. Also, it was noticed that the content of Pb exceeded the safe limit set for these elements according to both regulations.</p><p>Keywords: potato tuber, soil, toxic elements, ICP</p><p>Acknowledgement: This work was supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia (Research grant No. 46009).</p>


2018 ◽  
Vol 74 (2) ◽  
pp. 6074-2018
Author(s):  
WALDEMAR PASZKIEWICZ ◽  
KRZYSZTOF SZKUCIK ◽  
MONIKA ZIOMEK ◽  
MICHAŁ GONDEK ◽  
RENATA PYZ-ŁUKASIK

The objective of the research was to determine the occurrence of microorganisms of the Salmonella spp. and Listeria spp. in raw and frozen (cooked) snail meat obtained from both free-living and farmed edible snails. The research material comprised meat samples collected from three snail species (25g from each), that is, Roman snail (Helix pomatia – HP), small brown garden snail (Cornu aspersum aspersum – CAA) and large brown garden snail (Cornu aspersum maxima – CAM). Roman snails came from their natural environment and were harvested in Wielkopolska Voivodeship and Lower Silesia Voivodeship (regions A and B, respectively). The Cornu genus snails were obtained from two heliciculture farms located in the abovementioned voivodeships (farms A and B, respectively). On both farms, the snails were maintained under the mixed rearing system. The raw meat samples taken from the edible portion of snails, that is, the foot with collar and a fragment of the mantle, were obtained after the snails were sacrificed in the laboratory. The frozen meat samples, on the other hand, came from a snail meat processing facility. A total of 300 samples were examined for the presence of Salmonella spp., and 240 for the presence of Listeria spp. The research also included pooled soil samples of 0.5 kg each collected from polytunnels (in the pre-fattening stage) and outdoor farming plots (in the fattening stage). The tests for the Salmonella presence were performed in accordance with Polish standard PN-EN ISO 6579:2003, and the test for Listeria complied with PN-EN ISO 11290-1:1999. Listeria monocytogenes was identified by the PCR technique. Salmonella spp. were not detected in any of the 300 samples of raw and cooked snail meat under study. Nor were these pathogens isolated from the soil samples. The absence of these bacteria in the raw meat samples indicates that Salmonella spp. did not occur in either the natural habitat of Roman snails or the two farms producing Cornu genus snails. On the other hand, bacteria of Listeria spp. were detected in 101 (42.1%) snail meat samples. A particularly high load of microbiota was found in raw meat, as these bacteria contaminated from 60% (for HP from region A and CAM from farm B) up to 75% (for CAA from farm A) of samples. Notably, a markedly lower percentage (35%) of samples containing Listeria spp. was found only among the Roman snail raw meat samples from the region B. Listeria spp. were also detected in all the soil samples. Thermal treatment of meat achieved a substantial reduction in the load of Listeria spp., but did not eliminate it. The frequency of this genus in frozen meat samples was from 63.5% (for CAM from farm A) to 15.4% (for CAA from farm B) of that in raw meat. The PCR technique was used identify 15 selected strains, including 11 from raw meat samples and 4 from cooked meat. A total of 5 isolates were recognized as Listeria monocytogenes (2.1% of all samples examined and 4.95% of samples with Listeria spp.). All of them originated from the raw meat of farmed snails, including one (CAA) from the farm A and four (3 CAA and 1 CAM) from the farm B. Bacteria of the Salmonella and Listeria genera occur in the natural habitat of edible snails, which poses a potential hazard to human health. Effective implementation of control programmes at the primary production stage is the first step that could considerably limit the presence of these pathogens in farmed snails and, consequently, in snail meat. .


1964 ◽  
Vol 36 (1) ◽  
pp. 120-134
Author(s):  
Anna-Marja Halkilahti

In the petri dish trials the mycelia of Sclerotinia trifoliorum in sterilized soil samples generally infected clover quite readily. In unsterilized samples the infection was less severe and showed marked variations in different years and at different times of the year. In the outdoor trials clover became less infected in the middle of the summer than in the spring and autumn. On the other hand, in the thermostat trials, where the temperature was constantly 7—10°C, the temperature at the time of taking the soil samples did not have a pronounced effect on the extent of clover infection. Liming of the soil caused a marked decrease in the severity of clover rot infection. In some autumns clover plants growing in soil samples taken from fallow were more seriously infected than those growing in soil from a clover field. As a rule, however, there were only slight variations in the extent of infection in the soil samples taken at the same time from the various areas of the field cultivated in different ways. In general, the highest numbers of microorganisms in the soil were found in the autumn and the lowest in the spring. In clover fields there were often more microorganisms – particularly in the autumn – than in fallow. Liming caused an increase in the numbers of soil microbes. S. trifoliorum infected clover very severely at temperatures of 0—5°C; in the range 5—21°C the infection grew generally milder the more the temperature was found to be rising. At temperatures of 5– 10°C an increase in the numbers of soil microbes resulted in a decrease in the infection of the clover. Still higher temperatures, which did not increase the numbers of soil microorganisms, nevertheless enhanced the antagonistic power of the soil.


2020 ◽  
Vol 23 (3) ◽  
pp. 117-124
Author(s):  
Dušan Šrank ◽  
Vladimír Šimanský

The effort to achieve the sustainable farming system in arable soil led to the intensive search for a new solution but an inspiration can also be found in the application of traditional methods of soil fertility improvement as it is shown in numerous examples in history. Recently many scientific teams have focused their attention on the evaluation of biochar effects on soil properties and crop yields. Since there are a lot of knowledge gaps, especially in explanations how biochar can affect soil organic matter (SOM) and humus substances, we aimed this study at the solution of these questions. Therefore, the objective of the experiment was to evaluate the impact of two biochar substrates (B1 – biochar blended with sheep manure, and B2 – biochar blended with sheep manure and the residue from the biogas station) at two rates (10 and 20 t ha-1) applied alone or in combination with mineral fertilizers (Urea was applied in 2018, at rate 100 kg ha-1, and Urea at rate 100 kg ha-1 + AMOFOS NP 12-52 at 100 kg ha-1 were applied in 2019) on the quantity and quality of SOM and humus of sandy soil (Arenosol, Dolná Streda, Slovakia). The results showed that application of the biochar substrates together with mineral fertilizers (MF) had more pronounced effect on the organic matter mineralization in the sandy soil which resulted in low accumulation of soil organic carbon (Corg) and labile carbon compared to biochar substrates treatments without MF. The share of humic substances in Corg significantly decreased by 16, 50, 16 and 24% in B1 at 10 t ha-1, B1 at 20 t ha-1, B2 at 10 t ha-1 and B2 at 20 t ha-1 treatments, respectively, compared to the control. A similar tendency was observed for biochar substrates treatments + MF, compared to MF control. The carbon content of humic substances (CHS) was equal to 4.40 – 5.80 g kg-1 and the biochar substrates had statistically significant influence on CHS content. On average, there was a smaller decrease of CHS in B1 at rate 10 t ha-1 than at rate 20 t ha-1 and no effect of B2 compared to control. The carbon content of fulvic acid (CFA) was 9% higher in B1 at 10 t ha-1, and 20 t ha-1, 47% higher in B2 at 10 t ha-1 and 17% higher in B2 at 20 t ha-1 compared to control. As a result of biochar substrates + MF application, the reduction in CFA was observed. The results showed a decrease of CHA : CFA ratio with association to biochar substrates alone application compared to control on one hand, and a wider of CHA : CFA ratio in biochar substrates + MF treatments in comparison to MF control on the other hand. Humus stability was increased in biochar substrates alone treatments compared to control, on the other hand, compared to MF control, the application of biochar substrates + MF resulted in a lower humus stability.


2015 ◽  
Vol 34 (3) ◽  
pp. 226-234 ◽  
Author(s):  
Vladimír Šimanský

Abstract The effect of different fire severity on the changes of the soil organic matter (SOM) and soil structure was evaluated. Soil samples were collected (May 2010) in the locality of Nitra-Dražovce (Slovakia) from the following plots: 1) control (unburned place), 2) low severity of fire and 3) higher severity of fire. The results showed that the content of water-stable microaggregates (WSAmi) increased by 20% in the area with a low severity of fire, but on the other hand, it decreased by 42% in the area with the higher severity of fire in comparison to control. The higher severity of fire resulted in a decrease of smaller size fractions of water-stable macroaggregates (WSAma) (0.5−0.25) and a low severity of fire resulted in the decrease of WSAma 2−0.5 mm. On the other hand, the content of WSAma in the size fraction >5 mm was higher by 54% and by 32% in the lower and higher severity of fire, respectively, than in unburned soil. The higher severity of fire had a more positive effect on increases of the structure coefficient and coefficient of aggregate stability, as well as on the decrease of the vulnerability coefficient compared to the low severity of fire. After burning, the contents of soil organic carbon (Corg) and labile carbon were significantly increased by the severity of fire. However, the low severity of fire affected more markedly the increase of hot water-soluble and cold water-soluble carbon than the higher severity of fire. After burning and due to the severity of fire, both the carbon of humic and carbon of fulvic acids ratios and SOM stability increased. The parameters of SOM due to fire significantly increased also in WSA with the least changes in WSAmi. The results showed that a low severity of fire increased Corg mainly in WSAma >2mm and WSAmi, whereas high severity fire increased Corg content in the smaller fraction of WSAma.


1965 ◽  
Vol 11 (2) ◽  
pp. 213-219 ◽  
Author(s):  
Richard S. Berk

A survey of 75 cultures of Pseudomonas aeruginosa containing only one discernible phenotype indicated that 68 routinely exhibited spontaneous lysis, resulting in the appearance of turbid erosions or autoplaques (AP+) when grown on a tryptone–glucose agar medium. Single supplements of non-inhibitory levels of chloromycetin, aureomycin, tetracycline, declomycin, and streptomycin increased the degree of lysis of AP+ strains, but were without effect on AP− strains. Enhancement of lysis was also obtained with sulfadiazine, sulfathiazole, sulfamethoxypyridazine, elkosin, gantrisin, and triple sulfa, while little or no effect was observed with sulfamerizine and thiosulfil. On the other hand, low concentrations of either acriflavine or proflavine retarded the rate and degree of lysis, while single supplements of the active antibiotics overcame the suppressive effects of the dyes.


1914 ◽  
Vol 34 ◽  
pp. 190-201 ◽  
Author(s):  
John B. Robertson

Investigations into the nature of the organic matter in oil-shales began at the time of the famous Torbanehill case in 1854, when experts attempted to settle the question as to whether the substance known as “ Torbanite ” or “ Boghead Mineral” was a coal or an oil-shale. Several witnesses at the trial (Gillespie v. Russel, Session Papers, 1854) maintained that the oilproducing material in the Mineral was of organic origin, while others pronounced it to be bituminous and produced by subaqueous eruptions. T. S. Traill, M.D., proposed for the Boghead Mineral the name “ Bitumenite,” as it seemed to him to “ consist of much bitumen, mingled with earthy matter” (Trans. Roy. 8oc. Edin., 1857, xxi. p. 7). Dr Redfern (Quart. Jonrn. Micros. Soc, 1855, x. pp. 118-119), on the other hand, supposed the round orange-yellow bodies which occur in torbanite to have had their origin in "“ a mass of vegetable cells and tissues which have been disintegrated and otherwise changed by maceration, pressure, and chemical action, and subsequently solidified."” C. E. Bertrand and B. Renault (Bull. Soc. Hist. Nat. Autun, 1892-3) on microscopic examination have classed these bodies as the remains of gelatinous algae which have been altered by bacterial action.


1983 ◽  
Vol 63 (3) ◽  
pp. 479-484 ◽  
Author(s):  
A. ALZUBAIDI ◽  
G. R. WEBSTER

The kinds and concentrations of the major ion pairs were determined in saturation extracts of 141 soil samples collected from a Solonetzic soil treated with various kinds of tillage combined with surface-applied chemical amendments. The correlations between concentrations of ion pairs and EC and pH of saturation extracts were statistically tested. Sulfate ion pairs NaSO4−, MgSO40 and CaSO40 occurred in relatively high concentrations. The other ion pairs were of low concentrations. Of the total soluble Ca, ion pairs ranged from 20.8% in the Ap horizon to 50.5% in the Csk horizon and Mg was approximately the same. The comparable values for Na were 0.8% and 4.6%, respectively. Ion pairs NaSO4−, KSO4−, MgSO40 and CaSO40 were significantly correlated with EC. Only carbonate ion pairs were significantly correlated with pH. Correcting concentrations of Na, Ca and Mg for ion pairs and activities changed considerably the SAR values in the Bnt1 horizon. Key words: Ion pairs, Solonetzic soils, ion activities


1988 ◽  
Vol 42 (1) ◽  
pp. 44-48 ◽  
Author(s):  
S. M. Tang ◽  
S. H. Tang ◽  
T. S. Tay ◽  
A. T. Retty

Trace element analysis of 60 Burmese and Thai rubies by using the technique of proton-induced x-ray emission was carried out. It was found that the Burmese rubies contained higher concentrations of all impurities except iron. Our results also reveal that vanadium and iron are useful indicators for Burmese and Thai ruby attribution. The Thai rubies have high contents of iron and very low concentrations of vanadium. On the other hand, all the Burmese rubies examined contain significant amounts of vanadium, and their iron contents are, on the average, four times lower than those in the Thai rubies.


2021 ◽  
Vol 3 (2) ◽  
Author(s):  
Moses Oghenenyoreme Eyankware ◽  
Christopher Ogwah ◽  
Joy Chiaka Ike

This paper reviews the mineralogical and chemical characteristics of clays found in southern part of Nigeria, with a view to determine its usability. The usability of clays, depends on its chemical and mineralogical charactertics, the end product of clay after it is been processed is also based on it’s charactertics. From reviewed literature, it was observed that sampled clay within the study area were analyzed using the XRD, XRF and ICPMS method. Further findings also revealed that the dominant clay minerals within the study area include montmorillonite, illite, and kaolinite. On the other hand, it was observed that non-clay minerals such as feldspar, quartz, dickite and many others were found with clay as revealed by several scholars. While chemical charactertics of clay consists mainly of Al2O3, K2O, CaO and SiO2, with other major oxides such as P2O5, MgO, Fe2O3, TiO2, MnO and Na2O. Some trace elements such Be, Ba, Sc, Sr, Zr, V and Y were reported to be present in clays deposit found in selected part of Ogun state. From reviewed articles, it was observed that mineralogical and chemical charactertics of clay make it suitable for pharmaceutical, textile, cosmetic and polymer industries, but considered to be fairly suitable for oil and gas industry.


Sign in / Sign up

Export Citation Format

Share Document