scholarly journals Distribution of chromium, nickel, copper and zinc in the Al Zintan area, northwestern Libya

2018 ◽  
Vol 79 (2) ◽  
pp. 29-39
Author(s):  
Taher Alzarog ◽  
Boris Vakanjac ◽  
Ivana Jelic ◽  
Vakanjac Ristic ◽  
Zorana Naunovic ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Soil Sampling ◽  
Anthropogenic Sources ◽  
Rock Weathering ◽  
Chemical Analyses ◽  
Distribution Maps ◽  
Natural Processes ◽  
Nickel Copper ◽  
Farming Soil ◽  
Global Population

Global population is growing rapidly. As a result, increasingly large areas are being settled and farmed. This devastates soils and causes pollution by heavy metals and other components. Heavy metals in the environment originate from both natural and anthropogenic sources. Natural sources generally include rock weathering and the propagation of heavy metals, such as Cr and Ni, from ultrabasic rocks. These are natural processes that generally do not threaten human health. Anthropogenic sources include industry and inappropriate disposal of waste in the environment. In such cases concentrations of heavy metals can be harmful to people and other living beings. Al Zintan is a city located in northwestern Libya, on a plateau mainly built up of Cretaceous sediments. Since the 1980?s, nomadic population has rapidly been settling this area. As a result, a former part of the desert was transformed and is used for farming. Soil sampling at Al Zintan was conducted in 2017, across a 2?2 km grid. A total of 143 samples were collected from depths of about 30 cm. The samples weighed 2 to 2.5 kg and generally comprised sand with a clay component. A Niton Xl3t goldd+ instrument was used for chemical analyses, based on which GIS heavy-metal distribution maps were generated. The distribution of Cr, Ni, Cu and Zn is discussed on the paper.

scholarly journals Causes of variations of trace and rare earth elements concentration in lakes bottom sediments in the Bory Tucholskie National Park, Poland

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Mariusz Sojka ◽  
Adam Choiński ◽  
Mariusz Ptak ◽  
Marcin Siepak
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Spatial Variability ◽  
Bottom Sediments ◽  
National Park ◽  
Anthropogenic Sources ◽  
Geochemical Processes ◽  
Natural Processes ◽  
Sources Of Pollution ◽  
Geochemical Indices

AbstractThe objective of this study was to analyse spatial variability of the trace elements (TEs) and rare earth elements (REEs) concentration in lake bottom sediments in Bory Tucholskie National Park (BTNP); Poland. The following research questions were posed: which factors have a fundamental impact on the concentration and spatial variability of elements in bottom sediments, which of the elements can be considered as indicators of natural processes and which are related to anthropogenic sources. The research material was sediments samples collected from 19 lakes. The concentrations of 24 TEs and 14 REEs were determined. The analyses were carried out using the inductively coupled plasma mass spectrometry (ICP-QQQ). Cluster analysis and principal component analysis were used to determine the spatial variability of the TEs and REEs concentrations, indicate the elements that are the indicators of natural processes and identify potential anthropogenic sources of pollution. The geochemical background value (GBV) calculations were made using 13 different statistical methods. However, the contamination of bottom sediments was evaluated by means of the index of geo-accumulation, the enrichment factor, the pollution load index, and the metal pollution index. The BTNP area is unique because of its isolation from the inflow of pollutants from anthropogenic sources and a very stable land use structure over the last 200 years. This study shows high variability of TE and REE concentrations in lake sediments. The values of geochemical indices suggest low pollution of lakes bottom sediments. It was found that TEs originated mainly from geogenic sources. However, the concentrations of Li, Ni, Sc, Se, Be, Se, Ag, Re, Tl, Cd, Sb and U may be related to the impact of point sources found mainly in the Ostrowite Lake. Almost all REEs concentrations were strongly correlated and their presence was linked to with geochemical processes. The elements allowing to identify natural processes and anthropogenic pollution sources were Cr, Co, Cu, Ag, Cd, Zn, Bi, Re, Ba, Al and Rb in TEs group and Nd, Gd, Yb, Lu, Eu, Dy and Ce in REEs group. The analysis shows high spatial variability of TE and REE concentrations in lake sediments. The values of geochemical indices point to low pollution of lakes sediments. The anthropogenic sources only for two lakes had an impact on concentrations of selected TEs and REEs. The analyses allowed to identify elements among TEs and REEs documenting geochemical processes and those indicating anthropogenic sources of pollution.

scholarly journals Environmental Risk Assessment of Petroleum Activities in Surface Sediments, Suez Gulf, Egypt

2021 ◽  
Vol 9 (5) ◽  
pp. 473
Author(s):  
Magda M. Abou El-Safa ◽  
Mohamed Gad ◽  
Ebrahem M. Eid ◽  
Ashwaq M. Alnemari ◽  
Mohammed H. Almarshadi ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Heavy Metal ◽  
Surface Sediment ◽  
Surface Sediments ◽  
Surf Zone ◽  
Risk Index ◽  
Negative Relationship ◽  
Anthropogenic Sources ◽  
Suez Gulf

The present study focuses on the risk assessment of heavy metal contamination in aquatic ecosystems by evaluating the current situation of heavy metals in seven locations (North Amer El Bahry, Amer, Bakr, Ras Gharib, July Water Floud, Ras Shokeir, and El Marageen) along the Suez Gulf coast that are well-known representative sites for petroleum activities in Egypt. One hundred and forty-six samples of surface sediments were carefully collected from twenty-seven profiles in the intertidal and surf zone. The hydrochemical parameters, such as pH and salinity (S‰), were measured during sample collection. The mineralogy study was carried out by an X-ray diffractometer (XRD), and the concentrations of Al, Mn, Fe, Cr, Cu, Co, Zn, Cd, and Pb were determined using inductively coupled plasma mass spectra (ICP-MS). The ecological risks of heavy metals were assessed by applying the contamination factor (CF), enrichment factor (EF), geoaccumulation index (Igeo), pollution load index (PLI), and potential ecological risk index (RI). The mineralogical composition mainly comprised quartz, dolomites, calcite, and feldspars. The average concentrations of the detected heavy metals, in descending order, were Al > Fe > Mn > Cr > Pb > Cu > Zn > Ni > Co > Cd. A non-significant or negative relationship between the heavy metal concentration in the samples and their textural grain size characteristics was observed. The coastal surface sediment samples of the Suez Gulf contained lower concentrations of heavy metals than those published for other regions in the world with petroleum activities, except for Al, Mn, and Cr. The results for the CF, EF, and Igeo showed that Cd and Pb have severe enrichment in surface sediment and are derived from anthropogenic sources, while Al, Mn, Fe, Cr, Co, Ni, Cu, and Zn originate from natural sources. By comparison, the PLI and RI results indicate that the North Amer El Bahry and July Water Floud are considered polluted areas due to their petroleum activities. The continuous monitoring and assessment of pollutants in the Suez Gulf will aid in the protection of the environment and the sustainability of resources.

scholarly journals Little Akaki River sediment enrichment with heavy metals, pollution load and potential ecological risks in downstream, Central Ethiopia

2020 ◽  
Vol 9 (1) ◽  
Author(s):  
Deshu Mamo Mekuria ◽  
Alemnew Berhanu Kassegne ◽  
Seyoum Leta Asfaw
Keyword(s):  
Heavy Metals ◽  
River Sediment ◽  
Addis Ababa ◽  
Biological Effects ◽  
Sediment Quality ◽  
Contamination Factor ◽  
Anthropogenic Sources ◽  
Ecological Risks ◽  
Pollution Load ◽  
Akaki River

Abstract Addis Ababa City’s river ecosystem is under extreme pressure as a result of inappropriate practices of dumping domestic and industrial wastes; thus, threatening its ability to maintain basic ecological, social and economic functions. Little Akaki River which drains through Addis Ababa City receives inorganic and organic pollutants from various anthropogenic sources. Most of inorganic pollutants such as toxic heavy metals released into the river are eventually adsorbed and settle in the sediment. The objective of this study was to evaluate the enrichment levels, pollution load and ecological risks of selected heavy metals (Zn, Cr, Cd and Pb) using various indices. The mean concentrations of heavy metals in Little Akaki River sediment were: Zn (78.96 ± 0.021–235.2 ± 0.001 mg/kg); Cr (2.19 ± 0.014–440.8 ± 0.003 mg/kg); Cd (2.09 ± 0.001–4.16 ± 0.0001 mg/kg) and Pb (30.92 ± 0.018–596.4 ± 0.066 mg/kg). Enrichment factor values indicated that sediments were moderate to significantly enriched with Zn and Cr; moderate to very highly enriched with Pb, and very highly enriched in all sampled sites with Cd. Geo-accumulation index and contamination factor values indicated that the sediments were moderate to very highly contaminated with toxic Cd and Pb. The decreasing order of pollution load index (PLI) in downstream was: (S9) > (S4) > (S8) > (S3) > (S6) > (S10) > (S5) > (S2) > (S7) > (S1). PLI and hierarchical cluster analysis revealed that the highest pollution load occurred in the lower course of the river (S9) which may be due to metals inputs from anthropogenic sources. The ecological risk (RI = 350.62) suggested that the contaminated Little Akaki River sediment can pose considerable ecological risks of pollution. The concentrations of Zn, Cr, Cd and Pb in Little Akaki River sediment surpassed eco-toxicological guideline limits of USEPA (threshold effect concentration) and CCME (Interim Sediment Quality Guidelines). Thus, the contaminated sediments can pose adverse biological effects on sediment dwelling organisms.

Systematic Evaluation of Precision Farming Soil Sampling Requirements

2015 ◽  
pp. 253-265 ◽  
Author(s):  
David E. Clay ◽  
C. G. Carlson ◽  
J. Chang ◽  
S. A. Clay ◽  
D. D. Malo ◽  
...  
Keyword(s):  
Precision Farming ◽  
Soil Sampling ◽  
Systematic Evaluation ◽  
Farming Soil

scholarly journals Environmental impact of the Midia Port - Black Sea (Romania), on the coastal sediment quality

2016 ◽  
Vol 8 (1) ◽  
pp. 174-194 ◽  
Author(s):  
Irina Catianis ◽  
Constantin Ungureanu ◽  
Luca Magagnini ◽  
Elisa Ulazzi ◽  
Tiziana Campisi ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Oil Spills ◽  
Environmental Concern ◽  
Sediment Quality ◽  
Industrial Wastes ◽  
Anthropogenic Sources ◽  
Water Runoff ◽  
Quality Of Water ◽  
Wide Range ◽  
The Impact

AbstractThe aim of the study was to evaluate the impact of potential pollution sources, mainly from the upstream anthropogenic sources and port-related activities. The in-vestigated area covered a wide range of anthropogenic im-pacts (e.g., industrial wastes, storm water runoff, acciden-tal oil spills, intentional discharges and shipping activities). The quality of water and Sediments was assessed us-ing Standard methods, as physical-chemical parameters, chemistry and biology (microbiology, ecotoxicology) aim-ing to figure the level of pollution and the effect of port-related activities. Seawater quality results agreed generally with environmental Standards. Though, in some samples the concentrations of sulphates (mg/1) and heavy metals (μg/1), as B, As and Se exceeded the recommended lim-its, without posing a serious environmental concern. Most of the surface sediment samples contain critical levels of hydrocarbons (C>12), (mg/kg), polycyclic aromatic hydrocarbons (ng/g) and polychlorobiphenyls (ng/g). For some heavy metals (mg/kg), exchangeable concentrations were found to be very close or above the regulations. The signifi-cance of this study is incontestable taking into account the lack of previous relevant historical data of this area. In this sense, it was possible to indicate, in general, good environmental conditions, despite the industrial and concentrated local port-related activities in the investigated area.

scholarly journals Estimation of the Concentration of Some Heavy Metals in Groundwater in Rutba City

2021 ◽  
Vol 904 (1) ◽  
pp. 012009
Author(s):  
A W Abd Byty ◽  
M A Gharbi ◽  
A H Assaf
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Large Scale ◽  
Toxic Metal ◽  
Scale Production ◽  
Future Health ◽  
Distribution Maps ◽  
Guideline Values

Abstract Toxic metal pollutants in groundwater should be identified to prevent future health risks. In this paper, the presence of heavy metals in groundwater in the western region of Iraq was investigated. The heavy metals concentrations, including Ni2+, Co2+, Zn2+, Pb2+, Cr3+, Cd2+, As3+ and Hg2+ were explored in twenty selected aquifers near Rutba City and the results were presented as spatial distribution maps. Findings indicate that contamination with the investigated heavy metal ions possesses a serious threat to the study area’s groundwater quality when compared to WHO and IEPA guideline values. Thus, a new approach to remove or adsorb heavy metal ions can be developed for large-scale production and the safe use of these aquifers water. Results revealed that the highest concentrations in mg/L1 of 2.312 in w19, 1.098 in w2, 5.78 in w17, 0.292 in w9, 3.349 in w5, 0.32 in w13, 0.074 in w11 and 5.622 in w1 for Zn2+, Cr3+, As3+, Pb2+, Ni2+, Co2+, Cd2+ and Hg2+ were recorded, respectively.

scholarly journals GEOCHEMISTRY AND ENVIRONMENTAL ASSESSMENT OF HEAVY METALS IN SURFACE SOIL IN AL-HAWIJA, SOUTHWEST KIRKUK

2020 ◽  
Vol 53 (2E) ◽  
pp. 36-61
Author(s):  
Ahmed Al-Obeidi
Keyword(s):  
Heavy Metals ◽  
Soil Pollution ◽  
Ecological Risk ◽  
Inductively Coupled Plasma ◽  
Surface Soil ◽  
Risk Index ◽  
Size Fraction ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Anthropogenic Sources

Soil pollution adversely affects the safety and health of the human being. The main objective of the study is to determine the concentrations of heavy metals (As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb and Zn) in surface soil in Al-Hawija, southwestern Kirkuk. Twenty-one samples were collected and analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) to measure the content of heavy metals and assess the soil pollution by using the contamination factor, degree of contamination, geoaccumulation index, pollution load index and ecological risk index (RI). The results indicate that there is high pollution by lead, chromium and copper (78.8, 87.4 and 53.8 mg/kg) respectively, in industrial areas due to anthropogenic sources with the presence of significant ecological risk (Er) of the lead (116) in site S7, due to its high concentrations, while size fraction analysis indicated that all heavy metals are concentrated in the fine parts as a result of adsorption processes by clay minerals.

scholarly journals Ecological Indices of the Heavy Metals in the Soil of Shewasoor Sub-Basin, Kirkuk NE Iraq

2018 ◽  
Vol 3 (1) ◽  
Author(s):  
Mustafa Jamal Akbar ◽  
Omer Sabah Al-Tamimi
Keyword(s):  
Heavy Metals ◽  
Cancer Risk ◽  
Risk Index ◽  
Sediment Quality ◽  
Hazard Index ◽  
Soil Samples ◽  
Geochemical Background ◽  
Ecological Indices ◽  
Distribution Maps ◽  
Contamination Levels

The current research aimed to assess contamination levels in the soil of study area by heavy metals. Eight sites were selected for the collection of soil samples. The eight heavy metals namely As, Pb, Cd, Cr, Co, Cu, Ni, and Zn were analyzed in each soil samples by using ICP-MS technology. The measured concentrations of heavy metals were compared with Geochemical Background values, EPA Sediment Quality Guidelines, Ecological Screening values, and WHO Guidelines. The spatial distribution maps of ecological indices were performed using ArcGIS software (version 10.2), which provides an idea of the geographical distribution of heavy metals contamination levels in the soil of Shewasoor sub-basin. The soil contamination by heavy metals assessed using Potential Ecological Risk Index (RI), Nemerow Pollution Index (P_N), Hazard Index (HI), and Cancer Risk. The RI showed there are high risk of heavy metals in soil and according to P_N the soil has been moderate to severely contaminated by heavy metals. The hazard index of all soil samples was within acceptable range for adults and showed unacceptable risk for children. While the total cancer risk values of As and Cr were within acceptable limits, whereas of Pb, Cd, Co, and Ni were lower than acceptable risk range at all sites for adults and children. Ecological indices which are used to assess the contamination levels in the soil by heavy metals refers to the soil of study area was contaminated moderate to heavily by heavy metals, this attributed to the natural and anthropogenic pollution sources around and within the study area.

A Comparative Study on the Capability of Tree Species in Urban Afforestation to Accumulate Heavy Metals

2021 ◽  
Vol 9 (1) ◽  
pp. 79-90
Author(s):  
Samar Mortazavi ◽  
◽  
Masoud Hatamimanesh ◽  
Farzad Veysanlou ◽  
◽  
...  
Keyword(s):  
Heavy Metals ◽  
Tree Species ◽  
Metal Accumulation ◽  
Climatic Conditions ◽  
Heavy Metal Accumulation ◽  
Toxicity Potential ◽  
Nickel Copper ◽  
Accumulation Index ◽  
Copper Zinc ◽  
Lead Nickel

Background: The present study investigated the concentrations of lead, nickel, copper, zinc, their toxicity potential, and their ecological hazard in surface soils of Hamedan City, Iran. Also, using the Bio-concentration Factor (BCF), concentration Comprehensive Bio-concentration Index (CBCI), and Metal Accumulation Index (MAI), was evaluated the ability of some tree and shrub species to absorb heavy metals in soil and air. Methods: Sampling of leaves of nine tree species and shrubs (plane, acacia, elm, willow, mulberry, ash, redbud, pine, and cypress) was performed in six stations. After preparation and acid digestion of the samples, the concentrations of heavy metals were determined using an atomic absorption spectrometer. Results: The trend of changes in soil heavy Mean±SD metal concentrations was in the order of nickel> zinc> copper> lead in the amounts of 61.41±11.34˃ 43.04±14.4˃ 42.87±8.36˃ 18.77±6.51 mg/kg. Evaluation of acute toxicity potential indicators and ecological risk of heavy metals indicated low soil pollution status. Findings of BCF, CBCI, and MAI ndices in the leaves of the species showed that the highest levels of BCF of heavy metals, i.e., zinc, copper, lead, and nickel, were in willow, elm, cypress, and pine species, respectively. Results show that heavy metal accumulation in different species. Conclusion: Depends on soil type, tree species, climatic conditions, type of pollutant source, species age, and other factors. In this study, elm and acacia have the highest ability to absorb heavy metals from soil and air.

scholarly journals Data Analysis of Beach Sands’ Chemical Analysis Using Multivariate Statistical Methods and Heavy Metal Distribution Maps: The Case of Moonlight Beach Sands, Kemer, Antalya, Turkey

Symmetry ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 1538 ◽  
Author(s):  
Fusun Yalcin
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Data Analysis ◽  
Chemical Analysis ◽  
Statistical Methods ◽  
Risk Index ◽  
Multivariate Statistical Methods ◽  
Multivariate Statistical ◽  
Distribution Maps ◽  
Beach Sands

Multivariate statistical methods are widely used in several disciplines of fundamental sciences. In the present study, the data analysis of the chemical analysis of the sands of Moonlight Beach in the Kemer region was examined using multivariate statistical methods. This study consists of three parts. The multivariate statistical analysis tests were described in the first part, then the pollution indexes were studied in the second part. Finally, the distribution maps of the chemical analyses and pollution indexes were generated using the obtained data. The heavy metals were mostly observed in location K1, while they were sorted as follows based on their concentrations: Mg > Fe > Al > Ti > Sr > Mn > Cr > Ni > Zn > Zr > Cu > Rb. Also, strong positive correlations were found between Si, Fe, Al, K, Ti, P. According to the results of factor analysis, it was found that four factors explained 83.5% of the total variance. On the other hand, the coefficient of determination (R2) was calculated as 63.6% in the regression model. Each unit increase in the value of Ti leads to an increase of 0.022 units in the value of Si. Potential Ecological Risk Index analysis results (RI < 150) revealed that the study area had no risk. However, the locations around Moonlight Beach are under risk in terms of Enrichment Factor and Contamination Factor values. The index values of heavy metals in the anomaly maps and their densities were found to be successful; and higher densities were observed based on heavy metal anomalies.

Sign in / Sign up

Export Citation Format

Share Document