scholarly journals Assessment of xanthan gum and xanthan-g-silica derivatives as chemical flooding agents and rock wettability modifiers

Author(s):  
Ahmed Ashraf Soliman ◽  
Abdelaziz Nasr El-hoshoudy ◽  
Attia Mahmoud Attia

Currently, biomolecules flooding in the underground reservoirs acquires sustainable interest owing to their availability and eco-friendly properties. The current study reported chemical displacement by xanthan gum as well as xanthan/SiO2 and xanthan grafted with vinylsilane derivatives. Chemical characterization evaluated by traditional spectroscopic methods. Investigation of fluids response to reservoir environment assessed through rheological performance relative to shearing rate, ionic strength, and thermal stability. A sequence of flooding runs generated on 10 sandstone outcrops with different porosity and permeabilities. Core wetness assessed through relative permeability curves at different water saturation. The flooding tests indicate that grafting of the silica derivative overcome the shortage of xanthan solution in flooding operations relative to the reservoir conditions. The ability of the flooding solutions to alter rock wettability explored through relative permeability curves at different water saturation. The results reveal that the synthesized composite was a promised agent for enhancing oil recovery and profile conformance.

2014 ◽  
Vol 1010-1012 ◽  
pp. 1676-1683 ◽  
Author(s):  
Bin Li ◽  
Wan Fen Pu ◽  
Ke Xing Li ◽  
Hu Jia ◽  
Ke Yu Wang ◽  
...  

To improve the understanding of the influence of effective permeability, reservoir temperature and oil-water viscosity on relative permeability and oil recovery factor, core displacement experiments had been performed under several experimental conditions. Core samples used in every test were natural cores that came from Halfaya oilfield while formation fluids were simulated oil and water prepared based on analyze data of actual oil and productive water. Results from the experiments indicated that the shape of relative permeability curves, irreducible water saturation, residual oil saturation, width of two-phase region and position of isotonic point were all affected by these factors. Besides, oil recovery and water cut were also related closely to permeability, temperature and viscosity ratio.


Energies ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1979
Author(s):  
Omar Chaabi ◽  
Mohammed Al Kobaisi ◽  
Mohamed Haroun

Low salinity waterflooding (LSW) has shown promising results in terms of increasing oil recovery at laboratory scale. In this work, we study the LSW effect, at laboratory scale, and provide a basis for quantifying the effect at field scale by extracting reliable relative permeability curves. These were achieved by experimental and numerical interpretation of laboratory core studies. Carbonate rock samples were used to conduct secondary and tertiary unsteady-state coreflooding experiments at reservoir conditions. A mathematical model was developed as a research tool to interpret and further validate the physical plausibility of the coreflooding experiments. At core scale and a typical field rate of ~1 ft/day, low salinity water (LS) resulted in not only ~20% higher oil recovery compared to formation water (FW) but also recovered oil sooner. LS water also showed capability of reducing the residual oil saturation when flooded in tertiary mode. The greater oil recovery caused by LSW can be attributed to altering the wettability of the rock to less oil-wet as confirmed by the numerically extracted relative permeability curves.


2021 ◽  
pp. 91-107
Author(s):  
E. A. Turnaeva ◽  
E. A. Sidorovskaya ◽  
D. S. Adakhovskij ◽  
E. V. Kikireva ◽  
N. Yu. Tret'yakov ◽  
...  

Enhanced oil recovery in mature fields can be implemented using chemical flooding with the addition of surfactants using surfactant-polymer (SP) or alkaline-surfactant-polymer (ASP) flooding. Chemical flooding design is implemented taking into account reservoir conditions and composition of reservoir fluids. The surfactant in the oil-displacing formulation allows changing the rock wettability, reducing the interfacial tension, increasing the capillary number, and forming an oil emulsion, which provides a significant increase in the efficiency of oil displacement. The article is devoted with a comprehensive study of the formed emulsion phase as a stage of laboratory selection of surfactant for SP or ASP composition. In this work, the influence of aqueous phase salinity level and the surfactant concentration in the displacing solution on the characteristics of the resulting emulsion was studied. It was shown that, according to the characteristics of the emulsion, it is possible to determine the area of optimal salinity and the range of surfactant concentrations that provide increased oil displacement. The data received show the possibility of predicting the area of effectiveness of ASP and SP formulations based on the characteristics of the resulting emulsion.


2021 ◽  
Author(s):  
Marisely Urdaneta

Abstract This paper aims to address calibration of a coreflood Alkali Surfactant Polymer (ASP) formulation experiment through parametrization of fluid-fluid and rock-fluid interactions considering cation exchange capacity and by rock to guide an ASP pilot design. First of all, a series of chemical formulation experiments were studied in cores drilled from clastic reservoir so that displacement lab tests were run on linear and radial cores to determine the potential for oil recovery by ASP flooding and recommended the chemical formulation and flooding schemes, in terms of oil recovery. Therefore, to simulate the process, those tests performed with radial core injection were taken, because this type of test has a better representation of the fluid flow in reservoir, the fluids are injected by a perforation in the center of the core, moving in a radial direction the fluids inside the porous medium. Subsequently, displaced fluids are collected on the periphery of the core carrier and stored in graduated test tubes. The recommended test was carried out to the phase of numerical simulation and historical matching. Reservoir simulation is one of the most important tools available to predict behavior under chemical flooding conditions and to study sensitivities based on cost-effective process implementation. Then, a radial core simulation model was designed from formulation data with porosity of 42.6%, a pore volume (PV) of 344.45 ml, radius of 7.17 cm and weight of 1225.84 g. The initial oil saturation was 0.748 PV (257.58 ml), with a critical water saturation of 0.252 PV (86.78 ml). For the simulation model historical matching, adjustments were made until an acceptable comparison was obtained with laboratory test production data through parameterization of relative permeability curves, chemical adsorption parameters, polymer viscosity, among others; resulting in an accumulated effluents production mass 37% greater for alkali than obtained in the historical, regarding to surfactant the deviation was 8% considered acceptable and for the polymer the adjustment was very close. For the injector well bottom pressure, the viscosity ratio of the mixture was considered based on the polymer concentration and the effect of the shear rate on the viscosity of the polymer as well as the effect of salinity in the alkali case. Finally, a calibrated coreflood numerical simulation model was obtained for ASP flooding to design an ASP Pilot with a residual oil saturation of 0.09 PV (31 ml) meaning 64% more recovered oil compared to a waterflooding case.


2013 ◽  
Vol 53 (1) ◽  
pp. 363
Author(s):  
Yangfan Lu ◽  
Hassan Bahrami ◽  
Mofazzal Hossain ◽  
Ahmad Jamili ◽  
Arshad Ahmed ◽  
...  

Tight-gas reservoirs have low permeability and significant damage. When drilling the tight formations, wellbore liquid invades the formation and increases water saturation of the near wellbore area and significantly deceases permeability of this area. Because of the invasion, the permeability of the invasion zone near the wellbore in tight-gas formations significantly decreases. This damage is mainly controlled by wettability and capillary pressure (Pc). One of the methods to improve productivity of tight-gas reservoirs is to reduce IFT between formation gas and invaded water to remove phase trapping. The invasion of wellbore liquid into tight formations can damage permeability controlled by Pc and relative permeability curves. In the case of drilling by using a water-based mud, tight formations are sensitive to the invasion damage due to the high-critical water saturation and capillary pressures. Reducing the Pc is an effective way to increase the well productivity. Using the IFT reducers, Pc effect is reduced and trapped phase can be recovered; therefore, productivity of the TGS reservoirs can be increased significantly. This study focuses on reducing phase-trapping damage in tight reservoirs by using reservoir simulation to examine the methods, such use of IFT reducers in water-based-drilled tight formations that can reduce Pc effect. The Pc and relative permeability curves are corrected based on the reduced IFT; they are then input to the reservoir simulation model to quantitatively understand how IFT reducers can help improve productivity of tight reservoirs.


2019 ◽  
Vol 89 ◽  
pp. 01004
Author(s):  
Dylan Shaw ◽  
Peyman Mostaghimi ◽  
Furqan Hussain ◽  
Ryan T. Armstrong

Due to the poroelasticity of coal, both porosity and permeability change over the life of the field as pore pressure decreases and effective stress increases. The relative permeability also changes as the effective stress regime shifts from one state to another. This paper examines coal relative permeability trends for changes in effective stress. The unsteady-state technique was used to determine experimental relativepermeability curves, which were then corrected for capillary-end effect through history matching. A modified Brooks-Corey correlation was sufficient for generating relative permeability curves and was successfully used to history match the laboratory data. Analysis of the corrected curves indicate that as effective stress increases, gas relative permeability increases, irreducible water saturation increases and the relative permeability cross-point shifts to the right.


2007 ◽  
Vol 10 (06) ◽  
pp. 730-739 ◽  
Author(s):  
Genliang Guo ◽  
Marlon A. Diaz ◽  
Francisco Jose Paz ◽  
Joe Smalley ◽  
Eric A. Waninger

Summary In clastic reservoirs in the Oriente basin, South America, the rock-quality index (RQI) and flow-zone indicator (FZI) have proved to be effective techniques for rock-type classifications. It has long been recognized that excellent permeability/porosity relationships can be obtained once the conventional core data are grouped according to their rock types. Furthermore, it was also observed from this study that the capillary pressure curves, as well as the relative permeability curves, show close relationships with the defined rock types in the basin. These results lead us to believe that if the rock type is defined properly, then a realistic permeability model, a unique set of relative permeability curves, and a consistent J function can be developed for a given rock type. The primary purpose of this paper is to demonstrate the procedure for implementing this technique in our reservoir modeling. First, conventional core data were used to define the rock types for the cored intervals. The wireline log measurements at the cored depths were extracted, normalized, and subsequently analyzed together with the calculated rock types. A mathematical model was then built to predict the rock type in uncored intervals and in uncored wells. This allows the generation of a synthetic rock-type log for all wells with modern log suites. Geostatistical techniques can then be used to populate the rock type throughout a reservoir. After rock type and porosity are populated properly, the permeability can be estimated by use of the unique permeability/porosity relationship for a given rock type. The initial water saturation for a reservoir can be estimated subsequently by use of the corresponding rock-type, porosity, and permeability models as well as the rock-type-based J functions. We observed that a global permeability multiplier became unnecessary in our reservoir-simulation models when the permeability model is constructed with this technique. Consistent initial-water-saturation models (i.e., calculated and log-measured water saturations are in excellent agreement) can be obtained when the proper J function is used for a given rock type. As a result, the uncertainty associated with volumetric calculations is greatly reduced as a more accurate initial-water-saturation model is used. The true dynamic characteristics (i.e., the flow capacity) of the reservoir are captured in the reservoir-simulation model when a more reliable permeability model is used. Introduction Rock typing is a process of classifying reservoir rocks into distinct units, each of which was deposited under similar geological conditions and has undergone similar diagenetic alterations (Gunter et al. 1997). When properly classified, a given rock type is imprinted by a unique permeability/porosity relationship, capillary pressure profile (or J function), and set of relative permeability curves (Gunter et al. 1997; Hartmann and Farina 2004; Amaefule et al. 1993). As a result, when properly applied, rock typing can lead to the accurate estimation of formation permeability in uncored intervals and in uncored wells; reliable generation of initial-water-saturation profile; and subsequently, the consistent and realistic simulation of reservoir dynamic behavior and production performance. Of the various quantitative rock-typing techniques (Gunter et al. 1997; Hartmann and Farina 2004; Amaefule et al. 1993; Porras and Campos 2001; Jennings and Lucia 2001; Rincones et al. 2000; Soto et al. 2001) presented in the literature, two techniques (RQI/FZI and Winland's R35) appear to be used more widely than the others for clastic reservoirs (Gunter et al. 1997, Amaefule et al. 1993). In the RQI/FZI approach (Amaefule et al. 1993), rock types are classified with the following three equations: [equations]


1961 ◽  
Vol 1 (02) ◽  
pp. 61-70 ◽  
Author(s):  
J. Naar ◽  
J.H. Henderson

Introduction The displacement of a wetting fluid from a porous medium by a non-wetting fluid (drainage) is now reasonably well understood. A complete explanation has yet to be found for the analogous case of a wetting fluid being spontaneously imbibed and the non-wetting phase displaced (imbibition). During the displacement of oil or gas by water in a water-wet sand, the porous medium ordinarily imbibes water. The amount of oil recovered, the cost of recovery and the production history seem then to be controlled mainly by pore geometry. The influence of pore geometry is reflected in drainage and imbibition capillary-pressure curves and relative permeability curves. Relative permeability curves for a particular consolidated sand show that at any given saturation the permeability to oil during imbibition is smaller than during drainage. Low imbibition permeabilities suggest that the non-wetting phase, oil or gas, is gradually trapped by the advancing water. This paper describes a mathematical image (model) of consolidated porous rock based on the concept of the trapping of the non-wetting phase during the imbibition process. The following items have been derived from the model.A direct relation between the relative permeability characteristics during imbibition and those observed during drainage.A theoretical limit for the fractional amount of oil or gas recoverable by imbibition.An expression for the resistivity index which can be used in connection with the formula for wetting-phase relative permeability to check the consistency of the model.The limits of flow performance for a given rock dictated by complete wetting by either oil or water.The factors controlling oil recovery by imbibition in the presence of free gas. The complexity of a porous medium is such that drastic simplifications must be introduced to obtain a model amenable to mathematical treatment. Many parameters have been introduced by others in "progressing" from the parallel-capillary model to the randomly interconnected capillary models independently proposed by Wyllie and Gardner and Marshall. To these a further complication must be added since an imbibition model must trap part of the non-wetting phase during imbibition of the wetting phase. Like so many of the previously introduced complications, this fluid-block was introduced to make the model performance fit the observed imbibition flow behavior.


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