scholarly journals Inference of Pure Titanium Micro-arc Oxidation Process on Microstructure of Calcium Phosphate Membrane Layer

2017 ◽  
Author(s):  
Yu-lei LI ◽  
Jin-jun TANG ◽  
Yue-lai DAI ◽  
Li-jun ZHANG ◽  
Xiao-yu JIN
Keyword(s):  
Calcium Phosphate ◽  
Oxidation Process ◽  
Pure Titanium ◽  
Membrane Layer ◽  
Micro Arc Oxidation

scholarly journals Zn- or Cu-Containing CaP-Based Coatings Formed by Micro-arc Oxidation on Titanium and Ti-40Nb Alloy: Part I—Microstructure, Composition and Properties

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4116 ◽  
Author(s):  
Ekaterina G. Komarova ◽  
Yurii P. Sharkeev ◽  
Mariya B. Sedelnikova ◽  
Konstantin A. Prosolov ◽  
Igor A. Khlusov ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Adhesive Strength ◽  
Applied Voltage ◽  
Oxidation Process ◽  
Pure Titanium ◽  
Atomic Ratio ◽  
Linear Increase ◽  
Microcrystalline Structure ◽  
Micro Arc Oxidation ◽  
Alloy Part

Zn- and Cu-containing CaP-based coatings, obtained by micro-arc oxidation process, were deposited on substrates made of pure titanium (Ti) and novel Ti-40Nb alloy. The microstructure, phase, and elemental composition, as well as physicochemical and mechanical properties, were examined for unmodified CaP and Zn- or Cu-containing CaP coatings, in relation to the applied voltage that was varied in the range from 200 to 350 V. The unmodified CaP coatings on both types of substrates had mainly an amorphous microstructure with a minimal content of the CaHPO4 phase for all applied voltages. The CaP coatings modified with Zn or Cu had a range from amorphous to nano- and microcrystalline structure that contained micro-sized CaHPO4 and Ca(H2PO4)2·H2O phases, as well as nano-sized β-Ca2P2O7, CaHPO4, TiO2, and Nb2O5 phases. The crystallinity of the formed coatings increased in the following order: CaP/TiNb < Zn-CaP/TiNb < Cu-CaP/TiNb < CaP/Ti < Zn-CaP/Ti < Cu-CaP/Ti. The increase in the applied voltage led to a linear increase in thickness, roughness, and porosity of all types of coatings, unlike adhesive strength that was inversely proportional to an increase in the applied voltage. The increase in the applied voltage did not affect the Zn or Cu concentration (~0.4 at%), but led to an increase in the Ca/P atomic ratio from 0.3 to 0.7.

Preparation and characterization of porous bioceramic layers on pure titanium surfaces obtained by micro-arc oxidation process

2017 ◽  
Vol 123 (3) ◽  
Author(s):  
Chi-Sheng Chien ◽  
Yu-Chien Hung ◽  
Ting-Fu Hong ◽  
Chung-Chun Wu ◽  
Tsung-Yuan Kuo ◽  
...  
Keyword(s):  
Oxidation Process ◽  
Pure Titanium ◽  
Porous Bioceramic ◽  
Micro Arc Oxidation ◽  
Titanium Surfaces

Formation of silicon-calcium-phosphate-containing coating on Mg-Zn-Ca alloy by a two-step micro-arc oxidation technique

2018 ◽  
Vol 212 ◽  
pp. 37-40 ◽  
Author(s):  
Jinhe Dou ◽  
Chunyan Wang ◽  
Guochao Gu ◽  
Chuanzhong Chen
Keyword(s):  
Calcium Phosphate ◽  
Micro Arc Oxidation

scholarly journals Amorphous–Crystalline Calcium Phosphate Coating Promotes In Vitro Growth of Tumor-Derived Jurkat T Cells Activated by Anti-CD2/CD3/CD28 Antibodies

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3693
Author(s):  
Yurii P. Sharkeev ◽  
Ekaterina G. Komarova ◽  
Valentina V. Chebodaeva ◽  
Mariya B. Sedelnikova ◽  
Aleksandr M. Zakharenko ◽  
...  
Keyword(s):  
T Cells ◽  
Calcium Phosphate ◽  
Biological Effects ◽  
Electrical Potential ◽  
Biological Properties ◽  
Modern Trend ◽  
Calcium Phosphate Coating ◽  
Jurkat T Cells ◽  
Micro Arc Oxidation

A modern trend in traumatology, orthopedics, and implantology is the development of materials and coatings with an amorphous–crystalline structure that exhibits excellent biocopatibility. The structure and physico–chemical and biological properties of calcium phosphate (CaP) coatings deposited on Ti plates using the micro-arc oxidation (MAO) method under different voltages (200, 250, and 300 V) were studied. Amorphous, nanocrystalline, and microcrystalline statesof CaHPO4 and β-Ca2P2O7were observed in the coatings using TEM and XRD. The increase in MAO voltage resulted in augmentation of the surface roughness Ra from 2.5 to 6.5 µm, mass from 10 to 25 mg, thickness from 50 to 105 µm, and Ca/P ratio from 0.3 to 0.6. The electrical potential (EP) of the CaP coatings changed from −456 to −535 mV, while the zeta potential (ZP) decreased from −53 to −40 mV following an increase in the values of the MAO voltage. Numerous correlations of physical and chemical indices of CaP coatings were estimated. A decrease in the ZP magnitudes of CaP coatings deposited at 200–250 V was strongly associated with elevated hTERT expression in tumor-derived Jurkat T cells preliminarily activated with anti-CD2/CD3/CD28 antibodies and then contacted in vitro with CaP-coated samples for 14 days. In turn, in vitro survival of CD4+ subsets was enhanced, with proinflammatory cytokine secretion of activated Jurkat T cells. Thus, the applied MAO voltage allowed the regulation of the physicochemical properties of amorphous–crystalline CaP-coatings on Ti substrates to a certain extent. This method may be used as a technological mechanism to trigger the behavior of cells through contact with micro-arc CaP coatings. The possible role of negative ZP and Ca2+ as effectors of the biological effects of amorphous–crystalline CaP coatings is discussed. Micro-arc CaP coatings should be carefully tested to determine their suitability for use in patients with chronic lymphoid malignancies.

scholarly journals SEM and EDS Characterization of Porous Coatings Obtained On Titaniumby Plasma Electrolytic Oxidation in Electrolyte Containing Concentrated Phosphoric Acid with Zinc Nitrate

2017 ◽  
Vol 17 (2) ◽  
pp. 41-54 ◽  
Author(s):  
K. Rokosz ◽  
T. Hryniewicz ◽  
K. Pietrzak ◽  
W. Malorny
Keyword(s):  
Phosphoric Acid ◽  
Plasma Electrolytic Oxidation ◽  
Pure Titanium ◽  
Zinc Nitrate ◽  
Porous Coatings ◽  
Electrolytic Oxidation ◽  
Micro Arc Oxidation ◽  
Plasma Electrolytic ◽  
Peo Coatings

AbstractThe SEM and EDS results of porous coatings formed on pure titanium by Plasma Electrolytic Oxidation (Micro Arc Oxidation) under DC regime of voltage in the electrolytes containing of 500 g zinc nitrate Zn(NO3)2·6H2O in 1000 mL of concentrated phosphoric acid H3PO4at three voltages, i.e. 450 V, 550 V, 650 V for 3 minutes, are presented. The PEO coatings with pores, which have different shapes and the diameters, consist mainly of phosphorus, titanium and zinc. The maximum of zinc-to-phosphorus (Zn/P) ratio was found for treatment at 650 V and it equals 0.43 (wt%) | 0.20 (at%), while the minimum of that coefficient was recorded for the voltage of 450 V and equaling 0.26 (wt%) | 0.12 (at%). Performed studies have shown a possible way to form the porous coatings enriched with zinc by Plasma Electrolytic Oxidation in electrolyte containing concentrated phosphoric acid H3PO4with zinc nitrate Zn(NO3)2·6H2O.

Bioactivity, Wear and Corrosion Resistant Properties of Rare Earth/Calcium Phosphate Composite Coatings

2008 ◽  
Vol 368-372 ◽  
pp. 1194-1197 ◽  
Author(s):  
Chen Ma ◽  
Ying Hui Wang ◽  
Mu Qin Li ◽  
Li Jie Qu
Keyword(s):  
Rare Earth ◽  
Calcium Phosphate ◽  
Composite Coatings ◽  
Xrd Analysis ◽  
Wear Properties ◽  
Corrosion Resistant ◽  
Phosphate Coatings ◽  
Wear And Corrosion ◽  
Micro Arc Oxidation ◽  
Calcium Phosphate Coatings

Rare earth/calcium phosphate composite coatings were fabricated on the surface of Ti-6Al-4V by micro-arc oxidation (MAO) technique. The wear properties and corrosion resistant of rare earth/ calcium phosphate composite coatings in the simulated body fluid (SBF) have been investigated and the bioactivity of the composite coatings were evaluated. The results show that the friction coefficient of the composite coatings in the SBF is only 0.15~0.18 and the anode polarization potential of the coating has been obviously enhanced about 0.18V compared with that of coatings of calcium phosphate coatings. So the composite coatings have excellent wear and corrosion resistant properties. XRD analysis indicates that the composite coatings can induce hydroxyapatite to form on its surface after soaked in SBF for 9d, which shows that the composite coatings own good bioactivity.

Effect of Zn content on cytoactivity and bacteriostasis of micro-arc oxidation coatings on pure titanium

2013 ◽  
Vol 228 ◽  
pp. S428-S432 ◽  
Author(s):  
B.H. Zhao ◽  
W. Zhang ◽  
D.N. Wang ◽  
W. Feng ◽  
Y. Liu ◽  
...  
Keyword(s):  
Pure Titanium ◽  
Zn Content ◽  
Micro Arc Oxidation

scholarly journals Tribological functionalization of titanium alloys by Micro-Arc Oxidation for marine applications

2020 ◽  
Vol 321 ◽  
pp. 09001
Author(s):  
Aude MATHIS ◽  
Thierry MILLOT ◽  
Vincent BRANGER ◽  
Remy MULLER ◽  
Jean-Yves GUENEHEUX
Keyword(s):  
Friction Coefficient ◽  
Titanium Alloys ◽  
Pure Titanium ◽  
Dynamic Contact ◽  
Electrochemical Process ◽  
Commercially Pure Titanium ◽  
Tribological Behaviour ◽  
Stick Slip ◽  
Micro Arc Oxidation ◽  
Slip Phenomenon

Micro-arc Oxidation (MAO) process is a plasma assisted electrochemical process, which allows formation of ceramic-like dry oxides on top of light alloys surfaces. The good corrosion resistance as well as the low density of titanium alloys are recognized and so required for conception of structural parts in marine environment. However, their tribological behaviour reveals an important tendency to stick-slip phenomenon, which makes use of these alloys for dynamic contact mechanisms difficult. Through the MAO project from IRT M2P, formation of a MAO coating composed of aluminium titanate has been investigated to improve tribological behaviour of a commercially pure titanium (Grade 2) and an α+β alloy (TA6V, Grade 5). Pin-on-disc testing has been carried out to evaluate friction coefficient and the presence or not of stick-slip phenomenon in various contact configurations (involving non-treated titanium surfaces, MAO treated surfaces, with steel or titanium balls …) in dry or artificial seawater media. Those test campaigns are completed by evaluation of fatigue behaviour, and tribological testing on a demonstrator. Finally, this study highlights influence of MAO coating on diminishing (to removed) stick-slip phenomenon, accompanied by a reduction of friction coefficient, whatever the kind of contact (single treated surface or both ones) and the medium.

scholarly journals Method for measuring the micro-discharges temperature in the micro-arc oxidation process

2019 ◽  
Vol 1393 ◽  
pp. 012083 ◽  
Author(s):  
P E Golubkov ◽  
E A Pecherskaya ◽  
D V Artamonov ◽  
J V Shepeleva
Keyword(s):  
Oxidation Process ◽  
Micro Arc Oxidation
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