scholarly journals On the development of a new nonequilibrium chemistry model for Mars entry

2017 ◽  
Author(s):  
Richard L. Jaffe ◽  
David W. Schwenke ◽  
Galina M. Chaban ◽  
Dinesh K. Prabhu ◽  
Christopher O. Johnston ◽  
...  
Keyword(s):  
Nonequilibrium Chemistry

Nonequilibrium Chemistry in Circumstellar Shells

1988 ◽  
pp. 231-248 ◽  
Author(s):  
A. Goeres ◽  
R. Henkel ◽  
E. Sedlmayr ◽  
H.-P. Gail
Keyword(s):  
Circumstellar Shells ◽  
Nonequilibrium Chemistry

scholarly journals A simple hydrogel device with flow-through channels to maintain dissipative non-equilibrium phenomena

2020 ◽  
Vol 3 (1) ◽  
Author(s):  
Brigitta Dúzs ◽  
István Szalai
Keyword(s):  
Materials Science ◽  
Control Parameters ◽  
Living Matter ◽  
Equilibrium Conditions ◽  
Chemical Systems ◽  
Chemical Gradients ◽  
Nonequilibrium Phenomena ◽  
Reaction Zones ◽  
Flow Through ◽  
Nonequilibrium Chemistry

AbstractThe development of autonomous chemical systems that could imitate the properties of living matter, is a challenging problem at the meeting point of materials science and nonequilibrium chemistry. Here we design a multi-channel gel reactor in which out-of-equilibrium conditions are maintained by antagonistic chemical gradients. Our device is a rectangular hydrogel with two or more channels for the flows of separated reactants, which diffuse into the gel to react. The relative position of the channels acts as geometric control parameters, while the concentrations of the chemicals in the channels and the variable composition of the hydrogel, which affects the diffusivity of the chemicals, can be used as chemical control parameters. This flexibility allows finding easily the optimal conditions for the development of nonequilibrium phenomena. We demonstrate this straightforward operation by generating diverse spatiotemporal patterns in different chemical reactions. The use of additional channels can create interacting reaction zones.

scholarly journals Self-oscillating Chemoelectrical Interface of Solution-gated Ion-sensitive Field-effect Transistor Based on Belousov–zhabotinsky Reaction

2021 ◽  
Author(s):  
Toshiya Sakata ◽  
Shoichi Nishitani ◽  
Yusuke Yasuoka ◽  
Shogo Himori ◽  
Kenta Homma ◽  
...  
Keyword(s):  
Field Effect ◽  
Large Scale ◽  
Field Effect Transistor ◽  
Electrical Response ◽  
Polymer Brush ◽  
Gate Insulator ◽  
Polymer Gel ◽  
Bz Reaction ◽  
Effect Transistor ◽  
Nonequilibrium Chemistry

Abstract The Belousov–Zhabotinsky (BZ) self-oscillation reaction is an important chemical model to elucidate nonequilibrium chemistry in an open system. However, there are only a few studies on the electrical behavior of pH oscillation induced by the BZ reaction, although numerous studies have been carried out to investigate the mechanisms by which the BZ reaction interacts with redox reactions, which results in potential changes. Needless to say, the electrical characteristic of a self-oscillating polymer gel driven by the BZ reaction has not been clarified. On the other hand, a solution-gated ion-sensitive field-effect transistor (ISFET) has a superior ability to detect ionic charges and includes capacitive membranes on the gate electrode. In this study, we carried out the electrical monitoring of self-oscillation behaviors at the chemoelectrical interface based on the BZ reaction using ISFET sensors, focusing on the pH oscillation and the electrical dynamics of the self-oscillating polymer brush. The pH oscillation induced by the BZ reaction is not only electrically observed using the ISFET sensor, the electrical signals of which results from the interfacial potential between the solution and the gate insulator, but also visualized using a large-scale and high-density ISFET sensor. Moreover, the N-isopropylacrylamide (NIPAAm)-based self-oscillating polymer brush with Ru(bpy)3 as a catalyst clearly shows a periodic electrical response based on the swelling–deswelling behavior caused by the BZ reaction on the gate insulator of the ISFET sensor. Thus, the elucidation of the electrical self-oscillation behaviors induced by the BZ reaction using the ISFET sensor provides a solution to the problems of nonequilibrium chemistry.

scholarly journals A study of interstellar aldehydes and enols as tracers of a cosmic ray-driven nonequilibrium synthesis of complex organic molecules

2016 ◽  
Vol 113 (28) ◽  
pp. 7727-7732 ◽  
Author(s):  
Matthew J. Abplanalp ◽  
Samer Gozem ◽  
Anna I. Krylov ◽  
Christopher N. Shingledecker ◽  
Eric Herbst ◽  
...  
Keyword(s):  
Organic Molecules ◽  
Cosmic Ray ◽  
Formation Mechanisms ◽  
Molecular Precursors ◽  
Star Forming ◽  
Star Forming Regions ◽  
Interstellar Ices ◽  
A Chain ◽  
Nonequilibrium Chemistry ◽  
Complex Organic

Complex organic molecules such as sugars and amides are ubiquitous in star- and planet-forming regions, but their formation mechanisms have remained largely elusive until now. Here we show in a combined experimental, computational, and astrochemical modeling study that interstellar aldehydes and enols like acetaldehyde (CH3CHO) and vinyl alcohol (C2H3OH) act as key tracers of a cosmic-ray-driven nonequilibrium chemistry leading to complex organics even deep within low-temperature interstellar ices at 10 K. Our findings challenge conventional wisdom and define a hitherto poorly characterized reaction class forming complex organic molecules inside interstellar ices before their sublimation in star-forming regions such as SgrB2(N). These processes are of vital importance in initiating a chain of chemical reactions leading eventually to the molecular precursors of biorelevant molecules as planets form in their interstellar nurseries.

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