scholarly journals Degradation of an organophosphorus insecticide in aqueous medium by Electro-Fenton process

2021 ◽  
pp. 63-72
Author(s):  
Mirvet Assassi ◽  
Farid Madjene ◽  
Abdeltif Amrane
Keyword(s):  
Biological Treatment ◽  
Supporting Electrolyte ◽  
Operating Conditions ◽  
Organophosphorus Insecticide ◽  
Current Intensity ◽  
Fenton Process ◽  
Factors Affecting ◽  
Incomplete Removal ◽  
Temperature Solution ◽  
Major Factors

This work proposes the remediation of toxic and/or refractory pollutants, such as the organophosphorus insecticide (Phosmet) which cannot be completely degraded by conventional methods like biological treatment, adsorption, flocculation, electro-flocculation, reverse osmosis, ultrafiltration, coagulation. However, these techniques have some disadvantages such as incomplete removal, therefore, the Electro-Fenton process was used. The major factors affecting the removal of Phosmet, namely the current intensity, catalyst concentration (Fe3+), temperature solution, nature of the electrolytes and oxygenation duration of the solution were studied in this work. The optimal operating conditions appeared to be: current intensity 200 mA, 0.5 mmol L-1 of Fe3+, T= 20?C, pH =3 using Na2SO4 (50 mmol L-1) as supporting electrolyte and an oxygen supply throughout all the experiments (120 min). Under these optimal conditions, the removal efficiency of the phosmet was 88%.

Electrochemical removal of carbamazepine in water with Ti/PbO2 cylindrical mesh anode

2015 ◽  
Vol 73 (5) ◽  
pp. 1155-1165 ◽  
Author(s):  
J. D. García-Espinoza ◽  
P. Gortáres-Moroyoqui ◽  
M. T. Orta-Ledesma ◽  
P. Drogui ◽  
P. Mijaylova-Nacheva
Keyword(s):  
Supporting Electrolyte ◽  
Oxygen Demand ◽  
Electrochemical Reactor ◽  
Operating Conditions ◽  
Current Intensity ◽  
Oxygen Flux ◽  
Order Kinetic ◽  
Electrolysis Time ◽  
Direct Oxidation

Carbamazepine (CBZ) is one of the most frequently detected organic compounds in the aquatic environment. Due to its bio-persistence and toxicity for humans and the environment its removal has become an important issue. The performance of the electrochemical oxidation process and in situ production of reactive oxygen species (ROS), such as O3 and H2O2, for CBZ removal have been studied using Ti/PbO2 cylindrical mesh anode in the presence of Na2SO4 as supporting electrolyte in a batch electrochemical reactor. In this integrated process, direct oxidation at anode and indirect oxidation by in situ electrogenerated ROS can occur simultaneously. The effect of several factors such as electrolysis time, current intensity, initial pH and oxygen flux was investigated by means of an experimental design methodology, using a 24 factorial matrix. CBZ removal of 83.93% was obtained and the most influential parameters turned out to be electrolysis time, current intensity and oxygen flux. Later, the optimal experimental values for CBZ degradation were obtained by means of a central composite design. The best operating conditions, analyzed by Design Expert® software, are the following: 110 min of electrolysis at 3.0 A, pH = 7.05 and 2.8 L O2/min. Under these optimal conditions, the model prediction (82.44%) fits very well with the experimental response (83.90 ± 0.8%). Furthermore, chemical oxygen demand decrease was quantified. Our results illustrated significant removal efficiency for the CBZ in optimized condition with second order kinetic reaction.

Effect of SO2 Removal on the Biodegradability of Arbiso Spent Sulphite Liquor

1972 ◽  
Vol 7 (1) ◽  
pp. 77-83
Author(s):  
K.S. Ng ◽  
J.E. Jajic ◽  
D.F. Manchester ◽  
Y.K. Ng
Keyword(s):  
Operating Conditions ◽  
Biological Degradation ◽  
Lime Treatment ◽  
Factors Affecting ◽  
So2 Removal ◽  
Spent Sulphite Liquor ◽  
Initial Ph ◽  
Paper Company ◽  
Major Factors ◽  
Spent Liquor

Abstract The spent sulphite liquor derived from Abitibi Paper Company, Iroquois Falls Mills Arbiso process contained about 11.3% dissolved solid, 0.52% (W/V) residual SO2 and had a low pH of 4.3. The COD of the liquor was about 109,000 ppm and BOD5 26,000 ppm. The objective of the study was to investigate the technical feasibility of utilizing biodegradation to reduce the BOD5 of the spent liquor to acceptable levels. Upon first analysis, it appeared that the liquor would be amenable to biological degradation because of the presence of wood sugars. However, biological oxidation was retarded due to the presence of SO2. The maximum SO2 concentration tolerated by the microbes was about 0.32% (W/V). Boiling and lime treatment were found to be effective in reducing the SO2. Other major factors affecting biological activity were initial pH adjustment and nutrient addition. Nutrients required and optimal operating conditions are discussed. Under optimal conditions, a batch biological system was capable of removing 60% BOD5, in 11 days and 80% BOD5 in 16 days.

Investigations of Road Wear Caused by Studded Tires

2014 ◽  
Vol 42 (1) ◽  
pp. 2-15
Author(s):  
Johannes Gültlinger ◽  
Frank Gauterin ◽  
Christian Brandau ◽  
Jan Schlittenhard ◽  
Burkhard Wies
Keyword(s):  
Traffic Safety ◽  
Test Bench ◽  
Operating Conditions ◽  
Test Method ◽  
Analytical Models ◽  
The Road ◽  
Driving Speed ◽  
Major Factors ◽  
Tire Friction ◽  
Variable Operating Conditions

ABSTRACT The use of studded tires has been a subject of controversy from the time they came into market. While studded tires contribute to traffic safety under severe winter conditions by increasing tire friction on icy roads, they also cause damage to the road surface when running on bare roads. Consequently, one of the main challenges in studded tire development is to reduce road wear while still ensuring a good grip on ice. Therefore, a research project was initiated to gain understanding about the mechanisms and influencing parameters involved in road wear by studded tires. A test method using the institute's internal drum test bench was developed. Furthermore, mechanisms causing road wear by studded tires were derived from basic analytical models. These mechanisms were used to identify the main parameters influencing road wear by studded tires. Using experimental results obtained with the test method developed, the expected influences were verified. Vehicle driving speed and stud mass were found to be major factors influencing road wear. This can be explained by the stud impact as a dominant mechanism. By means of the test method presented, quantified and comparable data for road wear caused by studded tires under controllable conditions can be obtained. The mechanisms allow predicting the influence of tire construction and variable operating conditions on road wear.

scholarly journals Relationship between Land Use Mix and Walking Choice in High-Density Cities: A Review of Walking in Seoul, South Korea

2021 ◽  
Vol 13 (2) ◽  
pp. 810
Author(s):  
Eun Yeong Seong ◽  
Nam Hwi Lee ◽  
Chang Gyu Choi
Keyword(s):  
Land Use ◽  
Neighborhood Environment ◽  
Single Family ◽  
Housing Type ◽  
General Belief ◽  
Factors Affecting ◽  
Land Use Mix ◽  
Family Housing ◽  
Mixed Land Use ◽  
Major Factors

This study confirmed the general belief of urban planners that mixed land use promotes walking in Seoul, a metropolis in East Asia, by analyzing the effect of mixed land use on the travel mode choice of housewives and unemployed people who make non-commuting trips on weekdays. Using binomial logistic regression of commuting data, it was found that the more mixed a neighborhood environment’s uses are, the more the pedestrians prefer to walk rather than drive. The nonlinear relationship between the land use mix index and the choice to walk was also confirmed. Although mixed land use in neighborhoods increased the probability of residents choosing walking over using cars, when the degree of complexity increased above a certain level, the opposite effect was observed. As the density of commercial areas increased, the probability of selecting walking increased. In addition to locational characteristics, income and housing type were also major factors affecting the choice to walk; i.e., when the residents’ neighborhood environment was controlled for higher income and living in an apartment rather than multi-family or single-family housing, they were more likely to choose driving over walking.

Impact of climatic conditions on the parameters of failure flow of military vehicles

2021 ◽  
pp. 095440702110202
Author(s):  
Nikolaj Dobrzinskij ◽  
Algimantas Fedaravicius ◽  
Kestutis Pilkauskas ◽  
Egidijus Slizys
Keyword(s):  
Climatic Factors ◽  
Armed Forces ◽  
Climatic Conditions ◽  
Operating Conditions ◽  
Technical Equipment ◽  
Factors Affecting ◽  
Military Vehicles ◽  
Equipment Reliability ◽  
Number Of Factors ◽  
The Impact

Relevance of the article is based on participation of armed forces in various operations and exercises, where reliability of machinery is one of the most important factors. Transportation of soldiers as well as completion of variety of tasks is ensured by properly functioning technical equipment. Reliability of military vehicles – armoured SISU E13TP Finnish built and HMMWV M1025 USA built were selected as the object of the article. Impact of climatic conditions on reliability of the vehicles exploited in southwestern part of the Atlantic continental forest area is researched by a case study of the vehicles exploitation under conditions of the climate of Lithuania. Reliability of military vehicles depends on a number of factors such as properties of the vehicles and external conditions of their operation. Their systems and mechanisms are influenced by a number of factors that cause different failures. Climatic conditions represent one of the factors of operating load which is directly dependent on the climate zone. Therefore, assessment of the reliability is started with the analysis of climatic factors affecting operating conditions of the vehicles. Relationship between the impact of climatic factors and failure flow of the vehicles is presented and discussed.

scholarly journals Is it possible to estimate the need for surgical management in patients with a tubo-ovarian abscess at admission? A retrospective long-term analysis

2021 ◽  
Vol 18 (1) ◽  
Author(s):  
Murat Gözüküçük ◽  
Esra Gülen Yıldız
Keyword(s):  
Surgical Treatment ◽  
Antibiotic Therapy ◽  
Treatment Failure ◽  
Medical Treatment ◽  
Length Of Hospital Stay ◽  
Treatment Modalities ◽  
Laboratory Findings ◽  
Factors Affecting ◽  
Laboratory Infection ◽  
Major Factors

Abstract Background This study aimed to determine the possible prognostic factors correlated with the treatment modalities of tubo-ovarian abscesses (TOAs) and thus to assess whether the need for surgery was predictable at the time of initial admission. Materials and methods Between January 2012 and December 2019, patients who were hospitalized with a TOA in our clinic were retrospectively recruited. The age of the patients, clinical and sonographic presentation, pelvic inflammatory risk factors, antibiotic therapy, applied surgical treatment, laboratory infection parameters, and length of hospital stay were recorded. Results The records of 115 patients hospitalized with a prediagnosis of TOA were reviewed for the current study. After hospitalization, TOA was ruled out in 19 patients, and data regarding 96 patients was included for analysis. Twenty-eight (29.2%) patients underwent surgical treatment due to failed antibiotic therapy. Sixty-eight (70.8%) were successfully treated with parenteral antibiotics. Medical treatment failure and need for surgery were more common in patients with a large abscess (volume, > 40 cm3, or diameter, > 5 cm). The group treated by surgical intervention was statistically older than the patients receiving medical treatment (p < 0.05). Conclusions Although the treatment in TOA may vary according to clinical, sonographic, and laboratory findings; age of patients, the abscess size, and volume were seen as the major factors affecting medical treatment failure. Moreover, TOA treatment should be planned on a more individual basis.

scholarly journals Progress in Research on Carbon Nanotubes Reinforced Cementitious Composites

2015 ◽  
Vol 2015 ◽  
pp. 1-16 ◽  
Author(s):  
Qinghua Li ◽  
Jintao Liu ◽  
Shilang Xu
Keyword(s):  
Carbon Nanotubes ◽  
Large Scale ◽  
High Strength ◽  
Cementitious Composites ◽  
Scale Production ◽  
Multiwalled Carbon ◽  
Factors Affecting ◽  
Environment And Health ◽  
Research Activities ◽  
Major Factors

As one-dimensional (1D) nanofiber, carbon nanotubes (CNTs) have been widely used to improve the performance of nanocomposites due to their high strength, small dimensions, and remarkable physical properties. Progress in the field of CNTs presents a potential opportunity to enhance cementitious composites at the nanoscale. In this review, current research activities and key advances on multiwalled carbon nanotubes (MWCNTs) reinforced cementitious composites are summarized, including the effect of MWCNTs on modulus of elasticity, porosity, fracture, and mechanical and microstructure properties of cement-based composites. The issues about the improvement mechanisms, MWCNTs dispersion methods, and the major factors affecting the mechanical properties of composites are discussed. In addition, large-scale production methods of MWCNTs and the effects of CNTs on environment and health are also summarized.

Evaluation of Si Coating on Ferritic Steels by CVD-FBR Technology in Steam Oxidation

2009 ◽  
Vol 289-292 ◽  
pp. 413-420 ◽  
Author(s):  
F.J. Bolívar ◽  
L. Sánchez ◽  
M.P. Hierro ◽  
F.J. Pérez
Keyword(s):  
Power Plants ◽  
Protective Coatings ◽  
Steam Oxidation ◽  
Steam Turbines ◽  
X Ray Diffraction ◽  
Steam Power ◽  
Factors Affecting ◽  
Steam Power Plants ◽  
Temperature And Pressure ◽  
Major Factors

The development of new power generation plants firing fossil fuel is aiming at achieving higher thermal efficiencies of the energy conversion process. The major factors affecting the efficiency of the conventional steam power plants are the temperature and, to a lesser extent, the pressure of the steam entering the turbine. The increased operating temperature and pressure require new materials that have major oxidation resistance. Due to this problem, in the last years numerous studies have been conducted in order to develop new coatings to enhance the resistance of steels with chromium contents between 9 and 12% wt against steam oxidation in order to allow operation of steam turbines at 650 0C. In this study, Si protective coatings were deposited by CVD-FBR on ferritic steel P-91. These type of coatings have shown to be protective at 650 0C under steam for at least 3000 hours of laboratory steam exposure under atmospheric pressure. Morphology and composition of coatings were characterized by different techniques, such as scanning electron microscopy (SEM), electron probe microanalysis, and X-ray diffraction (XRD). The results show a substantial increase of steam oxidation protection afforded by Si coating by CVD-FBR process.

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