Quantification of rare earth elements with low pressure laser induced breakdown spectroscopy employing subtarget supported micro mesh sample holder

2019 ◽  
Vol 31 (3) ◽  
pp. 032001
Author(s):  
Mangasi Alion Marpaung ◽  
Javed Iqbal ◽  
Marincan Pardede ◽  
Muhammad Bilal ◽  
Rinda Hedwig ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Low Pressure ◽  
Laser Induced Breakdown Spectroscopy ◽  
Sample Holder ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown

scholarly journals Analysis of Rare Earth Elements in Uranium Using Handheld Laser-Induced Breakdown Spectroscopy (HH LIBS)

2018 ◽  
Vol 72 (11) ◽  
pp. 1653-1660 ◽  
Author(s):  
Benjamin T. Manard ◽  
E. Miller Wylie ◽  
Stephen P. Willson
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Uranium Oxide ◽  
Nuclear Material ◽  
Standard Reference Materials ◽  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown ◽  
Subsequent Exposure ◽  
Uranium Matrix

A portable handheld laser-induced breakdown spectroscopy (HH LIBS) instrument was evaluated as a rapid method to qualitatively analyze rare earth elements in a uranium oxide matrix. This research is motivated by the need for development of a method to perform rapid, at-line chemical analysis in a nuclear facility, particularly to provide a rapid first pass analysis to determine if additional actions or measurements are warranted. This will result in the minimization of handling and transport of radiological and nuclear material and subsequent exposure to their associated hazards. In this work, rare earth elements (Eu, Nd, and Yb) were quantitatively spiked into a uranium oxide powder and analyzed by the HH LIBS instrumentation. This method demonstrates the ability to rapidly identify elemental constituents in sub-percent levels in a uranium matrix. Preliminary limits of detection (LODs) were determined with values on the order of hundredths of a percent. Validity of this methodology was explored by employing a National Institute of Standards and Technology (NIST) standard reference materials (SRM) 610 and 612 (Trace Elements in Glass). It was determined that the HH LIBS method was able to clearly discern the rare earths elements of interest in the glass or uranium matrices.

scholarly journals Quantification of rare earth elements using laser-induced breakdown spectroscopy

2015 ◽  
Vol 114 ◽  
pp. 65-73 ◽  
Author(s):  
Madhavi Martin ◽  
Rodger C. Martin ◽  
Steve Allman ◽  
Deanne Brice ◽  
Ann Wymore ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown

scholarly journals Detection of Rare Earth Elements in Minerals and Soils by Laser-Induced Breakdown Spectroscopy (LIBS) Using Interval PLS

Minerals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1379
Author(s):  
Nina Rethfeldt ◽  
Pia Brinkmann ◽  
Daniel Riebe ◽  
Toralf Beitz ◽  
Nicole Köllner ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Matrix Effects ◽  
Principal Component ◽  
Laser Induced Breakdown Spectroscopy ◽  
Regression Methods ◽  
Breakdown Spectroscopy ◽  
Field Samples ◽  
Laser Induced Breakdown

The numerous applications of rare earth elements (REE) has lead to a growing global demand and to the search for new REE deposits. One promising technique for exploration of these deposits is laser-induced breakdown spectroscopy (LIBS). Among a number of advantages of the technique is the possibility to perform on-site measurements without sample preparation. Since the exploration of a deposit is based on the analysis of various geological compartments of the surrounding area, REE-bearing rock and soil samples were analyzed in this work. The field samples are from three European REE deposits in Sweden and Norway. The focus is on the REE cerium, lanthanum, neodymium and yttrium. Two different approaches of data analysis were used for the evaluation. The first approach is univariate regression (UVR). While this approach was successful for the analysis of synthetic REE samples, the quantitative analysis of field samples from different sites was influenced by matrix effects. Principal component analysis (PCA) can be used to determine the origin of the samples from the three deposits. The second approach is based on multivariate regression methods, in particular interval PLS (iPLS) regression. In comparison to UVR, this method is better suited for the determination of REE contents in heterogeneous field samples.

scholarly journals Evaluating Laser-Induced Breakdown Spectroscopy Sensor Technology for Rapid Source Characterization of Rare Earth Elements

2019 ◽  
Vol 141 (7) ◽  
Author(s):  
Daniel A. Hartzler ◽  
Chet R. Bhatt ◽  
Jinesh C. Jain ◽  
Dustin L. McIntyre
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
High Sensitivity ◽  
Spectral Lines ◽  
Sensor Technology ◽  
Laser Induced Breakdown Spectroscopy ◽  
Source Characterization ◽  
Solid Samples ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown

A prototype laser-induced breakdown spectroscopy (LIBS) sensor is tested for the determination of rare earth elements (Eu and Yb) in liquid and solid samples. The sensor head, built using a monolithic passively Q-switched (PQSW) Nd:YAG laser, produced a 1064 nm laser beam with ns pulses and an energy of 4.2 mJ. The measurements show good calibration linearity for both Eu and Yb with R2 values above 0.99 for all analyzed spectral lines in liquid and solid samples. Limits of detection (LODs) obtained were as low as 1 ppm, which are comparable to or better than those reported previously by using table top actively Q-switched systems. This study aims to develop a high sensitivity, field deployable sensor for characterizing existing and new sources of rare earth elements.

scholarly journals Determination of Rare Earth Elements in Geological Samples Using Laser-Induced Breakdown Spectroscopy (LIBS)

2017 ◽  
Vol 72 (1) ◽  
pp. 114-121 ◽  
Author(s):  
Chet R. Bhatt ◽  
Jinesh C. Jain ◽  
Christian L. Goueguel ◽  
Dustin L. McIntyre ◽  
Jagdish P. Singh
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Inductively Coupled Plasma ◽  
Mass Spectrometry Analysis ◽  
Laser Induced Breakdown Spectroscopy ◽  
Least Squares Regression ◽  
Geological Samples ◽  
Spectrometry Analysis ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown

Laser-induced breakdown spectroscopy (LIBS) was used to detect rare earth elements (REEs) in natural geological samples. Low and high intensity emission lines of Ce, La, Nd, Y, Pr, Sm, Eu, Gd, and Dy were identified in the spectra recorded from the samples to claim the presence of these REEs. Multivariate analysis was executed by developing partial least squares regression (PLS-R) models for the quantification of Ce, La, and Nd. Analysis of unknown samples indicated that the prediction results of these samples were found comparable to those obtained by inductively coupled plasma mass spectrometry analysis. Data support that LIBS has potential to quantify REEs in geological minerals/ores.

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