Energy transfer from the second excited singlet state of spirobifluorene

1978 ◽  
Vol 34 (3) ◽  
pp. 320-322
Author(s):  
Bruce S. Hass ◽  
Richard M. Hedges
2003 ◽  
Vol 2 (3) ◽  
pp. 251-258 ◽  
Author(s):  
Tero Kesti ◽  
Nikolai Tkachenko ◽  
Hiroko Yamada ◽  
Hiroshi Imahori ◽  
Shunichi Fukuzumi ◽  
...  

2003 ◽  
Vol 81 (6) ◽  
pp. 660-668 ◽  
Author(s):  
Wen-Shan Li ◽  
Lokman Torun ◽  
Harry Morrison

The synthesis, photochemistry, and photophysics of 17α-bromo-3α-(triphenylsilyloxy)-5α-androstan-6-one (1) and 17β-bromo-3β-(triphenylsilyloxy)-5α-androstan-6-one (2) have been studied in aqueous tetrahydrofuran. The 17α-bromo isomer gives evidence (reduced ϕf, τ1, and ϕisc for the ketone) for interaction between the ketone and C–Br moieties in the excited singlet state. Some photodehalogenation is also observed upon excitation of the ketone chromophore. This interaction seems to be absent or minimal for the 17β-bromo isomer.Key words: photodehalogenation, bromosteroid, ketosteroid, intramolecular singlet–singlet energy transfer (ISSET).


2002 ◽  
Vol 76 (1) ◽  
pp. 47 ◽  
Author(s):  
Joakim Andréasson ◽  
Gerdenis Kodis ◽  
Su Lin ◽  
Ana L. Moore ◽  
Thomas A. Moore ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document