The Linear Energy Transfer Dependence of Excited Singlet-State Lifetimes of Hydrocarbon Liquids Exposed to X Rays

1993 ◽  
Vol 135 (3) ◽  
pp. 312 ◽  
Author(s):  
Richard A. Holroyd ◽  
Jack M. Preses ◽  
Jonathan C. Hanson
2003 ◽  
Vol 2 (3) ◽  
pp. 251-258 ◽  
Author(s):  
Tero Kesti ◽  
Nikolai Tkachenko ◽  
Hiroko Yamada ◽  
Hiroshi Imahori ◽  
Shunichi Fukuzumi ◽  
...  

1997 ◽  
Vol 101 (37) ◽  
pp. 6931-6935 ◽  
Author(s):  
R. A. Holroyd ◽  
J. M. Preses ◽  
J. C. Hanson

2003 ◽  
Vol 81 (6) ◽  
pp. 660-668 ◽  
Author(s):  
Wen-Shan Li ◽  
Lokman Torun ◽  
Harry Morrison

The synthesis, photochemistry, and photophysics of 17α-bromo-3α-(triphenylsilyloxy)-5α-androstan-6-one (1) and 17β-bromo-3β-(triphenylsilyloxy)-5α-androstan-6-one (2) have been studied in aqueous tetrahydrofuran. The 17α-bromo isomer gives evidence (reduced ϕf, τ1, and ϕisc for the ketone) for interaction between the ketone and C–Br moieties in the excited singlet state. Some photodehalogenation is also observed upon excitation of the ketone chromophore. This interaction seems to be absent or minimal for the 17β-bromo isomer.Key words: photodehalogenation, bromosteroid, ketosteroid, intramolecular singlet–singlet energy transfer (ISSET).


2002 ◽  
Vol 76 (1) ◽  
pp. 47 ◽  
Author(s):  
Joakim Andréasson ◽  
Gerdenis Kodis ◽  
Su Lin ◽  
Ana L. Moore ◽  
Thomas A. Moore ◽  
...  

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