A Comparison of the Effects of X-Rays and Alpha Rays on Some Proteins and Amino Acids in Dilute Aqueous Solution

1961 ◽  
Vol 15 (4) ◽  
pp. 475 ◽  
Author(s):  
P. Alexander ◽  
D. Rosen
1953 ◽  
Vol 31 (4) ◽  
pp. 448-456 ◽  
Author(s):  
G. R. Freeman ◽  
A. B. Van Cleave ◽  
J. W.T. Spinks

The oxidation of benzene to phenol in dilute aqueous solution by Co60 gamma rays and betatron X-rays (23 Mev. peak energy) is compared with the oxidationof Fe++ to Fe+++ under similar conditions. The ratio [Formula: see text]was the same for Co60 and betatron radiations. The yield for the Co60 radiations was about 10% greater than the apparent yield for the betatron radiations, the difference probably being attributable to dose determination at high energies (>1 Mev.). It is concluded that both reactions are independent of energy and dose rate over the ranges investigated.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Ryota Yamaguchi ◽  
Rika Tanaka ◽  
Mayu Maetani ◽  
Hiroyasu Tabe ◽  
Yusuke Yamada

Hydrogen peroxide (H2O2) in dilute aqueous solution can be efficiently captured by co-crystallisation with enantiomeric and racemic amino acids as evidenced by colourimetric titration and the single crystal X-ray structural...


1968 ◽  
Vol 17 (3) ◽  
pp. 354-355 ◽  
Author(s):  
Atsushi MIZUIKE ◽  
Shigeki KANO

1965 ◽  
Vol 18 (5) ◽  
pp. 651 ◽  
Author(s):  
RW Green ◽  
PW Alexander

The Schiff base, N-n-butylsalicylideneimine, extracts more than 99.8% beryllium into toluene from dilute aqueous solution. The distribution of beryllium has been studied in the pH range 5-13 and is discussed in terms of the several complex equilibria in aqueous solution. The stability constants of the complexes formed between beryllium and the Schiff base are log β1 11.1 and log β2 20.4, and the distribution coefficient of the bis complex is 550. Over most of the pH range, hydrolysis of the Be2+ ion competes with complex formation and provides a means of measuring the hydrolysis constants. They are for the reactions: Be(H2O)42+ ↔ 2H+ + Be(H2O)2(OH)2, log*β2 - 13.65; Be(H2O)42+ ↔ 3H+ + Be(H2O)(OH)3-, log*β3 -24.11.


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