scholarly journals A comprehensive review of in situ polymer hydrogels for conformance control of oil reservoirs

Author(s):  
Kelly Lúcia Nazareth Pinho de Aguiar ◽  
Priscila Frias de Oliveira ◽  
Claudia Regina Elias Mansur

In fractured reservoirs, fluids injected Enhanced Oil Recovery (EOR) are channeled through the fracture zones and travel through highly permeable regions, failing to displace part of the oil, and decreasing oil recovery efficiency. To solve these problems, the conformance control technique is now widely used, as it allows the reservoir to be swept totally, similar to the ideal condition. In this context, polyacrylamide-based polymer gel systems can be used to block the high-permeability regions of the rock matrix, forming in situ hydrogels that block the rock pores, avoiding the channeling of the fluids, and increasing the oil production. These polyacrylamide-based hydrogels can be crosslinked by inorganic (metal ions) or organic substances, and various systems are used for conformance control. Due to the greater stability of the bond formed between the polymer and the organic crosslinker, these systems are now used in higher temperature reservoirs. In order to produce hydrogels with higher resistance to severe salinity and temperature conditions, nanoparticles are applied to form systems with good mechanical resistance, and high thermal stability. These have presented promising results for conformance control.

2021 ◽  
pp. 1-13
Author(s):  
Melek Deniz Paker ◽  
Murat Cinar

Abstract A significant portion of world oil reserves reside in naturally fractured reservoirs and a considerable amount of these resources includes heavy oil and bitumen. Thermal enhanced oil recovery methods (EOR) are mostly applied in heavy oil reservoirs to improve oil recovery. In situ combustion (/SC) is one of the thermal EOR methods that could be applicable in a variety of reservoirs. Unlike steam, heat is generated in situ due to the injection of air or oxygen enriched air into a reservoir. Energy is provided by multi-step reactions between oxygen and the fuel at particular temperatures underground. This method upgrades the oil in situ while the heaviest fraction of the oil is burned during the process. The application of /SC in fractured reservoirs is challenging since the injected air would flow through the fracture and a small portion of oil in the/near fracture would react with the injected air. Only a few researchers have studied /SC in fractured or high permeability contrast systems experimentally. For in situ combustion to be applied in fractured systems in an efficient way, the underlying mechanism needs to be understood. In this study, the major focus is permeability variation that is the most prominent feature of fractured systems. The effect of orientation and width of the region with higher permeability on the sustainability of front propagation are studied. The contrast in permeability was experimentally simulated with sand of different particle size. These higher permeability regions are analogous to fractures within a naturally fractured rock. Several /SC tests with sand-pack were carried out to obtain a better understanding of the effect of horizontal vertical, and combined (both vertical and horizontal) orientation of the high permeability region with respect to airflow to investigate the conditions that are required for a self-sustained front propagation and to understand the fundamental behavior. Within the experimental conditions of the study, the test results showed that combustion front propagated faster in the higher permeability region. In addition, horizontal orientation almost had no effect on the sustainability of the front; however, it affected oxygen consumption, temperature, and velocity of the front. On the contrary, the vertical orientation of the higher permeability region had a profound effect on the sustainability of the combustion front. The combustion behavior was poorer for the tests with vertical orientation, yet the produced oil AP/ gravity was higher. Based on the experimental results a mechanism has been proposed to explain the behavior of combustion front in systems with high permeability contrast.


2018 ◽  
Vol 32 (1) ◽  
pp. 360-372 ◽  
Author(s):  
Chao-Yu Sie ◽  
Bradley Nguyen ◽  
Marco Verlaan ◽  
Orlando Castellanos-Diaz ◽  
Kelli Adiaheno ◽  
...  

2021 ◽  
Author(s):  
Lyla Almaskeen ◽  
Abdulkareem AlSofi ◽  
Jinxun Wang ◽  
Ziyad Kaidar

Abstract In naturally fractured reservoirs, conformance control prior to enhanced oil recovery (EOR) application might be essential to ensure optimal contact and sufficient sweep. Recently, few studies investigated combining foams and gels into what is commonly coined as foamed-gels. Foamed-gels have been tested and shown to be potential for some field conditions. Yet, very limited studies were performed for high temperature and high salinity carbonates. Therefore, in this work, we study the potential of foamed-gels for high temperature and high salinity carbonates. The objective is to evaluate the potential of such synergy and to compare its value to the individual processes. For that purpose, in this work, we rely on bulk and core-scale tests. Bulk tests were used for initial screening. Wide range of foam-gel solutions were prepared with different polymer types and polymer concentrations. Test tubes were hand shacked thoroughly to generate foams. Foam heights were then measured from the test tubes. Heights were used to screen foaming agents and to study gelant effects on foamers in terms of foam strength (heights). The effect of foamers on gelation was evaluated through bottle tests. Based on the results, an optimal concentration ratio of gelant to foamer was determined and used in core-scale displacements, to further study the potential of this hybrid foam-gel process. Bulk results suggested that addition of the gelant up to a 4:1 foam to gel concentration ratio resulted in sufficient foam generation in some of the polymer samples. Yet, only two of the foam-gel samples generated a strong gel. Increasing the foamer concentration delayed the gelation time and in some samples, the solution did not gel. Through the coreflooding experiment, resistance factor (RF) and residual resistance factor (RRF) were obtained for different conformance control processes including foam, foam-gel, and gel. Foam-gel injection exhibited higher RF and RRF values than conventional foams. However, conventional gels showed even higher RF and RRF values than foam-gels. Combining two of the most widely used conformance control methods (foams and gels) can strike a balance. Foam-gel may offer a treatment that is deeper and more sustainable than foams and on the other a treatment that is more practical, and lower-cost than gels. Our laboratory results also demonstrate that such synergetic conformance control can be achieved in high salinity and high temperature carbonates with pronounced impact.


2018 ◽  
Vol 30 (1) ◽  
pp. 13-39 ◽  
Author(s):  
Zulhelmi Amir ◽  
Ismail Mohd Said ◽  
Badrul Mohamed Jan

SPE Journal ◽  
2016 ◽  
Vol 22 (01) ◽  
pp. 32-40 ◽  
Author(s):  
B.. Brattekås ◽  
M.. Steinsbø ◽  
A.. Graue ◽  
M. A. Fernø ◽  
H.. Espedal ◽  
...  

Summary Polymer gel is frequently used for conformance control in fractured reservoirs, where it is injected to reside in fractures or high-permeability streaks to reduce conductivity. With successful polymer-gel conformance control in place, increased pressure gradients across matrix blocks may be achieved during chase floods, diverting water, gas, or enhanced oil recovery (EOR) chemicals into the matrix to displace oil. Knowledge of gel behavior during placement and chase floods is important because it largely controls the success of subsequent injections. Polymer-gel behavior is often studied in corefloods, where differential pressure and effluents from fracture and matrix outlets give information about gel deposition during placement and flow paths during chase floods. The work presented in this paper uses complementary positron emission tomography (PET) chromatographic tomography (CT) imaging to quantify the behavior and blocking capacity of Cr(III)-acetate hydrolyzed polyacrylamide (HPAM) gel during chase waterflooding. In-situ imaging provides information about changes that may not be extracted from pressure measurements and material balance only, such as changes in local fluid saturations and dynamic spatial flow within the fracture and within the structure of the gel network. Polymer gel was placed in core plugs with longitudinal fractures that connected the inlet and outlet, and chase water was subsequently injected to measure the gel blocking capacity. The water phase was labeled with a positron emitting radiopharmaceutical (F-18) to visualize and quantify local flows with PET during gel rupture and subsequent flooding. By use of PET, we study gel rupture and the development of wormholes during gel erosion after rupture as a function of flow rate. A particular strength with access to dynamic, local flow patterns is the direct comparison to global measurements, such as differential pressure and production rate, to verify existing gel-behavior models.


Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Yanxia Zhou ◽  
Xiangguo Lu ◽  
Bao Cao ◽  
Yigang Liu ◽  
Yunbao Zhang ◽  
...  

NB35-2 oilfield is a typical offshore sandstone reservoir with viscous crude oil and high permeability. Due to the inherent severe heterogeneity, the efficiency of conventional water flooding is pretty low and usually accompanied with early water breakthrough. In order to recover the residual oil and better realize its potential, applications of enhanced oil recovery (EOR) technology are necessary. However, the selection of EOR method and related parameters may directly impact the final results and can be noticeably different for different reservoirs; therefore, to optimize the oil production rate and final oil recovery, systematical optimization of every detail based on the condition of a specific reservoir is of key importance. In this paper, physical simulations were first conducted to select the best recovery methods for the target area based on the static geophysical model under the guidance of reservoir engineering theory. Then, detailed development variants for each method were determined by numerical simulation with the support of data obtained from previous pilot tests (polymer gel flooding and thermal fluid huff and puff) conducted in this area. Three exploitation methods were developed for the target well group, including polymer gel flooding (conformance control, Pattern 1), steam huff and puff (thermal recovery method, Pattern 2), and a combination of polymer gel flooding and steam huff and puff (conformance control and thermal recovery, Pattern 3). The numerical simulation result also showed that Pattern 3 yielded the highest oil recovery. Moreover, the amount of additional oil being recovered by applying Pattern 3 was even higher than the total additional oil being extracted by Patterns 1 and 2. In addition, sensitivity analysis was conducted to rank the most important parameters based on the three Patterns. At last, it is thought that the synergistic effect between conformance control and thermal recovery made more oil recovered, which was intuitively clarified in the mechanism analysis.


1999 ◽  
Vol 2 (01) ◽  
pp. 14-24 ◽  
Author(s):  
T.L. Hughes ◽  
F. Friedmann ◽  
D. Johnson ◽  
G.P. Hild ◽  
A. Wilson ◽  
...  

Summary Large-volume foam-gel treatments can provide a cost-effective method to achieve in-depth conformance improvement in fractured reservoirs. The applicability and cost effectiveness of the approach depends on the availability of a cheap source of gas, the efficiency with which the foam can be placed into the high permeability thief zone(s), and the effectiveness of the gelled foam barrier in diverting reservoir drive fluids to improve oil recovery. This paper reviews progress in the application of large-volume CO2-foam-gel treatments to improve conformance in the Rangely Weber Sand Unit (RWSU), Colorado. During the period November 1996-November 1997 three large-volume foam-gel treatments were successfully placed into the Rangely reservoir. The first 36?400 bbl treatment, implemented November 1996, increased the pattern oil rate from 260 barrels of oil per day (BOPD) in March 1997 to ±330 BOPD in August 1998; a conservative estimate of incremental oil recovery is ±40?000 bbl by the end of August 1998. The second 43?450 bbl treatment, implemented August-September 1997, increased the pattern oil rate from ±430 BOPD in March 1998 to ±470 BOPD in August 1998; post-treatment, the pattern oil rate data is described by a linear regression with slope, +56 BOPD but it is too early to make a firm estimate of incremental oil recovery. The third 44?700 bbl treatment, implemented October-November 1997, increased the pattern oil rate from ±330 BOPD in May 1998 to ±375 BOPD in July-August 1998; a linear regression of the post-treatment data gives a positive slope but again it is too early to estimate incremental oil recovery. Some general features in the pattern production response given by the three foam-gel treatments were observed. First, each of the treatments induces a stabilization in the pattern oil rate which, for treatments I and II, is accompanied by a decrease in the pattern gas rate. Second, the first positive oil rate response given by each of the treatments is observed 6-8 months after treatment execution and is dominated by the response at producer wells lying to the west/southwest and/or east/southeast of the treated injector well. For a given treatment volume, the cost of a foam-gel treatment at Rangely is 40%-50% below the average cost of polymer gel treatments. As the foam is injected at a higher rate, the total pump time required for a 40?000 bbl foam-gel treatment is similar to a 20?000 bbl polymer gel treatment. Early during pumping treatments II and III, we attempted to increase the CO2 content of the foam from 80 to 85 vol?%; this resulted in a wellhead pressure which was too close to the CO2 pressure limit necessitating a decrease in foam injection rate. Thus, in optimizing foam-gel treatment cost, there is a balance between maximizing the content of the inexpensive CO2 phase and minimizing total pump time. For Treatments II and III, the cost of the liquid phase formulation was reduced by decreasing the concentrations of surfactant and buffer. The implementation and evaluation of three large-volume foam-gel treatments at Rangely indicates that the foam-gel approach provides a cost-effective method to achieve in-depth conformance improvement in fractured reservoirs. Introduction A recent survey1 indicated that the proportion of U.S. EOR production recovered by gas injection has increased from 18% to 41% during the period 1986-1996. A major contribution to this trend has been the strong increase in the number of miscible carbon dioxide (CO2) projects which now account for > 70% of the total number of ongoing gas injection projects in the U.S. The Rangely CO2 flood began in 1986; currently, there are 372 active producer wells and 300 active injector wells, 259 of which are injecting CO2 using the water-alternating-gas (WAG) process. In the application of gas injection to heterogeneous reservoirs, oil recovery efficiency can be limited by poor conformance as an increasing proportion of the injected gas flows through higher permeability thief zones and/or fractures. The importance of conformance improvement has long been recognized at Rangely. The main problem being addressed is poor CO2 conformance due to preferential flow through the natural fracture network leading to premature gas breakthrough at the associated producers. This process increases operating costs and reduces oil recovery. The objective of the Rangely Conformance Improvement Team (CIT) is to improve conformance in order to reduce operating costs and increase the oil recovery to >1 billion bbl (>50% OOIP) compared to the current 815 million bbl (43% OOIP). A number of mechanical methods and chemical treatments have been employed to improve conformance at Rangely. While dual injection strings and selective injection equipment (SIE) have been used for improved injection profile control, chemical treatments using polymer gels2 and CO2 foam3 have been used to improve volumetric sweep efficiency and oil recovery. During the period 1994-1997, 49 injector wells were treated by placing a MARCIT™ gel4 into the fracture network.5 While these treatments have improved local sweep efficiency and oil recovery, economics limit the maximum treatment volume per injector well to 15?000-20?000 bbl. Certain regions of the Rangely reservoir require considerably larger treatment volumes to reduce the permeability of a larger volume of the fracture network and improve conformance in a larger volume of the well pattern.


Fuels ◽  
2021 ◽  
Vol 2 (3) ◽  
pp. 304-322
Author(s):  
Velima Obino ◽  
Upendra Yadav

One highly undesirable characteristic of mature assets that inhibits oil recovery is high water production. Polymer gel treatment is a popular conformance improvement technique applied in this regard due to its cost effectiveness and proved efficiency. Despite this popularity, optimum performance of polymer hydrogels in water shut off is inhibited by excessive aggregation, difficulty in controlling gelation, and their instability at high temperature and high salinity reservoir conditions. To address these shortcomings, research on the application of nanoparticles (NPs) in polymer hydrogels to manage thermal stability and salinity sensitivity has significantly increased in the recent past. By incorporating metal-based NPs, silica or graphene at nanoscale; the gel strength, storage modulus, salinity tolerance and thermal stability of commonly used polymers have been greatly enhanced. In this paper, the advances in experimental studies on polymer-based nanocomposites are discussed and field experiences from adoption of polymer composites reviewed.


2020 ◽  
Vol 60 (2) ◽  
pp. 658
Author(s):  
Reza M. Rudd ◽  
Ali Saeedi ◽  
Colin D. Wood

Conformance control is a major challenge in hydrocarbon recovery operations. One of the effective technologies for improving the conformance of a flood front and modifying the injected fluid profile is the application of polymer hydrogels. In this technique, polymer hydrogels are prepared as gel particles, which are injected into the reservoir to block-off preferential flow paths and thief zones, such as fractures and high permeability zones. Subsequently, the fluid injected as part of oil recovery operation would be directed and forced to pass through low permeable zones and sweep more hydrocarbon mass towards the production wells. Depending on the situation, this technology can result in a considerable incremental hydrocarbon recovery from a reservoir. In the present research, nanotechnology was combined with polymer engineering to develop a novel polymer nanocomposite hydrogel with supreme properties, as confirmed using advanced rheological characterisation. Subsequently, the performance of the newly developed nanocomposite hydrogel was tested using a specially designed core flooding setup and procedure. The core flooding results showed that the application of this novel hydrogel could increase the oil recovery by up to 16% under laboratory conditions.


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