scholarly journals A Review on Expired Drug-Based Corrosion Inhibitors: Chemical Composition, Structural Effects, Inhibition Mechanism, Current Challenges, and Future Prospects

2021 ◽  
Vol 21 (5) ◽  
pp. 1316
Author(s):  
Muhamad Jalil Baari ◽  
Carla Wulandari Sabandar
Keyword(s):  
Chemical Composition ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Inhibition Mechanism ◽  
Future Prospects ◽  
Optimum Conditions ◽  
Structural Effects ◽  
Iron Copper ◽  
Treatment Conditions ◽  
Expired Drug

This comprehensive review highlighted how the expired drugs manage corrosion reactions on metal/alloy surfaces, especially types of carbon/mild steel, Sabic iron, copper, and aluminium in NaCl or acid solution. Several types of expired drugs and the optimum conditions presented in this review were summarized from relevant studies. The performance of expired drugs which covers inhibition efficiency, inhibition mechanisms, and metal surface analysis was informed. The contribution of the chemical composition, molecular structure, compatible treatment conditions, and some corrosion analysis methods were mentioned. Current challenges and future prospects were also discussed for further investigations and developments to obtain superior inhibitors and save the environment.

Corrosion inhibition of some azole derivatives on carbon steel in hydrochloric acid solution

2014 ◽  
Vol 61 (5) ◽  
pp. 300-306 ◽  
Author(s):  
B.P. Markhali ◽  
R. Naderi ◽  
M. Sayebani ◽  
M. Mahdavian
Keyword(s):  
Carbon Steel ◽  
Hydrochloric Acid ◽  
Organic Compounds ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Acid Corrosion ◽  
Molecular Structures ◽  
Inhibition Mechanism ◽  
Content Type

Purpose – The purpose of this paper is investigate the inhibition efficiency of three similar bi-cyclic organic compounds, namely, benzimidazole (BI), benzotriazole (BTAH) and benzothiazole (BTH) on carbon steel in 1 M hydrochloric acid (HCl) solution. Organic inhibitors are widely used to protect metals in acidic media. Among abundant suggestions for acid corrosion inhibitors, azole compounds have gained attention. Design/methodology/approach – The inhibition efficiency of the three organic compounds was investigated using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Findings – Superiorities of BTH and BTAH corrosion inhibitors were shown by EIS data and polarization curves. Moreover, the results revealed that BTAH and BTH can function as effective mixed-type adsorptive inhibitors, whereas no inhibition behavior was observed for BI. Both BTAH and BTH obeyed Longmuir adsorption isotherm. The results obtained from this isotherm showed that both inhibitors adsorbed on the specimen surface physically and chemically. The difference in inhibition efficiencies of BTAH, BTH and BI was related to the presence of nitrogen and sulfur hetero atoms on their molecular structures. Originality/value – This study evaluated inhibition efficiency of BI, BTAH and BTH using electrochemical methods. In addition, the study attempted to find inhibition mechanism of the inhibitors and to find modes of adsorption of the inhibitors, correlating effects of heteroatoms and inhibition efficiency.

SYNTHESIS OF CORROSION INHIBITORS WITH THE USE OF BANANA STEM EXTRACTS (MUSA ACUMINATA)

2020 ◽  
Vol 5 (2) ◽  
pp. 9-16
Author(s):  
K.F. Oyedeko ◽  
◽  
HEPHIZIBAH Olaniyi
Keyword(s):  
Carbon Steel ◽  
Steel Surface ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Low Carbon Steel ◽  
Musa Acuminata ◽  
Inhibition Mechanism ◽  
Low Carbon ◽  
Green Inhibitors ◽  
Carbon Steel Surface

Corrosion inhibitors are vital in industry for protection and prevention of surfaces from corrosion attack. There is need to have green inhibitors that are environmentally friendly and not hazardous to use. Extract from stem of banana (Musa species: Musa-Acuminata) was considered as green inhibitors. Extracts from the stem of banana was subjected to physico-chemical, phytochemical screening and corrosion test using gravimetric measurement with a low carbon steel flat bar coupon. The corrosion inhibition mechanism of the plant extract on the low carbon steel surface in 1M HCl and H2SO4 acid at different temperatures (30 to 60oC) showed that the inhibition efficiency (IE) increased with increase in concentration of the inhibitor (15ml to 75ml) but decreased with increase in temperature (303K to 333K) for the inhibitors throughout the test period, indicating a physisorption of extract on the carbon steel surface. The adsorption on the low carbon steel surface agrees with the Langmuir adsorption isotherm. The inhibition efficiency of the extract was above 50% in both media with banana extract having 69.55% inhibition efficiency in H2SO4 solution

scholarly journals STUDYING THE FACTORS EFFECTING THE PRODUCTION OF OKRA PROTEIN CONCENTRATE AND ISOLATE AND THEIR THERMAL PROPERTIES

2016 ◽  
Vol 47 (6) ◽  
Author(s):  
Kareem & Shakir
Keyword(s):  
Thermal Properties ◽  
Chemical Composition ◽  
Protein Denaturation ◽  
Protein Isolate ◽  
Extraction Time ◽  
Abelmoschus Esculentus ◽  
Protein Concentrate ◽  
Optimum Conditions ◽  
Precipitation Ph ◽  
Concentrate Preparation

The current study was included the use of okra seeds (Abelmoschus esculentus) for preparation of Defatted Okra Powder (DOP), Okra Protein Concentrate (OPC) and Okra Protein Isolate (OPI). Three methods were used to identify the best one for protein concentrate preparation . The concentrate with 72.1% protein was prepared by removal of seed peel, ground, defatting and treated with ethanol. The optimum conditions for  protein isolate preparation were 1:40 (water: DOP), extraction time of 75 minutes, extraction pH 9.0 and the precipitation pH was  4.0. This study also investigated the chemical composition to products that were 50.8,72.1,91.2% protein ,0.88,0.86,0.32 % fat ,8.45,9.94,2.67% ash and 35.23,12.37,3.26% carbohydrates For each of DOP ,OPC and OPI respectively. The amount of energy required for protein denaturation were 1.193, 0.5325, 0.236 J / g for DOP , OPC and OPI respectively.

scholarly journals Newly Synthesized N-Substituted Thiosemicarbazone as a Potential Corrosion Inhibitor for Mild Steel in 1 M HCl

2019 ◽  
Vol 7 (4.14) ◽  
pp. 168
Author(s):  
N Z. Nor Hashim ◽  
K Kassim ◽  
F H. Zaidon
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Potentiodynamic Polarization ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Langmuir Adsorption ◽  
Before And After ◽  
Ft Ir ◽  
L1 And L2

Two N-substituted thiosemicarbazone derivatives namely as 2-(4-chlorobenzylidene)-N-phenylhydrazinecarbothioamide and 2-benzylidene-N-phenylhydrazinecarbothioamide (L1 and L2, respectively) have been tested as corrosion inhibitors on mild steel in 1 M HCl. The ligands were synthesized and investigated using potentiodynamic polarization (PD) and electrochemical impedance spectroscopy (EIS).  The obtained results indicated that inhibition efficiency, (IE, %) L1 increased with increasing inhibitor concentrations which behaved as a good corrosion inhibitor compared to L2. The synthesized ligands were successfully characterized by melting point, elemental analysis (C, H, N, and S), Fourier-transform infrared spectroscopy (FT-IR) and NMR (1H and 13C) spectroscopy. The excellent inhibition effectiveness for both compounds on mild steel before and after immersion in 1 M HCl solution containing 40 ppm of L1 and L2 were also verified by scanning electron microscope (SEM). Based on potentiodynamic polarization results, it can be concluded that all investigated compounds are mixed-type inhibitors and obey the Langmuir adsorption isotherm. 

scholarly journals AN INVESTIGATION ON CORROSION INHIBITORS FOR STEEL IN ETHANOL FUEL BLEND

2018 ◽  
Vol 56 (3B) ◽  
pp. 11
Author(s):  
Nguyễn Đăng Nam
Keyword(s):  
Corrosion Inhibitors ◽  
Protective Layer ◽  
Inhibition Mechanism ◽  
Ethanol Fuel ◽  
Fuel Blend

Cerium (III) chloride, sodium 4-hydroxycinnamate, and cerium 4-hydroxycinnamate have been successfully characterized as effective anodic, cathodic, and mixed inhibitors for steel in ethanol fuel blend by electrochemical and surface analyses. Electrochemical and surface analyses indicate that good inhibition performances are due to the formation of protective layer as a result of adsorption between the metal and inhibitor components. In addition, the inhibition mechanism of each inhibitor is also suggested and discussed in detail.

scholarly journals BIA, DPA, MBTA and DMA as Vapour Phase Corrosion Inhibitors for Mild Steel under Different Atmospheric Conditions

2013 ◽  
Vol 20 ◽  
pp. 52-66
Author(s):  
Harish Kumar ◽  
Vikas Yadav
Keyword(s):  
Mild Steel ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Salt Spray ◽  
Vapour Phase ◽  
Raw Material ◽  
Atmospheric Conditions ◽  
Sem Images ◽  
Corrosion Inhibition Efficiency ◽  
Diphenyl Amine

Mild steel is widely used as main raw material in fabrication of equipment, chief material of construction and as weapons. During its storage and transportation conditions, it comes in contact with aggressive environment which leads to decrease in mechanical strength and loss in useful properties. Four different vapor phase corrosion inhibitors (VPCIs) i.e. Benzaimidazole (BIA), Diphenyl amine (DPA), 2-mercapto benzothiazole (MBTA) and N,N-dimethyl aniline (DMA) were tested under different atmospheric conditions at 40 °C by Weight Loss, Eschke test, Salt Spray, SO2 test and SEM techniques. All the four VPCIs show good corrosion inhibition efficiency i.e. 65-96 %. The results obtained from all the four corrosion experiments were supported by SEM images.

scholarly journals Ethanolamines as Corrosion Inhibitors for Zinc in (HNO3+H2SO4) Binary Acid Mixture

2010 ◽  
Vol 7 (2) ◽  
pp. 665-668 ◽  
Author(s):  
R. T. Vashi ◽  
H. M. Bhajiwala ◽  
S. A. Desai
Keyword(s):  
Corrosion Rate ◽  
Acid Concentration ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Corrosion Behaviour ◽  
Acid Mixture ◽  
Inhibitor Concentration

This work deals with the study of corrosion behaviour for zinc in (HNO3+ H2SO4) binary acid mixture containing ethanolamines. Corrosion rate increases with concentration of acid and temperature. At constant acid concentration, the inhibition efficiency of ethanolamines increases with the inhibitor concentration. Value of ΔGa increases and inhibition decreases with temperature. The mode of inhibition action appears to be chemisorption.

Scale inhibitors with a hyper-branched structure: preparation, characterization and scale inhibition mechanism

RSC Advances ◽  
2016 ◽  
Vol 6 (95) ◽  
pp. 92943-92952 ◽  
Author(s):  
Henghui Huang ◽  
Qi Yao ◽  
Hualin Chen ◽  
Bailing Liu
Keyword(s):  
Inhibition Efficiency ◽  
Water Bodies ◽  
Inhibition Mechanism ◽  
Industrial Water ◽  
Scale Inhibitor ◽  
Phosphorus Pollution ◽  
Scale Inhibition ◽  
New Type ◽  
Branched Structure

In order to improve the scale inhibition efficiency of existing scale inhibitors for industrial water and to reduce the phosphorus pollution of water bodies, a new type of scale inhibitor with a hyper-branched structure has been developed.

Alkaloid and Non Alkaloid Extracts of Solanum melongena Leaves as Green Corrosion Inhibitors on Carbon Steel in Alkaline Medium

2014 ◽  
Vol 3 (1) ◽  
Author(s):  
B U Ugi
Keyword(s):  
Carbon Steel ◽  
Thermodynamic Parameters ◽  
Inhibition Efficiency ◽  
Physical Adsorption ◽  
Solanum Melongena ◽  
Inhibition Mechanism ◽  
Maximum Inhibition ◽  
Efficiency Increase ◽  
Alkaloid Extracts ◽  
Green Corrosion Inhibitors

The corrosion and inhibition behavior of Carbon steel (CS) in high alkaline solution [Sodium trioxocarbonate (IV)] in the presence of alkaloid and non alkaloid extracts of Solanum melongena leaves have been studied using conventional methods - mass loss and gasometric techniques. The results indicate that the extracts inhibit the corrosion of Carbon steel. However, the Alkaloid extract of Solanum melongena leaves (AESML) exhibits higher maximum inhibition efficiency of 81.1% than Non alkaloid extract of Solanum melongena leaves [NAESML] (65.1%) at 3.0 g/L concentration. Inhibition efficiency increase with increasing concentration of extracts but decreased with rise in temperature. Inhibition mechanism was deduced from the activation and thermodynamic parameters that govern the process. Adsorption of extract on the CS was found to obey the Langmuir adsorption isotherm. The phenomenon of physical adsorption is proposed from the obtained thermodynamic parameters.

Sign in / Sign up

Export Citation Format

Share Document